Cade 617J

Hazard statements (CLP)

H320

Code

Statements

H320

Causes eye irritation

SECTION 2: Hazards identification

OSHA Emergency Telephone Number CHEMTREC® 800-424-9300 Telephone inquiry 972-579-2477

Physical hazards

None

Health hazards

Serious Eye Damage/Eye Irritation Category 2B Ofher hazards None

Signal word

WARNING

Precautionary statements

H320 - Causes eye irritation P264 - Wash face, hands and any exposed skin thoroughly after handling P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if prasant and easy to do. Continue rinsing. P33? + P313 - If eye irritation persists, get medical attention. & % of the mixture consists of ingredient(s) of unknown toxicity ON INGREDIENTS Component CAS No. Weight % * Petroleum distillates, hydrotreated heavy paraffinic (<3% DMSO 64742-54-7 60-100 extractable} Petroleum distillates, solvent dewaxed heavy paraffinic (<3% DMSO 64742-65-0 7-13 extractable) Zine alkyl dithiophosphate 68649-42-3 1-5 *The exact percentage (concentration) of composition has been withheld as a trade secret General advice Avoid contact with skin, eyes and clothing. Avoid breathing mist. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention If irritation develops and persists. Skin Gontact Wash off with soap and plenty of water. Get medical attention if irritation develops and persists. Inhalation If inhaled, remove to fresh air. Get medical attention if symptoms occur. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention if symptoms occur. Notes to physician Treat symptomatically. Flash Point 428 °F /220 °C Method Open cup Flammability Limits in Air %: Not applicable. Upper: No data available Lower: No data available Sultable Extinguishing Media Carbon dioxide (CO2}, Dry chemical. Foam. Water spray. Use extinguishing measures that are appropriate to Jocal circumstances and the surrounding environment. Specific hazards arising from the chemical Material can create slippery conditions. Protective Equipment and Precautions for Firetighters As in any fire, wear self-contained breathing apparatus pressure-demand, NOHSC (approved or equivalent) and full protective gear. NFPA Health 2 _ Flammability 1 Instability 0 HMIS Health 2 Flammability 1 Instability 0 Personal Precautions Use personal protective equipment. Prevent further leakage or spillage if safe to do so. Material can create slippery conditions. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Methods for Cleaning Up Pick up and transfer ta properly labeled containers. Neutralizing Agent Not applicable. Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists.

Storage

Store in original container. Keep containers tightly closed in a dry, coal and well-ventilated place. Temperature Minimum -30 °F /-34 °C Maximum 130 °F /54°C Conditions Indoor x Outdoor Heated Refrigerated Exposure Guidelines Component ACGIH TLV

Product information

No information available, The following values are calculated based on chapter 3.1 of the GHS document Oral LD50 No information avallable Dermal LD50 No information available Inhalation LC50 Gas No information available Mist No information available Vapor No information available No information available. Component Information Component Toxicity to Algae Toxicity to Fish Microtox Crustacea log Pow Petroleum distillates, hydrotreated | No information available. | LO&0 > 5000 mg/L Cncorhynchus | No information available } 1000: 48 h Daphnia N/A heavy paraffinic (<3% DMSO mykiss 96 h magna mg/L EC&0 extractable) Petroleum distillates, solvent No information available. | LO50 > 5000 mg/L Oncorhynchus | No information available 1000: 48 h Daphnia N/A dewaxed heavy paraffinic (<3% mykiss 96 h magna mg/L EC50 DMSO extractable} Zine alkyl dithlophosphate No information available.| LC50 1.0- 5.0 mg/. Pimephales | No information available | 1- 1.5: 48 h Daphnia N/A promelas 96 h magna ma/L ECS LC50 16.0 - 35.0 mg/L Pimephales promelas 96 h Persistence and Degradability No information available. Bioaccumulation No information available. Mability No information available. Product Disposal Dispose of in accordance with local regulations. Container Disposal Empty containers should be taken for local recycling, recovery, or waste disposal. DOT Not regulated TDG Not regulated ICAO Not regulated IATA Not regulated IMDG/IMO Not regulated Inventories TSCA Complies DSL Complies U.S. Federal Regulations SARA 313 Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This preduct contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Component CAS No. Weight % * SARA 313 - Threshold Values Zinc alkyl dithiophosphate 68649-42-3 4-5 1.0 SARA 311/312 Hazardous Categorization . Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Reactive Hazard

Principle Routes of Exposure

Eye contact, Inhalation, Skin contact. None known. Acute Effects: Eyes Causes eye irritation. Skin Low hazard for usual industrial or commercial handling. Inhalation Low hazard for usual industrial or commercial handling. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic Toxicity No information available. Target Organ Effects None known.

Medical Conditions Generally Aggravated by Exposure

None known. Component Information Acuto Toxicity Component Oral LD50 Dermal LD50 Inhalation L¢50 Draize Test Other Petroleum distillates, > 5000 mg/kg (Rat) > 5000 mg/kg (Rabbit) No data available hydrotreated heavy paraffinic (<3% DMSO extractable) 64742-54-7 Petrolaum distillates, solvent >5000 mg/kg (rat) >5000 mafkg (rabbit) ne data available No data available dewaxed heavy paraffinic (<3% DMSO extractable) 64742-65-0 Zinc alkyl dithiophosphate 2230 mafkg (Rat) > 2000 mg/kg (Rat) No data available 68649-42-3 Carcinogenicity Contains no ingredient listed as a carcinogen.