Ecological

Hazard statements (CLP)

H225, H302, H312, H315, H319, H332, H336

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

1272/2008 and Compounds

vPvB Substances

Danger mechanism assessment criteria of for action this hazard and Not other class available Safety data sheet information ETHANOLAMINE Threshold Oxidising Very properties Limit Persistent Value and very Bioaccumulative as for Not REACH available Regulation SECTION 4. 7. First Information ASPIRATION On Substances - WGK: Type the basis

Hazard statements

Water not subject of HAZARD Handling available to Country classes the data, aid measures Rotterdam and storage (German). the TWA/8h product Convention: does not contain any STEL/15min PBT or vPvB in percentage greater than 0,1%. 9.2. None 4.1. 7.1. SECTION available

Further information

Description

Precautionary statements

1. of for H318 Identification first safe aid handling measures of the eye substance/mixture Causes serious mg/m3 ppm damage. mg/m3 ppm and of the company/undertaking 12.6. Information Does Other H315 WEL not meet adverse on likely the effects Parliament Avoid leakage / doctor. for rescue of the workers. product into the environment. 8.2. Intended Interactive Regulation 7. Exposure There Reuse, are when Regulation use no particular effects (EC) controls (EU) No. 487/2013 possible. risks 648/2004 (IV Atp. CLP) of the European Product of reaction residues with should other be substances considered in special Detergent Parliament all purpose for hard surfaces. normal hazardous conditions waste. of use. The hazard level of waste containing this product 4.2. 7.2. should Ingredients 8. Regulation according Most Conditions be important evaluated (EU) 944/2013 for safe symptoms according to Regulation

Principle Routes of Exposure

GBR Causes criteria 2,5 skin for irritation. this hazard 1 class 7,6 3 SKIN 1.1. VOC Substances GENERAL EYES: Keep away Product VLEP (Directive Remove identifier BIBLIOGRAPHY from heat, subject 2010/75/EC) contact sparks to ITA the Stockholm lenses, and naked 2,5 Convention: 1 if present. flames; Wash do not immediately 22,70 % 7,6 - 224,28 3 smoke or use with matches plenty of or lighters. g/litre SKIN water for Vapours at least may 30-60 catch minutes, fire and opening an explosion the eyelids may fully. Get Precautionary VOC Information None 1. Regulation medical occur; vapour OEL (volatile not (EU) advice/attention. carbon) accumulation is therefore to be avoided by leaving windows and doors open and ensuring good cross ventilation. Without

Disposal

the charges. subject to good drink considerations When working reactivity as performing much practices. water transfer Avoid as operations littering. possible. Inform Get involving the medical competent large advice/attention. containers, authorities, connect should Do to not an the induce earthing product vomiting system reach waterways unless and wear explicitly or Legend: Workers 4. Regulation P305+P351+P338 exposed (EU) Stability

Storage

and (V Atp. (EC) to including applicable effects, any CLP) No. of the 648/2004 both regulations. incompatibilities European Parliament acute and delayed Identified As Information 9. Regulation

Contains

the use Uses of not (EU) adequate available 605/2014 technical ALKYL (VI Atp. equipment ALCOHOL CLP) of must the ETHOXYLATED European always Industrial take Parliament priority over personal Professional protective equipment, make sure Consumer 2-BUTOXYETHANOL Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. that the workplace is 15.2. Washing, well 10. Chemical Specific Store LC50 CONTAMINATED Decomposes Regulation aired through - only for information in Fish the under cleaning safety (EU) effective original PACKAGING 2015/1221 on symptoms and assessment the container. maintenance effect of and ETHANOLAMINE local (VII aspiration. Atp. CLP) Store heat. effects product. the containers of the European Parliament caused 1700 by sealed, the mg/l/96h product in a Goldfish are well unknown. ventilated place, away from direct sunlight. Store in a well ventilated Ready-to-use When ACUTE 11. Regulation choosing TOXICITY product. (EU) personal 2016/918 Application protective (VIII Atp. equipment, with CLP) manual of the ask European your chemical Parliament substance supplier for advice. place, EC50 Contaminated - keep for Crustacea far packaging away from must sources be recovered of heat, naked or disposed flames 1700 of and mg/l/48h in sparks compliance Daphnia and other with national sources waste of ignition. management Keep containers regulations. processes. Personal No chemical away from any protective safety assessment equipment must has be been CE processed marked, showing for the - mixture that it complies and the substances with applicable it contains. standards. 4.3. incompatible DIPROPYLENE Indication of materials, - any GLYCOL immediate see MONOMETHYL section medical 10 for attention details. ETHER and special treatment needed Uses Provide LC50 - The (Inhalation) Merck Advised an emergency Index. Against of - the 10th shower mixture: Edition with face and eye wash station. > 20 mg/l ETHANOLAMINE May react with oxidising substances.When heated to decomposition releases harsh fumes,zinc alloys 7.3. Information SECTION All Ingredients HAND LD50 - Handling LC50 Specific uses (Oral) - for Fish PROTECTION different Chemical end according not available 14. of the Transport use(s) from mixture: Safety to those Regulation indicated. information (EC) No. 648/2004 170 mg/l/96h Carassius auratus >2000 mg/kg SECTION Protect LD50 - INRS (Dermal) - hands Fiche 16. with Toxicologique of Other the category mixture: information III (toxicological work gloves sheet) (see standard EN >2000 374). mg/kg 10.2. EC50 Chemical - for Crustacea stability 65 mg/l/48h daphnia magna 1.3. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail Less The - Patty Details following than - Industrial of 5% the should supplier Hygiene be considered of and the Toxicology safety when data choosing sheet work non-ionic glove material: surfactants compatibility, degradation, failure time and permeability. Information Text of hazard (RID), of the not (H) International available indications mentioned in section 2-3 of the sheet: Maritime Dangerous Goods (IMDG), SECTION perfumes The - N.I. work The ALKYL product Sax ALCOHOL gloves' - Dangerous 5. Firefighting is stable ETHOXYLATED Association resistance in normal conditions of use and storage. properties to chemical measures of Industrial regulations. agents Materials-7, should Code be 1989 checked Edition before and of use, the as International it can be unpredictable. Air Transport The gloves' wear (IATA) time depends on Name the - IFA duration GESTIS 2-BUTOXYETHANOL and website type of use. Chem-Italia S.r.l. LC50 Flam. - for Liq. number media Fish 2 Flammable liquid, category > 1 mg/l/96h 2 5.1. 14.1. Full Extinguishing SECTION SKIN - ECHA PROTECTION UN address LD50 website 8. (Oral) Exposure controls/personal Via Galileo protection 615 Galilei, mg/kg Rat 41 10.3. EC50 Possibility Acute - for Tox. Crustacea of 4 hazardous reactions Acute toxicity, category > 1 4 mg/l/48h 2.3. District Wear - Database EC50 Skin Other category - for Corr. and LD50 Algae 1B / Aquatic Plants Skin corrosion, category of Country (Dermal) SDS II professional models for long-sleeved chemicals - Ministry overalls of and 24040 > 1 mg/l/72h Health safety and 1B Chignolo 405 footwear ISS mg/kg (Istituto D'Isola Rabbit (see Superiore Directive 89/686/EEC di Sanità) - Italy and standard (BG) EN ISO 20344). Wash body 8.1. SUITABLE Not Control with soap LC50 applicable and (Inhalation) parameters EXTINGUISHING EQUIPMENT water after removing protective clothing. ITALY 2,2 mg/l/4h Rat The Eye Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can vapours Dam. may 1 also form explosive Serious mixtures eye damage, with the category air. 1 12.2. Persistence On EYE the PROTECTION Eye Irrit. 2 and degradability basis of available data, the product does not contain Eye irritation, category 2 Tel. any +39 PBT 0354944127 or vPvB in percentage greater than 0,1%. 14.2. be Regulatory Wear a ETHANOLAMINE Note for users: UN used proper hood visor or protective visor combined with airtight to disperse References: shipping flammable name vapours and protect those Fax trying goggles +39 to 0354944078 stem the leak. (see standard EN 166). SECTION 2-BUTOXYETHANOL e-mail UNSUITABLE RESPIRATORY The information contained in the present sheet are based on 1515 Skin Irrit. 2 address LD50 (Oral) 3. EXTINGUISHING of Composition/information PROTECTION the competent EQUIPMENT Skin irritation, category 2 person on ingredients our own mg/kg knowledge Rat on the date of the last version. Users must verify the Do GBR Not not May STOT react SE 3 dangerously with: aluminium,oxidising applicable use jets of water. United Water Kingdom is not effective Specific target organ agents.Forms EH40/2005 for putting toxicity - single Workplace out fires but peroxides exposure exposure, can be limits with: category used to cool containers exposed to flames to prevent air. 3 responsible If the threshold suitability and thoroughness of provided information according LD50 for (Dermal) the value Safety (e.g. Data TLV-TWA) Sheet is exceeded for laboratorio@chem-italia.com the substance 2504 to each mg/kg or specific one Rat of the use substances of the product. present in the product, use a mask with a type 3.1. DIPROPYLENE explosions. ITA Substances H225 GLYCOL MONOMETHYL Italia Highly flammable ETHER liquid and vapour. Decreto Legislativo 9 Aprile 2008, n.81 A This ETHANOLAMINE Solubility filter document H302 in water whose class must (1, not 2 be or regarded 3) must be as chosen Harmful if swallowed. 1000 - 10000 mg/l a guarantee according on any to the specific limit of product use concentration. property. (see standard EN 14387). In the presence of gases 14.3. Product EU or vapours The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the are Transport PROPAN-2-OL distribution of various hazard by: OEL EU kinds class(es) and/or gases or vapours Chem-Italia Directive (EU) 2017/164; containing particulate S.r.l. Directive Via (aerosol Galileo 2009/161/EU; Galilei, sprays, 41 fumes, Directive - 24040 2006/15/EC; mists, Chignolo etc.) combined D'Isola Directive filters (BG) 2004/37/EC; - current ITALY required. health Information Rapidly - Tel. May H312 react degradable not dangerously relevant with: Harmful acrylonitrile,chloroepoxypropane,chlorosulphuric in contact with skin. Directive mixture 2000/39/EC; Directive acid,hydrogen chloride,iron-sulphur compounds,acetic 5.2. Respiratory and safety laws and regulations. The producer is relieved from any liability Special LD50 acid,acetic H332 protection (Oral) arising anhydride,mesityl Harmful devices from must oxide,nitric the be substance used if the or technical if inhaled. acid,sulphuric acid,strong acids,vinyl acetate,cellulose nitrate. +39 0354944127 measures 4710 mg/kg Fax 91/322/EEC. adopted Rat arising +39 are 035494078 from not improper suitable - www.chem-italia.com for uses. restricting the worker's - info@chem-italia.com exposure to the threshold Not applicable Provide appointed staff with adequate LD50 values (Dermal) considered. TLV-ACGIH The protection training provided ACGIH 2016 on how by to masks use chemical 12800 is in mg/kg 3.2. 2-BUTOXYETHANOL any products. Mixtures H314 case Rat limited. BY EXPOSURE Causes severe skin burns and eye damage. IN THE If Emergency the substance LC50 CAUSED (Inhalation) telephone considered number is odourless or its EVENT olfactory OF threshold FIRE 72,6 is mg/l/4h higher Rat than the corresponding TLV-TWA and in the case of an 10.4. Solubility 14.4. Excess Conditions Packing H318 in water to avoid pressure group may form in containers exposed to fire at a risk Causes serious eye 1000 damage. - 10000 mg/l 2-BUTOXYETHANOL of explosion. Do not breathe combustion products. emergency, Changes to previous Rapidly H319 degradable wear open-circuit review: compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing Causes serious eye irritation. For Threshold apparatus The following compliance urgent ALKYL (in inquiries Limit Value sections ALCOHOL refer were to with ETHOXYLATED modified: standard EN 138). For Italian a correct Poison choice Control of respiratory Center protection ( 24/24 h): device, see standard EN 529. 5.3. Not Advice Avoid H315 Type applicable overheating. Avoid bunching Causes for firefighters Country TWA/8h of electrostatic skin irritation. charges. Avoid all sources of ignition. STEL/15min ENVIRONMENTAL 01 / 02 / LD50 Identification ETHANOLAMINE H335 03 / 04 (Oral) / 07 EXPOSURE / 08 / 09 / 10 CONTROLS x = Conc. May % cause respiratory / 11 / 12 / 14 / 15. Pavia - CAV Classification irritation

Hazard categories

Not available These indications apply for both processing staff and those involved in emergency and/or the environment are given in sections 11 and 12 of this sheet. 15.1. procedures. INDEX Flash Partition - INDEX Safety, health and environmental regulations/legislation specific for the substance or mixture May point develop: NUMBER: coefficient: hydrogen. Identifier n-octanol/water in Annex VI of CLP > 60 0,81 °C CARCINOGENICITY Reg. Evaporation - LC50: no. classification Lethal 02-2119552461-55-0000 Rate Concentration and indication: 50% Not available PROPAN-2-OL 6.2. Seveso Threshold Limit Value Environmental Serious Category precautions damage, - Directive 2012/18/EC: None ETHANOLAMINE Flammability - LD50: Type Lethal eye of dose solids 50% and category Country gases 1 TWA/8h Not available STEL/15min H318 Causes serious eye damage. Does not meet the classification criteria for this hazard class CAS Lower Partition - OEL: Skin May inflammability Occupational develop: irritation, coefficient: 141-43-5 nitric category n-octanol/water Exposure limit oxide,carbon 1 2 ≤ x Level < 3 oxides. Acute Tox. Not -2,3 4 available H302, Acute H315 Tox. 4 H312, Acute Causes Tox. skin 4 irritation. H332, Skin Corr. 1B H314, The Restrictions product must relating not to penetrate the product into or the contained mg/m3 sewer system ppm substances or come pursuant mg/m3 into contact to Annex ppm with XVII surface to EC water Regulation

PBT Substances

inflammability WEL Persistent bioaccumulative GBR limit and toxic as STOT 999 REACH SE Not Regulation 400 3 available H335 1250 500 2.2. Product REPRODUCTIVE elements TOXICITY EC Lower PROPAN-2-OL - PEC: Label explosive TLV-ACGIH Predicted 205-483-3 limit environmental Concentration 492 200 Not available 983 400 6.3. SECTION INDEX Upper Partition - PEL: Methods Point explosive Predicted coefficient: 603-030-00-8 and material 11. Toxicological limit exposure n-octanol/water for level containment and cleaning information Not 0,05 available up Hazard Does not meet the classification criteria for this hazard class Reg. Vapour - PNEC: no. labelling pressure Predicted 01-2119486455 pursuant no effect to concentration EC Regulation 1272/2008 Not (CLP) available and subsequent amendments and supplements. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it Collect

2.1 Classification of the substance or mixture

1272/2008 (CLP) < 2000 IRCCS mg/kg Fondazione Rat Maugeri Tel.+39 0382 24444 The emissions generated by manufacturing processes, Milano mg/m3 ppm including - mg/m3 CAV those Ospedale generated ppm Niguarda by ventilation Ca’ Granda equipment, Tel.+39 should 02 66101029 be checked to ensure 2-BUTOXYETHANOL Solubility H336 in water May cause drowsiness 1000 or - dizziness. 10000 mg/l 14.5. GENERAL compliance SKIN CORROSION Environmental WEL INFORMATION with environmental hazards / IRRITATION GBR standards. 123 25 Bergamo 246 - CAV Ospedali 50 Riuniti Tel.+39 SKIN 800 883300 2-BUTOXYETHANOL Rapidly Use VLEP Avoid degradable jets of water to cool exposure to: sources of heat,naked flames. ITA the containers 98 to prevent 20 product 50 and the development SKIN Firenze decomposition - 246 CAV Ospedale Careggi Tel.+39 of 055 substances 7947819 potentially hazardous for CAS health. Not OEL applicable Always wear full EU fire prevention 111-76-2 5 ≤ x < 8 98 gear. Collect Acute Tox. 4 H302, Acute Tox. 4 H312, Acute Tox. 4 H332, Eye Irrit. 2 H319, Skin Irrit. 2 H315 20 extinguishing water to 50 prevent it from SKIN draining into the sewer system. Dispose of Causes skin irritation EC ETHANOLAMINE PROPAN-2-OL LEGEND: 203-905-0 Roma - CAV 246 Policlinico Gemelli Tel.+39 SECTION contaminated TLV-ACGIH 06 3054343 9. water Physical used for extinction and 97 chemical and the remains 20 properties Roma of the - CAV fire according Policlinico to Umberto applicable I Tel.+39 regulations. 06 49978000 14.6. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS INDEX Rapidly - ADR: Avoid European degradable exposure 603-014-00-0 precautions Agreement to: air,sources user concerning of heat. the carriage of Dangerous goods by Road SERIOUS DIPROPYLENE - CAS NUMBER: GLYCOL Special EYE DAMAGE for Chemical MONOMETHYL / IRRITATION Abstract Service ETHER Number Napoli - CAV Ospedale Cardarelli Tel.+39 081 7472870 Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves Foggia (BS - Az. EN Osp. 659) Univ. and boots Foggia (HO Tel.+39 specification 0881 732326 A29 and A30) in combination with 9.1. 10.5. CAS ALKYL - CE50: self-contained Not applicable open circuit positive pressure compressed Information Incompatible ALCOHOL Effective 34590-94-8 on materials concentration basic ETHOXYLATED physical 4 ≤ x < (required 7 and chemical to Substance induce properties DIPROPYLENE with a 50% a community air breathing effect) workplace exposure limit. GLYCOL apparatus MONOMETHYL (BS EN 137). ETHER Causes serious eye damage EC Rapidly - CE NUMBER: degradable 252-104-2 Identifier in ESIS (European archive of existing substances) Threshold Limit Value 14.7. RESPIRATORY SECTION INDEX Appearance ETHANOLAMINE - CLP: EC Regulation 1272/2008 Transport Type 2. in Hazards bulk SKIN Country according identification to TWA/8h Annex II of Marpol and STEL/15min liquid the IBC Code OR 12.3. SECTION PROPAN-2-OL Colour - DNEL: Bioaccumulative Incompatible SENSITISATION Derived 6. Accidental with: No Effect potential iron,strong Level release acids,strong measures mg/m3 oxidants. yellow ppm mg/m3 ppm 2.1. CAS Odour - EmS: Information Classification WEL Emergency 67-63-0 of Schedule not relevant GBR the substance 1 ≤ x < 4 or mixture Flam. Liq. 308 50 alcoholic/parfumed 2 H225, Eye Irrit. 2 H319, STOT SE 3 H336 SKIN 6.1. Does not meet the classification criteria for this hazard class 10.6. EC Odour - GHS: Personal Hazardous threshold Globally 200-661-7 precautions, protective equipment and emergency procedures decomposition Harmonized System products of classification Not and available labeling of chemicals