Piperazine

Hazard statements (CLP)

H228, H302, H314, H317, H318, H334, H361

Code

Statements

H228

Flammable solid

SECTION 2: Hazards identification

NFPA Rating Classification of the substance or mixture d ~ GHS02 Flame Flammable solids 1 H228 Flammable solid d ~ GHS08 Health hazard Sensitization - respiratory 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Reproductive toxicity 2 H361 Suspected of damaging fertility or the unborn child Contd. from page 1) d ~ GHS05 Corrosion Skin corrosion 1A H314 Causes severe skin burns and eye damage Eye damage 1 H318 Causes serious eye damage d ~ GHS07 Acute toxicity - oral 4 H302 Harmful if swallowed Sensitization - skin 1 H317 May cause an allergic skin reaction

2.2 Label elements

The substance is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

d ~ d ~ d ~ d ~ GHS02 GHS05 GHS07 GHS08

Signal word

Danger

Hazard statements

H228 Flammable solid. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H361 Suspected of damaging fertility or the unborn child.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground / bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting] equipment. P260 Do not breathe dusts or mists. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P284 [In case of inadequate ventilation] wear respiratory protection. P301+P312 If swallowed: Call a poison center/doctor if you feel unwell. P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P308+P313 IF exposed or concerned: Get medical advice/attention. (Contd. from page 2) P321 Specific treatment (see on this label). P362+P364 Take off contaminated clothing and wash it before reuse. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a poison center/doctor. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use CO2, powder or water spray to extinguish. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Information pertaining to particular dangers for man and environment

Classification system

· NFPA ratings (scale 0 - 4) Health = 3 2 Fire = 2 3 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *3 Health = *3 FIRE 2 Fire = 2 REACTIVITY 0 Reactivity = 0

PBT Substances

Not applicable

vPvB Substances

Not applicable

2.3 Other hazards

There are no adverse physical or health effects known that are not covered by the hazard classes of the Hazard Communications Standard.

2.1 Classification of the substance or mixture

d ~