Sodium sulfide nonahydrate

Physical hazards

Pyrophoric solids Category 1

Health hazards

Acute toxicity, oral Category 3 Acute toxicity, dermal Category 3 Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1

Environmental hazards

Hazardous to the aquatic environment, acute Category 1 Hazardous to the aquatic environment, Category 1

Long term hazards

OSHA defined hazards Not classified.

Signal word

Danger

Hazard statements

Catches fire spontaneously if exposed to air. Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Prevention

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow contact with air. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear eye protection/face protection. Wear protective gloves/protective clothing/eye protection/face protection.

Response

If swallowed Immediately call a poison center/doctor. If swallowed Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Take off immediately all contaminated clothing and wash it before reuse. In case of fire: Use appropriate media to extinguish. Collect spillage.

Storage

Store locked up. Store contents under appropriate liquid or inert gas.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known.

Additional information

None.