Portland cement clinker

Cementarnica Usje A.D. Skopje”

Revision date : 2017-01-04

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GHS05 GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

1305-78-8

Name of the chemical

Calcium oxide

Concentration

N/A

General Information

Revision date

2017-01-04

Product name

Portland cement clinker

CAS No.

65997-15-1

1.2.1 Relevant identified uses

Portland cement clinker is used for the production of common cements or other hydraulic binders in industrial installations. Cement and hydraulic binders are used in

Emergency telephone

University clinic of toxicology

Icons in SDS

Company Information

company name

Cementarnica Usje A.D. Skopje”

e-mail address of the competent person responsible for the Safety Data Sheet

ivana@usje.com.mk, natasak@usje.com.mk

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H318, H335

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

2.1 Classification of the substance or mixture

2.1.1 According to Regulation (EC) no. 1272/2008

Hazard statements

Skin irritation 2 H315: Causes skin irritation Serious eye damage/eye irritation 1 H318: Causes serious eye damage Skin sensitisation 1Β H317: May cause an allergic skin reaction Specific target organ toxicity H335: May cause respiratory single exposure respiratory tract 3 irritation H318 Causes serious eye damage H315 Causes skin irritation H317 May cause an allergic skin reaction H335 May cause respiratory irritation

2.2 Label elements

2.2.1 According to Regulation (EC) No 1272/2008

Hazard pictograms

Danger Attention

Signal word

Danger TITAN GRUPATION CEMENTARNICA "USJE" A.D - SKOPJE ul. Boris Trajkovski 94, 1000 Skopje, R. Macedonia, Phone no. + 389 2 2782 500, Sales 2786 536, Fax 2786 314 WWW.USJE.COM.MK 2 | 30

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338+P310 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician P302+P352+P333+P313 IF ON SKIN Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention P261+P304+P340+P312: Avoid breathing dust/fume/gas/mist/vapours/spray. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

2.3 Other hazards

Portland cement clinker does not meet the criteria for PBT or vPvB in accordance with Annex XIII of REACH (Regulation (EC) No 1907/2006). When Portland cement clinker accidentally comes into contact with water or when clinker or clinker dust becomes damp, a strong alkaline solution is produced. Due to the high alkalinity, wet Portland cement clinker may provoke skin and eye irritation. It may also cause an allergic reaction in some individuals due to the soluble Chromium Cr(VI) content. TITAN GRUPATION CEMENTARNICA "USJE" A.D - SKOPJE ul. Boris Trajkovski 94, 1000 Skopje, R. Macedonia, Phone no. + 389 2 2782 500, Sales 2786 536, Fax 2786 314 WWW.USJE.COM.MK 3 | 30

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