Note: Ingredients listed on restricted chemical lists
General Information
Revision date
2020-12-21
Product name
ESP
Product Synonyms
Dipropylene Glycol Monomethylether
CAS No.
108-31-6
REACH No
01-2119457861-32-xxxx
1.2.1 Relevant identified uses
Dipropylene Glycol Monomethylether Sensitising for the skin None PROC 4 regarding hygiene and safety under his own responsibility. No responsibility is assumed for improper use
supplier name
Information in case of fire and explosion: mg/kg bw/d
Emergency telephone
+39 02 66101029, +39 0382 24444, +39 06 49978000
Icons in SDS
Company Information
company name
CARLO RICCO & F.LLI S.p.A.
e-mail address of the competent person responsible for the Safety Data Sheet
sicurezza@ricco.it
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H302, H304, H314, H315, H317, H318, H319, H332, H334, H335, H361d, H372, H412
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
2-Hydroxyethyl methacrylate EC50 - for Crustacea Carbon dioxide (CO₂) The ideal holding temperature is 23 ° C. Heating causes pressure increases and risks of Dipropylene Glycol Monomethylether H412 LD50 (Oral) Harmful to aquatic life with long lasting effects. 4,7 mg/l/48h Invertebrati - Daphnia magna 1090 mg/kg rat CAS with soap and water after removing protective clothing. 12. Regulation (EU) 2016/1179 (IX Atp. CLP) EC50 - for Algae / Aquatic Plants EUH071 LD50 (Dermal) 868-77-9 21 ≤ x < 22 Corrosive to the respiratory tract. Eye Irrit. 2 H319, Skin Irrit. 2 H315, Skin Sens. 1 H317, 4,9 mg/l/72h Algae - Selenastrum Capricornutum 2620 mg/kg rabbit Under certain fire conditions, traces of other harmful substances cannot be excluded. deflagrations. EYE PROTECTION Information not available 13. Regulation (EU) 2017/776 (X Atp. CLP) Forms peroxides with: air.
2.1 Classification of the substance or mixture
Chronic NOEC for Fish LC50 (Inhalation) Classification note according to Annex VI to the CLP Regulation: D 101 mg/l Invertebrati - Daphnia magna 4,35 mg/l/1h rat (vapour) 10.2. Chemical stability Keep the containers in a well-ventilated place. Wear airtight protective goggles (see standard EN 166). 14. Regulation (EU) 2018/669 (XI Atp. CLP) 5.3. Advice for firefighters EC Directive 2012/18 / EU (Seveso) Use descriptor system: Proceed carefully to reopen drums that have already started. 212-782-2 The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent 15. Regulation (EU) 2018/1480 (XIII Atp. CLP) INDEX · Qualifying quantity (tonnes) for the application of the lower threshold requirements 5,000 tonnes The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments ERC 2 607-124-00-X Formulation into mixture Thermal decomposition / conditions to avoid: accidental absorption. 16. Regulation (EU) 2019/521 (XII Atp. CLP) and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. EPY 10.3.0 - SDS 1004.13 ... / >> Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Hazard classification and indication: Reproductive toxicity, category 2 H361d Suspected of damaging the unborn child. Specific target organ toxicity - repeated exposure, H372 Causes damage to organs through prolonged or repeated category 1 exposure. Eye irritation, category 2 H319 Causes serious eye irritation. Skin irritation, category 2 H315 Causes skin irritation. Skin sensitization, category 1A H317 May cause an allergic skin reaction. 1272/2008 (CLP) 2-Hydroxyethyl methacrylate CAS 868-77-9 21 ≤ x < 22 Eye Irrit. 2 H319, Skin Irrit. 2 H315, Skin Sens. 1 H317, Classification note according to Annex VI to the CLP Regulation: D EC 212-782-2 INDEX 607-124-00-X SECTION 3. Composition/information on ingredients ... / >> Reg. no. 01-2119490169-29-xxxx Styrene CAS 100-42-5 12 ≤ x < 13 Flam. Liq. 3 H226, Repr. 2 H361d, Acute Tox. 4 H332, STOT RE 1 H372, Asp. Tox. 1 H304, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Aquatic Chronic 3 H412, Classification note according to Annex VI to the CLP Regulation: D EC 202-851-5 INDEX 601-026-00-0 Reg. no. 01-2119457861-32-xxxx Maleic anhydride CAS 108-31-6 0,05 ≤ x < 0,08 Acute Tox. 4 H302, STOT RE 1 H372, Skin Corr. 1B H314, Eye Dam. 1 H318, Resp. Sens. 1 H334, Skin Sens. 1A H317, EUH071 EC 203-571-6 INDEX 607-096-00-9 Reg. no. 01-2119472428-31-xxxx Dipropylene Glycol Monomethylether CAS 34590-94-8 0,007 ≤ x < 0,009 Substance with a community workplace exposure limit. EC 252-104-2 INDEX Reg. no. 01-2119450011-60-xxxx The full wording of hazard (H) phrases is given in section 16 of the sheet. Styrene The range refers to the maximum content of Styrene. 2-Hydroxyethyl methacrylate The range refers to the maximum content of 2-hydroxyethyl methacrylate.
2.2 Label elements
Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.
Signal word
Danger
Hazard statements
H361d Suspected of damaging the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction.
Precautionary statements
P280 Wear protective gloves/ protective clothing / eye protection / face protection. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P201 Obtain special instructions before use. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P308+P313 IF exposed or concerned: Get medical advice / attention. P337+P313 If eye irritation persists: Get medical advice / attention. P264 Wash your hands thoroughly after use. P241 Use explosion-proof, explosion-proof electrical equipment, ventilation and lighting devices; the same applies to all material handling equipment.
Contains
Styrene 2-Hydroxyethyl methacrylate Maleic anhydride Identification x = Conc. %
2.3 Other hazards
On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. SECTION 3. Composition/information on ingredients 3.2. Mixtures