Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
N/A
General Information
Revision date
2014-12-19
Product name
PM-500-18
Product Synonyms
• Aromatic Isocyanate
1.2.1 Relevant identified uses
• Component for polyurethane
Manufacturer Name
Carpenter Co
Icons in SDS
Company Information
company name
Carpenter Co
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H333, H334, H335, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
Classification in accordance with 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200): Respiratory Sensitization Category 1 – H334 Skin Sensitization Category 1 – H317 Acute Toxicity Inhalation Category 4 – H333 Eye Irritation Category 2A – H319 Skin Irritation Category 2 – H315 Specific Target Organ Single Exposure 3 (respiratory system) – H335 Specific Target Organ Toxicity Repeated Exposure 2 (respiratory system) – H373
Signal word
DANGER
Hazard statements
H332 – Harmful if inhaled. H319 – Causes serious eye irritation. H315 – Causes skin irritation. H317 – May cause an allergic skin reaction. H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 – May cause respiratory irritation. H373 – May cause damage to organs through prolonged or repeated exposure (lungs).
Prevention
P260 - Do not breathe dust, mist, or vapors. P270 - Do not eat, drink or smoke when using this product. P271 – Use only outdoors or in a well-ventilated area. P285 - In case of inadequate ventilation wear respiratory protection. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P264 - Wash thoroughly after handling. P272 Contaminated work clothing must not be allowed out of the workplace.
Response
P308+P311 – IF exposed or concerned: Call a physician. P312 – Call a physician if you feel unwell. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical attention. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342+P311 - If experiencing respiratory symptoms: Call a physician. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P333+P313 - If skin irritation or rash occurs: Get medical attention. P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P362 + P364 – Take off contaminated clothing and wash before reuse. Storage/Disposal P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. P405 - Store locked up. P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
2.3 Other hazards
Onset of symptoms may be delayed. • Refer to Section 11 Toxicological Information for additional toxicity information. • Refer to Section 16 Other Information for HMIS and NFPA Codes. 10/31/2019 Carpenter Co.