Codeine-d3 (CRM)

Hazard statements (CLP)

H225, H301, H301+H311+H331, H311, H331, H370

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

NFPA Rating Classification of the substance or mixture d ~ GHS02 Flame Flammable liquids 2 H225 Highly flammable liquid and vapor d ~ GHS06 Skull and crossbones Acute toxicity - oral 3 H301 Toxic if swallowed Acute toxicity - dermal 3 H311 Toxic in contact with skin Acute toxicity - inhalation 3 H331 Toxic if inhaled d ~ GHS08 Health hazard Specific target organ toxicity (single exposure) 1 H370 Causes damage to the central nervous system and the visual organs Contd. from page 1)

2.2 Label elements

The product is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

d ~ d ~ d ~ GHS02 GHS06 GHS08

Signal word

Danger

Hazardous Ingredients

Methanol

Hazard statements

H225 Highly flammable liquid and vapor. H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled. H370 Causes damage to the central nervous system and the visual organs.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground / bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting] equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharge. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P301+P310 If swallowed: Immediately call a poison center/doctor. P321 Specific treatment (see on this label). P330 Rinse mouth. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P308+P311 IF exposed or concerned: Call a poison center/doctor. P312 Call a poison center/doctor if you feel unwell. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P370+P378 In case of fire: Use CO2, powder or water spray to extinguish. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Information pertaining to particular dangers for man and environment

Classification system

· NFPA ratings (scale 0 - 4) Health = 2 3 Fire = 3 2 0 Reactivity = 0 (Contd. from page 2) · HMIS-ratings (scale 0 - 4) HEALTH *2 Health = *2 FIRE 3 Fire = 3 REACTIVITY 0 Reactivity = 0

PBT Substances

Not applicable

vPvB Substances

Not applicable

2.3 Other hazards

There are no adverse physical or health effects known that are not covered by the hazard classes of the Hazard Communications Standard. *

2.1 Classification of the substance or mixture

d ~