ASCB 1

Hazard statements (CLP)

H317, H318, H331, H334, H341, H350

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

GHS Ratings Hazard Summary: Extremely corrosive and destructive to tissue. Specialized medical treatment is required for all exposures. May be fatal if inhaled, absorbed through skin, or swallowed. Target Organs: Liver, Kidney

Classifications

Inhalation Toxicity Acute Tox. 3 Gases>500+<=2500ppm, Vapors>2+<=10mg/l, Dusts&mists>.05+<=1mg/l Skin corrosive 1A Destruction of dermal tissue: Exposure <3 min. Observation <1 hour, visible necrosis in at least one animal Eye corrosive 1 Serious eye damage Irreversible damage 21 days after exposure, Draize score Corneal opacity >=3, Iritis > 1.5 Respiratory sensitizer 1 Respiratory sensitizer Skin sensitizer 1 Skin sensitizer Mutagen 2 Suspected/Possible: May include heritable mutation in human germ cells, Positive evidence from tests in mammals and somatic cell tests, In vivo somatic genotoxicity supported by in vitro mutagenicity Carcinogen 1B Presumed Human Carcinogen, Based on demonstrated animal carcinogencity Reproductive toxin 2 Human or animal evidence possibly with other information

Hazard statements

H3 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H318 Causes serious eye damage H331 Toxic if inhaled H334 May cause allergy or asthma difficulties if inhaled H341 Suspected of causing genetic defects H350 May cause cancer

Precautionary statements

P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P260 Do not breathe dust/fume/gas/mist/vapors/spray P261 Avoid breathing dust/fume/gas/mist/vapors/spray symptoms or breathing P264 Wash thoroughly after handling P271 Use only outdoors or in a well-ventilated area P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P281 Use personal protective equipment as required P285 In case of inadequate ventilation, wear respiratory protection P310 Immediately call a POISON CENTER or doctor/physician P311 Call a POISON CENTER or doctor/physician P321 Specific treatment (see . . . on this label) P363 Wash contaminated clothing before reuse P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with soap and water. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P333+P313 If skin irritation or a rash occurs: Get medical advice/attention. P342+P311 Call a POISON CENTER or doctor/physician P405 Store locked up P403+P233 Store in a well ventilated place. Keep container tightly closed. P501 Dispose of contents/container to . . . Danger: Acute Toxicity: Signs & Symptoms of Exposure Eyes: Burns, pain, watering eyes. Inhalation: Burning, choking, coughing, wheezing, laryngitis, shortness of breath, headache or nausea. Skin: Burning, irritation Ingestion: Severe and rapid corrosive burns of the mouth, gullet, and gastrointestinal tract, burning, choking, nausea, vomiting and severe pain.

Potential chronic health

May cause Fluorosis or hypocalcaemia