According to MKC EN 197-1

Cementarnica Usje A.D. Skopje”

Revision date : 2017-02-14

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GHS05 GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

General Information

Revision date

2017-02-14

Product name

According to MKC EN 197-1

CAS No.

7720-78-7

1.2.1 Relevant identified uses

Cements are used in industrial installations to manufacture/formulate hydraulic binders for

Icons in SDS

Company Information

company name

Cementarnica Usje A.D. Skopje”

e-mail address of the competent person responsible for the Safety Data Sheet

ivana@usje.com.mk, natasak@usje.com.mk

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H318, H335

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

2.1 Classification of the substance or mixture

2.1.1 According to Regulation (EC) no. 1272/2008

Hazard statements

Skin irritation 2 H315: Causes skin irritation Serious eye damage/eye irritation 1 H318: Causes serious eye damage H317: May cause an allergic skin Skin sensitisation 1Β reaction Specific target organ toxicity single 3 H335: May cause respiratory irritation exposure respiratory tract irritation H318 Causes serious eye damage H315 Causes skin irritation H317 May cause an allergic skin reaction H335 May cause respiratory irritation

2.2 Label elements

2.2.1 According to Regulation (EC) No 1272/2008

Hazard pictograms

Danger Attention TITAN GRUPATION CEMENTARNICA "USJE" A.D - SKOPJE ul. Boris Trajkovski 94, 1000 Skopje, R. Macedonia, Phone no. + 389 2 2782 500, Sales 2786 536, Fax 2786 314 WWW.USJE.COM.MK 2 | 39

Precautionary statements

P102: Keep out of reach of children P264: Wash thoroughly after handling P272: Contaminated work clothing should not be allowed out of the workplace P280: Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338+P310 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician P302+P352+P333+P313 IF ON SKIN Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention P261+P304+P340+P312: Avoid breathing dust/fume/gas/mist/vapours/spray. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment P362: Take off contaminated clothing and wash before reuse P501: Dispose of contents/container according to current regulations

Additional information

Skin contact with wet cement, fresh concrete or mortar may cause irritation, dermatitis or burns. May cause damage to products made of aluminium or other non-noble metals.

2.3 Other hazards

Portland cement does not meet the criteria for PBT or vPvB in accordance with Annex XIII of REACH (Regulation (EC) No 1907/2006). Cement dust can cause irritation of the respiratory system. When the cement reacts with water, for example when concrete or plaster is made, or when the cement is becoming wet, a strong alkaline solution is created. As a result of the high alkalinity, the wet cement can cause TITAN GRUPATION CEMENTARNICA "USJE" A.D - SKOPJE ul. Boris Trajkovski 94, 1000 Skopje, R. Macedonia, Phone no. + 389 2 2782 500, Sales 2786 536, Fax 2786 314 WWW.USJE.COM.MK 3 | 39 irritation of the skin and eyes. In some individuals it can cause an allergic reaction as a result of the contents of water soluble chromium Cr(VI). Usually, there is a low water soluble chromium Cr (VI) in the cement, or reduction agents are added to control the hypersensitivity of the water soluble chromium Cr(VI) under 2 mg/kg (0.0002%) of the total weight of dry cement ready to be used according to the legislation in TITAN GRUPATION CEMENTARNICA "USJE" A.D - SKOPJE ul. Boris Trajkovski 94, 1000 Skopje, R. Macedonia, Phone no. + 389 2 2782 500, Sales 2786 536, Fax 2786 314 WWW.USJE.COM.MK 4 | 39

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