TyrFil Hevi-Duty ISO Component

Hazard statements (CLP)

H304, H315, H317, H319, H330, H334, H340, H350, H360, H371, H372

Code

Statements

H304

May be fatal if swallowed and enters airways

Classifications

Inhalation Toxicity Acute Tox. 2 Gases>100+<=500ppm, Vapors>0.5+<=2mg/l, Dusts&mists>0.05+<=0.5mg/l Skin corrosive 2 Reversible adverse effects in dermal tissue, Draize score: >= 2.3 < 4.0 or persistent inflammation Eye corrosive 2A Eye irritant: Subcategory 2A, Reversible in 21 days Respiratory sensitizer 1 Respiratory sensitizer Skin sensitizer 1 Skin sensitizer Mutagen 1B Known to produce heritable mutations in human germ cellsSubcategory 1B, Positive results: In vivo heritable germ cell tests in mammals, Human germ cell tests, In vivo somatic mutagenicity tests, combined with some evidence of germ cell mutagenicity Carcinogen 1B Presumed Human Carcinogen, Based on demonstrated animal carcinogenicity Reproductive toxin 1B Presumed, Based on experimental animals Organ toxin single 2 Presumed to be harmful to human health- Animal studies with exposure significant toxic effects relevant to humans at generally moderate exposure (guidance) - Human evidence in exceptional cases Organ toxin repeated 1 Significant toxicity in humans- Reliable, good quality human exposure case studies or epidemiological studies Presumed significant toxicity in humans- Animal studies with significant and/or severe toxic effects relevant to humans at generally low exposure

Aspiration hazard

1 Aspiration Toxicity Category 1: Known (regarded)- human evidence - hydrocarbons with kinematic viscosity ? 20.5 mm2/s at 40° C.

Hazard statements

H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H330 Fatal if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H340 May cause genetic defects H350 May cause cancer H360 May damage fertility or the unborn child H371 May cause damage to organs H372 Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P260 Do not breathe dust/fume/gas/mist/vapors/spray P261 Avoid breathing dust/fume/gas/mist/vapors/spray P264 Wash hands thoroughly after handling P270 Do not eat, drink or smoke when using this product P271 Use only outdoors or in a well-ventilated area P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P281 Use personal protective equipment as required P285 In case of inadequate ventilation wear respiratory protection P311 Call a POISON CENTER or doctor/physician P314 Get Medical advice/attention if you feel unwell P321 Specific treatment is urgent (see Section 4 First Aid measures) P331 Do NOT induce vomiting P362 Take off contaminated clothing and wash before reuse P363 Wash contaminated clothing before reuse P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P302+P352 IF ON SKIN: Wash with soap and water P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing P308+P313 IF exposed or concerned: Get medical advice/attention P309+P311 IF exposed or you feel unwell: Call a POISON CENTER or doctor/physician P332+P313 If skin irritation occurs: Get medical advice/attention P333+P313 If skin irritation or a rash occurs: Get medical advice/attention P337+P313 Get medical advice/attention P342+P311 Call a POISON CENTER or doctor/physician P405 Store locked up P403+P233 Store in a well ventilated place. Keep container tightly closed P501 Dispose of contents/container in accordance with existing federal, state, and local environmental control laws.

Signal word

Danger

Potential Acute Health Effects

Eyes: Severe irritation, tearing, swelling, and possible damage to cornea. Skin: Irritation, redness, swelling, skin sensitization, rash, scaling, and blistering. Inhalation: Mucous membrane and respiratory tract irritation, tightness of chest, isocyanate sensitization. Conditions Aggravated by Exposure: Asthma, respiratory disorders, skin disorders, and eye disorders.

Potential chronic health

Isocyanates may cause skin and respiratory sensitivity in some individuals Sensitized individuals may react to very low levels diisocyanates below the PEL. Sensitized people who continue to work with diisocyanates may develop symptoms sooner after each exposure. Limited evidence of possible carcinogenic effects. Possible other harmful target organ effects.