5-bromo-5-nitro-1,3-Dioxane

Hazard statements (CLP)

H302, H311, H314, H317, H318, H335, H373, H400, H410

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

NFPA Rating Classification of the substance or mixture d ~ GHS06 Skull and crossbones Acute toxicity - dermal 3 H311 Toxic in contact with skin d ~ GHS08 Health hazard Specific target organ toxicity (repeated exposure) 2 H373 May cause damage to the liver, the heart and the stomach through prolonged or repeated exposure Contd. from page 1) d ~ GHS05 Corrosion Skin corrosion 1A H314 Causes severe skin burns and eye damage Eye damage 1 H318 Causes serious eye damage d ~ GHS09 Environment Aquatic Acute 1 H400 Very toxic to aquatic life Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects d ~ GHS07 Acute toxicity - oral 4 H302 Harmful if swallowed Sensitization - skin 1 H317 May cause an allergic skin reaction Specific target organ toxicity (single exposure) 3 H335 May cause respiratory irritation

2.2 Label elements

The substance is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

d ~ d ~ d ~ d ~ d ~ GHS05 GHS06 GHS07 GHS08 GHS09

Signal word

Danger

Hazard statements

H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H373 May cause damage to the liver, the heart and the stomach through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P260 Do not breathe dusts or mists. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P301+P312 If swallowed: Call a poison center/doctor if you feel unwell. P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. (Contd. from page 2) P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P321 Specific treatment (see on this label). P314 Get medical advice/attention if you feel unwell. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Information pertaining to particular dangers for man and environment

Classification system

· NFPA ratings (scale 0 - 4) Health = 3 0 Fire = 0 3 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *3 Health = *3 FIRE 0 Fire = 0 REACTIVITY 0 Reactivity = 0

PBT Substances

Not applicable

vPvB Substances

Not applicable

2.3 Other hazards

There are no adverse physical or health effects known that are not covered by the hazard classes of the Hazard Communications Standard.

2.1 Classification of the substance or mixture

d ~ GHS06 Skull and crossbones Acute toxicity - dermal 3 H311 Toxic in contact with skin. d ~ GHS08 Health hazard Specific target organ toxicity (repeated exposure) 2 H373 May cause damage to the liver, the heart and the stomach through prolonged or repeated exposure. (Contd. from page 1) d ~ GHS05 Corrosion Skin corrosion 1A H314 Causes severe skin burns and eye damage. Eye damage 1 H318 Causes serious eye damage. d ~ GHS09 Environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. d ~ GHS07 Acute toxicity - oral 4 H302 Harmful if swallowed. Sensitization - skin 1 H317 May cause an allergic skin reaction. Specific target organ toxicity (single exposure) 3 H335 May cause respiratory irritation.