General Information
Version
3.2 en
Revision date
2019-03-06
Product name
Wijs-solution 0,1 mol ICl/l - 0,2 N
1.2.2. Uses advised against
Do not use for squirting or spraying. Do not use for products which come into direct contact with the skin. Do not use for private purposes (house- hold). Food, drink and animal feedingstuffs 1.3
Icons in SDS
Company Information
company name
Carl Roth GmbH + Co. KG
e-mail address of the competent person responsible for the Safety Data Sheet
sicherheit@carlroth.de
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H290, H302, H312, H314, H315, H318, H319, H332, H335, H372, H400
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Classification according to GHS
Section
Hazard categories
Cat- Hazard class and egory
Hazard statements
2.6 Flammable liquid 3 Flam. Liq. 3 H226 2.16 Substance or mixture corrosive to metals 1 Met. Corr. 1 H290 3.2 Skin corrosion/irritation 1A Skin Corr. 1A H314 3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318 For full text of abbreviations: see SECTION 16 H226 Flammable liquid and vapour H290 May be corrosive to metals H314 Causes severe skin burns and eye damage
Most important adverse effects
Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi- dermis and into the dermis. The product is combustible and can be ignited by potential ignition sources.
Signal word
Danger
Hazard pictograms
GHS02, GHS05 Notes stance GHS Acetic acid ...% CAS No 95 – < 100 Flam. Liq. 3 / H226 B 64-19-7 Skin Corr. 1A / H314 GHS-HC Eye Dam. 1 / H318 IOELV EC No 200-580-7 Index No 607-002-00-6 Iodine CAS No < 1 Acute Tox. 4 / H302 GHS-HC 7553-56-2 Acute Tox. 4 / H312 Acute Tox. 4 / H332 EC No Skin Irrit. 2 / H315 231-442-4 Eye Irrit. 2 / H319 STOT SE 3 / H335 Index No STOT RE 1 / H372 053-001-00-3 Aquatic Acute 1 / H400 Notes B: Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solutions require different classification and labelling since the hazards vary at different concentra- tions. In Part 3 entries with Note B have a general designation of the following type: ‘nitric acid ... %’. In this case the supplier must state the percentage concentration of the solution on the label. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight basis. GHS-HC: Harmonised classification (the classification of the substance corresponds to the entry in the list according to 1272/2008/EC, Annex VI) IOELV: Substance with a community indicative occupational exposure limit value Name of sub- Identifier Specific Conc. Limits M-Factors ATE
Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor
Hazardous Ingredients
Acetic acid ...%
Results of PBT and vPvB assessment
Does not contain a PBT-/vPvB-substance at a concentration of ≥ 0,1%. Endocrine disrupting properties Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%. SECTION 3: Composition/information on ingredients 3.1 Substances not relevant (mixture) 3.2 Mixtures Description of the mixture Name of sub- Identifier Wt% Classification acc. to
Principle Routes of Exposure
stance Acetic acid ...% CAS No Skin Corr. 1A; H314: C ≥ 90 % - 64-19-7 Skin Corr. 1B; H314: 25 % ≤ C < 90 % EC No Skin Irrit. 2; H315: 10 % ≤ C < 25 % 200-580-7 Eye Dam. 1; H318: C ≥ 25 % Eye Irrit. 2; H319: 10 % ≤ C < 25 % Iodine CAS No - 1.500 mg/kg oral 7553-56-2 1.100 mg/kg dermal >4,588 mg/l inhalation: EC No /4h dust/mist 231-442-4
Remarks
For full text of abbreviations: see SECTION 16