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Hazard statements (CLP)

H223, H280, H319, H336

Code

Statements

H223

Flammable aerosol

Physical hazards

OSHA Flammable Aerosols Category 2 Gases under pressure Liquefied gas

Health hazards

Serious Eye Damage/Eye Irritation Category 2A Specific target organ systemic toxicity (single exposure) Category 3

2.3 Other hazards

None

Signal word

DANGER

Precautionary statements

H223 - Flammable aerosol P210 - Keep away from heat, sparks, open flames or hot surfaces. H336 - May cause drowsiness or dizziness P211 - Donot spray on an open flame or other ignition source H319 - Causes serious eye irritation P251 - Pressurized container: Do not pierce or burn, even after use H280 - Contains gas under pressure; may explode ifheated . os P261 - Avoid breathing vapors, mist or gas P271 - Use in a well-ventilated area. P280 - Wear protective gloves, protective clothing and eye protection. P264 - Wash face, hands and any exposed skin thoroughly after handling P304 + P340 - IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P312 - Call a physician if unwell. P305 + P351 +P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists, get medical attention. P403 - Store in a well-ventilated place P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/1 22 °F P501 - Dispose of contents and container in accordance with applicable local regulations. Component CAS No. Weight % ETHANOL | 64-17-5 60-100 Methyl acetate 79-20-9 10-30 | Carbon dioxide | 124-38-9 1-5 | “The exact percentage (concentration) of composition has been withheld as a trade secret General advice Do not breathe vapors or spray mist. Do not getin eyes, on skin or on clothing. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for atleast 15 minutes, Get medical attention immediately. Skin Contact Wash off immediately with soap and plenty of water. Get medical attention if irritation develops and persists. Remove and wash contaminated clothing before re -use. Inhalation If inhaled, remove to fresh air. In case of shortness of breath, give oxygen. If breathing has stopped, apply artificial respiration. Get medical attention immediately. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth. Notes to physician

Aspiration hazard

if swallowed - can enter lungs and cause damage. May be fatal if swallowed and enters airways. 3 ? | an ee PRE FIGHTING MEASURES Flash Point 55 °F /13°C Method Seta closed cup Flammability Limits in Air %: Solvent mixture. Upper: 36 Lower: 1.2 Suitable Extinguishing Media Water spray. Carbon dioxide (CO2). Alcohol -resistant foam.. Dry chemical. Use extinguishing measures that are appropriate to local . circumstances and the surrounding environment Specific hazards arising from the chemical Flammable. Solvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Flame extension: 18 inches / 45 cm and Burnback: 6inch /15 cm. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure -demand, NOHSC (approved or equivalent) and full protective gear. Aerosol Level (NFPA 30B) - 2 NFPA Health 3 Flammability 4 Instability 0 HMIS Health 3 Flammability 4 Instability 0 6 ACCIDENTAL RELEASE MEASURES | || Personal Precautions Use personal protective equipment. Remove all sources ofignition. Ensure adequate ventilation. Material can create slippery conditions. Take precautionary measures against static discharges. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non -combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Methods for Cleaning Up Use clean non-sparking tools to collect absorbed material. Pick up and transfer to properly labeled containers. Neutralizing Agent Not applicable. Bs Handling Keep away from open flames, hot surfaces and sources of ignition. Do not breathe vapors or spray mist. Do not getin eyes, on skin or on clothing.

Storage

Keep away from heat and sources ofignition. Keep in a dry, cool and well -ventilated place. Temperature Minimum 30 °F {2 °C Maximum 120 °F /49 °C Conditions Indoor xX Outdoor Heated Refrigerated _8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV

Principle Routes of Exposure

Inhalation, Skin contact, Eye contact | Skin contact, Skin Absorption. Acute Effects: Eyes Severe eye irritant. Skin May cause slight irritation. inhalation May cause irritation of respiratory tract. Inhalation of vapors in high concentration can cause narcotic effects and metabolic acidosis. Inhalation may cause central nervous system effects. May cause central nervous system depression. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. . Ingestion Ingestion may cause irritation to mucous membranes. Causes headache, drowsiness or other effects to the central nervous system. Lowered blood pressure. May be fatal or cause blindness if swallowed. | Chronic Toxicity May cause damage to the kidneys/iver/eyes/brain/digestive system/central nervous system through prolonged or repeated exposure if swallowed. Repeated and prolonged exposure to solvents may cause brain and nervous system damage. Contains a known or suspected carcinogen. Target Organ Effects Blood, Central nervous system, Gastrointestinal tract, Liver, Reproductive System, Respiratory system, Eyes, Heart, Kidney, Skin, Spleen, Pancreas.

Medical Conditions Generally Aggravated by Exposure

Heart, Liver disorders, Neurological disorders, Skin disorders, Respiratory disorders, Kidney disorders, Blood disorders, Cardiovascular. Component Information Acute Toxicity Component Oral LD50 Dermal LD50 Inhalation LC50 Draize Test Other ETHANOL No data available no data available =1247 mg (Rat)4h No data available 64-17-5 Methyl acetate > 5000 mg/kg ( Rat) > 5 g/kg ( Rabbit ) = 16000 ppm (Rat) 4h No data available 79-20-9 Component Mutagenicity Sensitization Developmental Reproductive Target Organ Effects Toxicity ETHANOL No data available Blood Skin Central nervous 64-17-5 system Eyes Respiratory system Reproductive System Liver Methyl acetate No data available Skin Central nervous _ 79-20-9 . system Eyes Respiratory system Carbon dioxide No data available Respiratory system Cardiovascular 124-38-9 system Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component ACGIH _IARC NTP