Skin sensitization, category 1A

Hazard statements (CLP)

H225, H226, H302, H304, H312, H314, H315, H317, H318, H319, H332, H334, H335, H360Fd, H361d, H372, H373, H400, H410, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention. Rapidly degradable Thermal decomposition / conditions to avoid: Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: Maleic anhydride article) 7.1. Precautions for safe handling In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent - The Merck Index. - 10th Edition INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly ERC states at or below OEL values. The ototoxic action is amplified by the presence of LD50 (Oral) 8b Widespread use of reactive processing aid (no inclusion into or onto article, indoor) 1090 mg/kg rat

UN Number

The product does not decompose if handled and stored according to the standards. None accidental absorption. - Handling Chemical Safety noise (even at relatively low levels, for example below 85dBA) and by presence

2.1 Classification of the substance or mixture

authorised by a doctor. Xylene, mixture of isomers ERC LD50 (Dermal) 8c Widespread use leading to inclusion into/onto article (indoor) 2620 mg/kg rabbit Store in a cool place and away from humidity in perfectly closed drums. RESPIRATORY PROTECTION (A / P FILTER 2) - INRS - Fiche Toxicologique (toxicological sheet) INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops Rapidly degradable simultaneous use of several ototoxic substances LC50 (Inhalation) 8f Widespread use leading to inclusion into/onto article (outdoor) 4,35 mg/l/1h rat (vapour) 10.3. Possibility of hazardous reactions ADR / RID, IMDG, IATA: Substances subject to the Rotterdam Convention: ERC 1866 The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments If the threshold value (eg TLV-TWA) of the substance or one or more of the substances present in the product is exceeded, it is advisable to breathing, administer artificial respiration. Take suitable precautions for rescue workers. Protect from heat and direct sunlight. - Patty - Industrial Hygiene and Toxicology The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments PROC 1 Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent None Accurate ventilation / extraction in the workplace. wear a type A filter mask whose class (1, 2 or 3) must be chosen in relation to the limit concentration of use. (ref.EN 14387 standard). If gases 1272/2008 (CLP) 2-Hydroxyethyl methacrylate CAS 868-77-9 16 ≤ x < 17 Eye Irrit. 2 H319, Skin Irrit. 2 H315, Skin Sens. 1 H317, Classification note according to Annex VI to the CLP Regulation: D EC 212-782-2 INDEX 607-124-00-X Reg. no. 01-2119490169-29-xxxx Styrene CAS 100-42-5 14 ≤ x < 15 Flam. Liq. 3 H226, Repr. 2 H361d, Acute Tox. 4 H332, STOT RE 1 H372, Asp. Tox. 1 H304, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Aquatic Chronic 3 H412, Classification note according to Annex VI to the CLP Regulation: D EC 202-851-5 INDEX 601-026-00-0 Reg. no. 01-2119457861-32-xxxx Xylene, mixture of isomers CAS 1330-20-7 0,08 ≤ x < 0,1 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, STOT RE 2 H373, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Aquatic Acute 1 H400 M=1, Aquatic Chronic 3 H412, Classification note according to Annex VI to the CLP Regulation: C EC 215-535-7 INDEX 601-022-00-9 Reg. no. 01-2119488216-32-xxxx Maleic anhydride CAS 108-31-6 0,05 ≤ x < 0,08 Acute Tox. 4 H302, STOT RE 1 H372, Skin Corr. 1B H314, Eye Dam. 1 H318, Resp. Sens. 1 H334, Skin Sens. 1A H317, EUH071 EC 203-571-6 INDEX 607-096-00-9 Reg. no. 01-2119472428-31-xxxx Cobalt bis (2-Ethylhexanoate) CAS 136-52-7 0,05 ≤ x < 0,08 Repr. 1B H360Fd, Eye Irrit. 2 H319, Skin Sens. 1 H317, Aquatic Acute 1 H400 M=1, Aquatic Chronic 1 H410 M=1, EUH208 EC 205-250-6 INDEX Reg. no. 01-2119524678-29-xxxx Ethyl alcohol CAS 64-17-5 0,03 ≤ x < 0,05 Flam. Liq. 2 H225, Eye Irrit. 2 H319 EC 200-578-6 INDEX 603-002-00-5 Reg. no. 01-2119457610-43-xxxx Dipropylene Glycol Monomethylether CAS 34590-94-8 0,013 ≤ x < 0,015 Substance with a community workplace exposure limit. EC 252-104-2 INDEX Reg. no. 01-2119450011-60-xxxx The full wording of hazard (H) phrases is given in section 16 of the sheet. Styrene The range refers to the maximum content of Styrene. 2-Hydroxyethyl methacrylate The range refers to the maximum content of 2-hydroxyethyl methacrylate.

Aspiration hazard

N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. EPY 10.3.0 - SDS 1004.13 ... / >> Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Hazard classification and indication: Flammable liquid, category 3 H226 Flammable liquid and vapour. Reproductive toxicity, category 2 H361d Suspected of damaging the unborn child. Specific target organ toxicity - repeated exposure, H372 Causes damage to organs through prolonged or repeated category 1 exposure. Eye irritation, category 2 H319 Causes serious eye irritation. Skin irritation, category 2 H315 Causes skin irritation. Skin sensitization, category 1A H317 May cause an allergic skin reaction.

2.2 Label elements

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H361d Suspected of damaging the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. EUH208

Contains

Cobalt bis (2-Ethylhexanoate) May produce an allergic reaction. Styrene 2-Hydroxyethyl methacrylate Maleic anhydride Identification x = Conc. %

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P370+P378 In case of fire: extinguish with carbon dioxide, foam, chemical powder. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P201 Obtain special instructions before use. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P308+P313 IF exposed or concerned: Get medical advice / attention. P241 Use explosion-proof, explosion-proof electrical equipment, ventilation and lighting devices; the same applies to all material handling equipment.

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. SECTION 3. Composition/information on ingredients SECTION 3. Composition/information on ingredients ... / >> 3.2. Mixtures