Piperazine

Hazard statements (CLP)

H314, H317, H318, H334, H361, H402

Code

Statements

H314

Causes severe skin burns and eye damage

2.1 Classification of the substance or mixture

Skin Corrosion/Irritation, Category 1B Serious Eye Damage/Eye Irritation, Category 1 Respiratory Sensitization, Category 1 Skin Sensitization, Category 1 Toxic To Reproduction, Category 2 Aquatic Toxicity (Acute), Category 3

Signal word

Danger

Hazard statements

H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H361: Suspected of damaging fertility or the unborn child. H402: Harmful to aquatic life.

Precautionary statements

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe {dust/fume/gas/mist/vapors/spray}. P264: Wash {hands} thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear {protective gloves/protective clothing/eye protection/face protection}. P285: In case of inadequate ventilation wear respiratory protection.

Response

P301+330+331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+352 IF ON SKIN Wash with plenty of soap and water P303+361+353 IF ON SKIN (or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+351+338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+313 IF exposed or concerned Get medical attention/advice P310: Immediately call a POISON CENTER or doctor/physician. P333+313: If skin irritation or rash occurs, seek medical advice/attention. P342+311: If experiencing respiratory symptoms call a POISON CENTER or doctor/physician. P362+364: Take off contaminated clothing and wash it before reuse. P363: Wash contaminated clothing before reuse.

Storage

Please refer to Section 7 for Storage and Section 13 for Disposal information.

Potential health effects

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful to aquatic life. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Material may be irritating to the mucous membranes and upper respiratory tract. May be harmful by inhalation, ingestion, or skin absorption. May cause eye, skin, or respiratory system irritation. Suspected of damaging fertility or the unborn child. To the best of our knowledge, the toxicological properties have not been thoroughly investigated.