Fentanyl (citrate)

Hazard statements (CLP)

H300, H300+H310+H330, H310, H317, H330, H334

Code

Statements

H300

Fatal if swallowed

SECTION 2: Hazards identification

NFPA Rating Classification of the substance or mixture d ~ GHS06 Skull and crossbones Acute toxicity - oral 2 H300 Fatal if swallowed Acute toxicity - dermal 2 H310 Fatal in contact with skin Acute toxicity - inhalation 2 H330 Fatal if inhaled d ~ GHS08 Health hazard Sensitization - respiratory 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Contd. from page 1) d ~ GHS07 Sensitization - skin 1 H317 May cause an allergic skin reaction

2.2 Label elements

The substance is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

d ~ d ~ GHS06 GHS08

Signal word

Danger

Hazard statements

H300+H310+H330 Fatal if swallowed, in contact with skin or if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves / protective clothing. P284 [In case of inadequate ventilation] wear respiratory protection. P301+P310 If swallowed: Immediately call a poison center/doctor. P330 Rinse mouth. P302+P352 If on skin: Wash with plenty of water. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P320 Specific treatment is urgent (see on this label). P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a poison center/doctor. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Information pertaining to particular dangers for man and environment

Classification system

· NFPA ratings (scale 0 - 4) Health = 4 0 Fire = 0 4 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *4 Health = *4 FIRE 0 Fire = 0 REACTIVITY 0 Reactivity = 0 (Contd. from page 2)

PBT Substances

Not applicable

vPvB Substances

Not applicable

2.3 Other hazards

There are no adverse physical or health effects known that are not covered by the hazard classes of the Hazard Communications Standard.

2.1 Classification of the substance or mixture

d ~ GHS06 Skull and crossbones Acute toxicity - oral 2 H300 Fatal if swallowed. Acute toxicity - dermal 2 H310 Fatal in contact with skin. Acute toxicity - inhalation 2 H330 Fatal if inhaled. d ~ GHS08 Health hazard Sensitization - respiratory 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. (Contd. from page 1) d ~ GHS07 Sensitization - skin 1 H317 May cause an allergic skin reaction.