Penner Whirlpool Disinfectant Cleaner

Hazard statements (CLP)

H314

Code

Statements

H314

Causes severe skin burns and eye damage

Further information

| RD17-76B Recommended use of the chemical and restrictions on use ] Recommended Use | A quaternary ammonium disinfectant cleaner formulated with non-ionic and cationic weiting agents. | Details of the supplier of the safety data sheet | Manufacturer Address Distributed by Central Solutions, Inc. Penner Patient Care, Inc. 401 Funston Rad. 102 Grant Street Kansas Gity, KS 66115 Aurora, NE 68818 Phone: 866-736-6377 Emergency Telephone Number] | Company Phone Number | , 913-621-6542 (M-F 8am to 4:30pm, CST) | Emergency Telephone (24 hr) | INFOTRAG 1-352-323-3500 (International) 1-800-535-5053 (North America) | Appearance Ciear yellow Physical State Liquid Odor Quaternary

2.1 Classification of the substance or mixture

Precautionary Statements - Prevention

Signal word

Danger

Hazard statements

Causes severe skin burns and eye damage This product is a U.S. EPA Registered pesticide, EPA Reg. No. 1839-95-741 02, and is subject to roy specific labeling requirements under Federal pesticide law. These requiremenis differ from the a x classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide products Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection

Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse iF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately cali a poison center or doctor/physician IF SWALLOWED: rinse mouth. Do NOT induce vomiting

Storage

KEEP OUT OF REACH OF CHILDREN-Do not contaminate water, food or feed by storage or disposal. Store ina dry place no lower in temperature than 50, or higher than 120°F. Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up. Keep out of the reach of children. DO NOT CONTAMINATE WATER, FOOD OR FEED BY STORAGE OR DISPOSAL. incompatible Materials None known based on information supplied. Exposure Guidelines Chemical Name ACGIH TLV

Disposal

Dispose of contents/container to an approved waste disposal plant - See product label for further instruction

2.3 Other hazards

Harmiul to aquatic life with long lasting effects Unknown Acute Toxicity 3% of the mixture consists of ingredient(s) of unknown toxicity Chemical Name CAS No Weight-% Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl 85409-23-0 25 ammonium chloride (Alternate CAS 68956-79-6) Alkyl dimethyl benzy! ammonium chloride (C12-18) 68391-01-5 EDTA 25 60-00-4 <5 Ethanol 64-17-5 <1 “if Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures Eye Contact Promptly wash eyes with plenty of water while lifting the eye lids. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician or Poison Control Center immediately. Obtain medical attention and take along these instructions. Skin Contact Wash with soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. Inhalation If symptoms are experienced, remove source of contamination or move victim to fresh air. if symptoms persist, get medical attention. If the affected person is not breathing, apply artificial respiration. if breathing is difficult, give oxygen. Get medical attention immediately. ingestion Call a physician or Poison Control Center immediately. Give one or two glasses or water if Patient is alert and able to swallow. Seek immediate medical attention. Do not induce vomiting. Never give anything by mouth to an unconscious person. Most important symptoms and effects Symptoms Protonged contact may even cause severe skin irritation or mild burn. Prolonged contact may cause irreversible damage to eye. Contact will cause irritation and redness to exposed areas. Will cause gastrointestinal tract irritation. Inhalation symptoms may include dizziness and headache. indication of any immediate medical attention and special treatment needed Notes to Physician If the product is ingested, probable mucosal damage may contraindicate the use of gastric lavage. Treat the affected person appropriately. Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical None known. Hazardous Combustion Products: Carbon oxides. Nitrogen oxides (NOx). Ammonia. Amines. Chlorine gas. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fult protective gear. Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas. Methods for Clean-Up Wear appropriate protective equipment and clothing during clean-up. Small Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Large Spills: Dike far ahead of liquid spill for later disposal. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or R it Precautions for safe handling Advice on Safe Handling Wash thoroughly after handling. Use personal protection recommended in Section 8. Do not breathe dust/fume/gas/mist/vapors/spray. Do not contaminate water, food, or feed. Do Not reuse empty containers. Keep containers clean and closed. Conditions for safe storage, including any incompatibilities

Appearance/Odor

Clear yellow liquid Quaternary Coior Clear yellow Odor Threshold Not determined Property Values

Remarks

Method_ pH 10.2- 12.2 Melting Point/Freezing Point 32 °F (0 C) Boiling Point/Boiling Range 100 °C /212 F Flash Point Non-flammable water based liquid Evaporation Rate Not established Flammability (Solid, Gas) néa-liquid Upper Flammability Limits Not applicable Lower Flammability Limit Not applicable Vapor Pressure Not established Vapor Density Not established Specific Gravity 1.023-1.054 (1=Water) @ 25 °C (77 ) Water Solubility Completely soluble Soiubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined Density 8.53-8.79 Ib/gal Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Keep out of reach of children. Incompatibie Materiais None known based on information supplied. Hazardous Decomposition Products Carbon oxides. Ammonia. Amines. Nitrogen oxides (NOx). Chlorine gas. Information on likely routes of exposure Product Information Eye Contact Causes severe eye damage. Skin Contact Causes severe skin burns. Inhalation Avoid breathing vapors or mists. ingestion Do not taste or swallow. Component Information (Chemical Name Oral LD50 Dermal LDS56 Inhalation LC50 EDTA = 1700 mg/kg { Rat) - 60-00-4 - Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl ammonium = >50 — 500 mg/kg (Ratad - chloride Alkyt dimethy! benzyt lammonium chloride (C12-18) = >50 — 500 mg/kg (Rata0 - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Ethanol has been shown to be carcinogenic in iong-term studies only when consumed as an alcoholic beverage. Chemical Name ACGIH IARC NTP OSHA Ethyt Alcohot A3 Group 1 Known x 64-17-5 Legend ACGIH (American Conference of Governmental industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity Not determined Unknown Acute Toxicity 3% of the mixture consists of ingredient(s) of unknown toxicity. Ecotoxicity Harmful to aquatic life with iong lasting effects. Chemical Name Algae/aquatic plants Fish Toxicity to Crustacea microorganisms EDTA 1.01: 72 h Desmodesmus 34 - 62: 96 h Lepomis 113: 48 h Daphnia magna 60-00-4 subspicatus mg/L EC50 macrochirus mg/L LC50 mo/L EC50 Static Static 44.2 - 76.5: 96h Pimephales promelas mg/L LC50 static Ethyl Alcohol 12.0 - 16.0: 96 h EC50 = 34634 mg/L 30 min | 9268 - 14221: 48h Daphnia 64-17-5 Oncorhynchus mykiss mL/L} EC50 = 35470 mg/L $ min Imagna mg/L LCSO 10800: 24! LCS0 static 100: 96h h Daphnia magna mg/L Pimephales promelas mg/L ECSO 2: 48 h Daphnia LC50 static 13400 - 15100: magna mg/L ECS Static 96 h Pimephales promelas mg/L LC50 flow-through Persistence/Deqradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Partition Coefficient Ethyl Alcohol -0.32 64-17-5