ANHYDROUS AMMONIA

Physical hazards

Flammable gases Category 2 Gases under pressure Liquefied gas

Health hazards

Acute toxicity, inhalation Category 3 Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1

Environmental hazards

Hazardous to the aquatic environment, acute Category 1 OSHA defined hazards Not classified.

Signal word

Danger

Hazard statements

Flammable gas. Contains gas under pressure; may explode if heated. Toxic if inhaled. Causes severe skin burns and eye damage. Very toxic to aquatic life. ANHYDROUS AMMONIA SDS US Date: - Issue date 11-July-2014 920537 ~=—~ Version #: 01 1/8 17 9. Physical and chemical properties Appearance Colorless liquefied gas. Physical state Gas Form Liquefied gas. Color Colorless. Odor Strong pungent. Odor threshold Not available. Melting point/freezing point -110 - -30 °F (-78.89 - -34.44 °C) Initial boiling point and boiling -28 °F (-33.33 °C) range Flash point Not available. Evaporation rate Not available. Flammability (solid, gas) Flammable gas. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Vapor pressure 7.52 mm Hg at 100 °F / 37 °C Vapor density 0.596 at 32 °F /0°C Relative density 0.68 + 0.03 Relative density temperature 77 °F (25 °C) Solubility(ies) Solubility (water) Soluble in water. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not applicable. 10. Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport. Chemical stability Stable under normal temperature conditions and recommended use. Possibility of hazardous Polymerization will not occur. reactions Conditions to avoid In a fire or if heated, a pressure increase will occur and the container may burst or explode. Incompatible materials Oxidizing agents. Reducing agents. Acids. Hazardous decomposition Nitrous gases. products

TOXICOLOGICAL INFORMATION

Information on likely routes of exposure Ingestion This material is a gas under normal atmospheric conditions and ingestion is unlikely. Inhalation Toxic if inhaled. Skin contact Causes severe skin burns. Eye contact Causes serious eye damage. Symptoms related to the Symptoms include itching, burning, redness, and tearing of eyes. Contact with liquefied gas may physical, chemical and cause frostbite. Be aware that symptoms of lung edema (shortness of breath) may develop up to toxicological characteristics 24 hours after exposure. Information on toxicological effects Acute toxicity Toxic if inhaled. Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygen below safe breathing levels. Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn"). ANHYDROUS AMMONIA SDS US 920537 Version #: 01 Date: - Issue date 11-July-2014 4/8 20 Components Test Results Species Anhydrous Ammonia (CAS 7664-41-7) Acute Inhalation LC50 Rat 4000 ppm, 1 Hours 2000 ppm, 4 Hours Skin corrosion/irritation Causes severe skin burns. Serious eye damage/eye Causes serious eye damage. irritation Respiratory or skin sensitization Respiratory sensitization No data available. Skin sensitization Not a skin sensitizer. Germ cell mutagenicity No data available. Carcinogenicity This product is not considered to be a carcinogen by NTP, IARC, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity No data available. Specific target organ toxicity- No data available. single exposure Specific target organ toxicity - No data available. repeated exposure

Aspiration hazard

Not classified.

ECOLOGICAL INFORMATION

Ecotoxicity Very toxic to aquatic organisms. Components Species Test Results Anhydrous Ammonia (CAS 7664-41-7) Aquatic Fish LC50 Silver carp (Hypophthalmichthys molitrix) 0.38 mg/l, 96 hours Acute Algae EC50 Chlorella vulgaris < 2700 mg/|, 432 hours Crustacea EC50 Daphnia 25.4 mg/l, 48 hours NOEC Daphnia < 0.79 mg/l Fish LC50 Rainbow Trout 0.16 - 1.1 mg/l, 96 Hours NOEC Rainbow Trout < 1.2 mg/l Chronic Crustacea Daphnia 0.79 mg/l, 4 days Fish Ictalurus punctatus 0.048 mg/l, 31 days Persistence and degradability No data available. Bioaccumulative potential No data available Mobility in soil The product is water soluble and may spread in water systems.

Other hazards

No data available. 13. Disposal considerations Disposal instructions Dispose in accordance with all applicable regulations. Empty containers may contain product residues. Do not puncture or incinerate even when empty. This material and/or its container must be disposed of as hazardous waste. Return the empty cylinder to the supplier. Dispose ofin accordance with local regulations. Hazardous waste code Waste codes should be assigned by the user based on the application for which the product was used. Waste from residues / unused _ Dispose of in accordance with local regulations. products ANHYDROUS AMMONIA SDS US 920537 Vertsion#:01 Date: - Issue date 11-July-2014 5/8 21 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Anhydrous Ammonia (CAS 7664-41-7) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories

Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name CAS number Reportable Threshold quantity planning quantity planning quantity, be ch ge __2lowervalue ___Uppervalue Anhydrous Ammonia 7664-41-7 100 500 Ibs SARA 311/312 Hazardous Yes chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Anhydrous Ammonia 7664-41-7 >99.5 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Anhydrous Ammonia (CAS 7664-41-7) Clean Water Act (CWA)

Hazardous Ingredients

Section 112(r) (40 CFR 68.130) Safe Drinking Water Act Not regulated. (SDWA) US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List Anhydrous Ammonia (CAS 7664-41-7) US. New Jersey Worker and Community Right-to-Know Act Anhydrous Ammonia (CAS 7664-41-7) US. Pennsylvania Worker and Community Right-to-Know Law Anhydrous Ammonia (CAS 7664-41-7) US. Rhode Island RTK Anhydrous Ammonia (CAS 7664-41-7) US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 11-July-2014 Date: # Version # 01 ANHYDROUS AMMONIA SDS US 920537 Version#:01 Date: - Issue date 11-July-2014 7/8 23

NFPA Ratings

oo References Registry of Toxic Effects of Chemical Substances (RTECS) GESTIS Substance Database Disclaimer The information contained herein is accurate to the best of our knowledge. However, data, safety standards and government regulations are subject to change and, therefore, holders and users should satisfy themselves that they are aware of all current data and regulations relevant to their particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN. CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions relating to storage, handling, and use of the product are beyond the control of Carus Corporation, and shall be the sole responsibility of the holder or user of the product. (Carus and design) is a registered service mark of Carus Corporation. ANHYDROUS AMMONIA SDS US 920537 Version#:01 Date: - Issue date 11-July-2014 8/8 24 Form #: SDS 853020H iS @ HAW KE R Revised: err AA (06-16-16) sr Supersedes: 05/14/2015 ECO #: 1001735 (VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION ee Exposure Limits (mg/m3) Note: N.E.= Not Established INGREDIENTS OSHA PEL ACGIH US NIOSH Quebec PEV Ontario OEL EU OEL (Chemical/Common Names) Lead and Lead Compounds (inorganic) 0.05 0,15 (b) Antimony 0s 0.5 0.5 (b,e) Arsenic 0.2 0.01 NE 0,002 Calcium N.E NE Tin 2 NE Electrolyte (Sulfuric Acid) 1 0.2 1 I 0.2 0.05 (c) Polypropylene NE Polystyrene NE N.E NE N.E NE Styrene Acrylonitrile NE ‘Acrylonitrile Butadiene Styrene N.E NE N.E Styrene Butadiene N.E NE Polyvinylchloride NE i NE Polycarbonate, Hard Rubber, Polyethylene N.E NE N.E Silicon Dioxide (Gel Batteries Only) NE N.E NE Sheet Molding Compound (Glass reinforced polyester) NE N.E NOTES: (b) As inhalable aerosol (c) Thoracic fraction (e) Based on OEL;s Of Austria, Belgium, Denmark, France, Netherlands, Switzerland, & U.K. Engineering Controls (Ventilation): Store and handle in well-ventilated area. If mechanical ventilation is used, components must be acid-resistant. Handle batteries cautiously to avoid spills. Make certain vent caps are on securely. Avoid contact with internal components. Wear protective clothing, eye and face protection when filling, charging or handling batteries. Do not allow metallic materials to simultaneously contact both the positive and negative terminals of the batteries. Charge the batteries in areas with adequate ventilation. General dilution ventilation is acceptable. Respiratory Protection (NIOSH/MS) roved): None required under normal conditions. When concentrations of sulfuric acid mist are known to exceed the PEL, use NIOSH or MSHA-approved respiratory protection. Skin Protection: If battery case is damaged, use ubber or plastic acid-resistant gloves with elbow-length gauntlet, acid-resistant apron, clothing and boots. E ection: If batlery case is damaged, use chemical goggles or face shield. Other Protection: In areas where sulfuric acid is handled in concentrations greater than 1%, emergency eyewash stations and showers should be provided, with unlimited water supply. Acid-resistant apron. Under severe exposure emergency conditions, wear acid-resistant clothing and boots. Face shield recommended when adding water or clectrolyte to batteries, wash hands after handling. TX. PHYSICAL AND CHEMICAL PROPERTIES eee ce eee es et Properties Listed Below are for Electrolyte: Boiling Point: 203 - 240° F Specific Gravity (H20 = 1): 1.215 to 1.350 Melting Point: 10 N/A ‘Vapor Pressure (mm Hg); Solubility in Water: | 100% ‘Vapor Density (AIR = 1): Greater than Evaporation Rate: (Butyl Acetate = 1) Less than | % Volatile by Weight: N/A pH:|~1 to2 Flash Point: Below room temperature (as hydrogen gas) LEL (Lower Explosive Limit) 4.1% (Hydrogen) UEL (Upper Explosive Limit) 74.2% (Hydrogen)

Appearance/Odor

Manufactured article; no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating, pungent odor. Page 3 27 - CAMEO Calculations | Screening & Scenarios Last Modified 5/3/2018 Facility / Route Name|indianhead Foodservice | Chemical {SULFURIC ACID | CAS|7664-93-9 Scenario Name|indianhead Foodservice - Sulfuric Acid - Worst Case | Datasheet — > In Inventory |_| In Transit |_| Shipper Scenario Description Notes Amount Released |262 pounds Physical State |) Gas as Concentration |199 weight % Ne. [Ambient oli Release Duration minutes If stored in container with a dike, enter surface area within dike:[ ————_—isqft Atmospheric Concentration Level of Concern gm/m* LOC Description |Greenbook LOC Weather Information Wind Speed | 3.35 | mph Ground Roughness Wind From | in degrees measured clockwise from 0 N, Stability Class (for example: 015, 315, 270) Risk Assessment = pi-,[_| Probability of described accident occurring Consequences| i Severity of consequence to people Overall Risk} || Combination of probability and severity of consequence Threat Zone Radius miles 32 {Screening & Scenarios Last Modified 5/3/2018 Facility / Route Namelindianhead Foodservice Chemical [SULFURIC ACID ] CAS |[7664-93-9 ‘Scenario Namelindianhead Foodservice - Sulfuric Acid - Reevaluation Eee X In Inventory (In Transit [1] Shipper “Scenario Description Amount Released [262 __|pounds Physical State {© Gas Concentration |100 weight % @ Liquid u [Ambient Release Duration minutes OQ Solid If stored in container with a dike, enter surface area within dike:[_____|sq ft ‘Atmospheric Concentration Level of Concern gmim® LOC Description |Greenbook LOC Weather Information Wind Speed [17,9 _] mph Ground Roughness Wind From in degrees measured clockwise from 0 N. Stability Class [D] (for example: 015, 315, 270) Risk Assessment — gi, __| Probability of described accident occurring Consequences| __| Severity of consequence to people Overall Riski | Combination of probability and severity of consequence Threat Zone Radius 33 2013 | Edit Screening & Scenarios Last Modified 4/30/2018 | Facility / Route Name|indianhead Foodservice | Chemical [ANHYDROUS AMMONIA | CAS|7664-41-7 Scenario Nameilndianhead Foodservice - Worst Case XI In Inventory In Transit | Shipper Scenario Description Notes Amount Released 6083 pounds Physical State'@ Gas Concentration 3100 Eweight % Ua Release Duration!10 Eminutes Solid Atmospheric Concentration Level of Concern [035s gm LOC Description Greenbook LOC Ba Weather Information Wind Speed mph Wind From in degrees measured clockwise from 0 N. (for example: 015, 315,270) Risk Assessment Risk Probability of described accident occurring Consequences i:Severity of consequence to peaple Overall Risk: =:;Combination of probability and severity of consequence 34 2018 Edit Screening & Scenarios Last Modified 4/30/2018 Facility / Route Name|indianhead Foodservice Chemical [ANHYDROUS AMMONIA | casi7e64-41-7__ | Scenario Nameiindianhead Foodservice - Ammonia - Reevaluation i XX In Inventory {n Transit Shipper Scenario Description Amount Released 6083 Ipounds Physical State @ Gas Concentration 1100 ‘weight % QO Liquid Release Duration [19 minutes (O Solid If stored in container with a dike, enter surface area within dike:| Atmospheric Concentration Level of Concern 1.035 gmim® LOC Description Greenbook LOC =i Weather Information elas _ a Wind Speed mph Ground Roughness open country seh Wind From in degrees measured clockwise from 0 N. Stability Class D_] (for example: 015, 315,270) RISK ae sine Deere Probability of described accident occurring Consequences Severity of consequence to people Overall Risk Combination of probability and severity of consequence (CGisinrste Tireatzone Rass) 1.2 —_}mites Save Changes 35 2013 4" ote ¥. ZS Menard, Inc. Facility Off-Site Emergency Response Plan Facility #143371 Eau Claire County Office of Emergency Management Menard, Inc 721 Oxford Avenue 5101 Menard Dr Suite 3344 Eau Claire, Wisconsin 54703 TABLE OF CONTENTS SECTION 1: FACILITY INFORMATION EMergency CONTACTS 2.0... ececceeseseeeceeeeeeeeeeeeeeeeaaaeeeeeaaaeeeceeaaaeeeeeeaaaeeeceauaaeeeceaaaeeeeaeaaeeeeeaaanes Extremely Hazardous Substances HaZAardOuS SUDStTANCES ........ccecceccecceccecceceeeeeeeeeeneeaaeeae eee eeeeeeeeeseeeeeeeeeeeeeeeeeeeeeeeceeceeeeeceeseeneeaeeaas Resources/Support Available...........cccsccccssssscccsssseceecssseesessssseecsseseeeecesaeesesssaeeseseseeeesesaaesessgs Hazard AnalySis ...........cccccccecesceeeeeceeeeeeeeeeeeeeeeeeeaeeaaeeaeeee eee eeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeceeeeeseeseeeeeaeeaas Access to Facility SECTION 2: OUTSIDE RESOURCES Primary RESPONSE ABeN Cie ...........ccccccccssssseesccecececesseeeceeceeesauaaeeecesceesaaaaaneseeeceeasauaaseeeeeeeeaaeues Hazardous Materials Response Teams Other Outside Assistance SECTION 3: POPULATION/ENVIRONMENTAL PROTECTION Shelter-In-Place EVACUATION........cccccsseccceseeeceseeeeeeeeseseeesenseeeessetansseesussetenssenenaseeauecesaueesaanesseesssaneesseneessaeeessneees@a Nearby Shelters...........cccccccccsscceeeeceececeeeeeeeeeeesneseeaaeeaeeaseaeesseesseeeeeeeeeeeeeeeeeeeeeeeececeeeeeceeseeseeaeeass SECTION 4: VULNERABILITY ZONES/GENERAL INFORMATION