Diphenylamine

Hazard statements (CLP)

H301, H301+H311+H331, H311, H331, H373, H400, H410

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

NFPA Rating Classification of the substance or mixture d ~ GHS06 Skull and crossbones Acute toxicity - oral 3 H301 Toxic if swallowed Acute toxicity - dermal 3 H311 Toxic in contact with skin Acute toxicity - inhalation 3 H331 Toxic if inhaled d ~ GHS08 Health hazard Specific target organ toxicity (repeated exposure) 2 H373 May cause damage to organs through prolonged or repeated exposure Contd. from page 1) d ~ GHS09 Environment Aquatic Acute 1 H400 Very toxic to aquatic life Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects

2.2 Label elements

The substance is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

d ~ d ~ d ~ GHS06 GHS08 GHS09

Signal word

Danger

Hazard statements

H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves / protective clothing. P301+P310 If swallowed: Immediately call a poison center/doctor. P321 Specific treatment (see on this label). P330 Rinse mouth. P302+P352 If on skin: Wash with plenty of water. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P311 Call a poison center/doctor. P312 Call a poison center/doctor if you feel unwell. P314 Get medical advice/attention if you feel unwell. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Information pertaining to particular dangers for man and environment

Classification system

· NFPA ratings (scale 0 - 4) Health = 4 1 Fire = 1 4 0 Reactivity = 0 (Contd. from page 2) · HMIS-ratings (scale 0 - 4) HEALTH 3 Health = 3 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0

PBT Substances

Not applicable

vPvB Substances

Not applicable

2.3 Other hazards

There are no adverse physical or health effects known that are not covered by the hazard classes of the Hazard Communications Standard.

2.1 Classification of the substance or mixture

d ~ GHS06 Skull and crossbones Acute toxicity - oral 3 H301 Toxic if swallowed. Acute toxicity - dermal 3 H311 Toxic in contact with skin. Acute toxicity - inhalation 3 H331 Toxic if inhaled. d ~ GHS08 Health hazard Specific target organ toxicity (repeated exposure) 2 H373 May cause damage to organs through prolonged or repeated exposure. (Contd. from page 1) d ~ GHS09 Environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.