Piperidine ≥99 %, for synthesis

Hazard statements (CLP)

H225, H302, H311, H311+H331, H314, H318, H331

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

According to Regulation (EC) No 1272/2008 [CLP Classification of the substance or mixture

Hazard categories

Cat- Hazard class and Hazard egory category statement 2.6 Flammable liquid Flam. Liq. 2 H225 3.1O Acute toxicity (oral) Acute Tox. 4 H302 3.1D Acute toxicity (dermal) Acute Tox. 3 H311 3.1I Acute toxicity (inhal.) Acute Tox. 3 H331 3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314 3.3 Serious eye damage/eye irritation Eye Dam. 1 H318 For full text of abbreviations: see SECTION 16

Most important adverse effects

Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi- dermis and into the dermis. The product is combustible and can be ignited by potential ignition sources

Signal word

Danger Danger Not required

Hazard pictograms

GHS02, GHS05, GHS06 H311+H331 Toxic in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P311 Call a POISON CENTER/doctor. Labelling of packages where the contents do not exceed 10 ml

Hazard statements

H225 Highly flammable liquid and vapour H302 Harmful if swallowed H311+H331 Toxic in contact with skin or if inhaled H314 Causes severe skin burns and eye damage Not required

Prevention

P210 Keep away from heat, sparks, open flames, hot surfaces. No smoking P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower] P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P311 Call a POISON CENTER/doctor Labelling of packages where the contents do not exceed 125 ml

Precautionary statements

Not required

Results of PBT and vPvB assessment

According to the results of its assessment, this substance is not a PBT or a vPvB. Endocrine disrupting properties Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP) Section Hazard class Cat- Hazard class and Hazard egory category statement 2.6 Flammable liquid 2 Flam. Liq. 2 H225 3.1O Acute toxicity (oral) 4 Acute Tox. 4 H302 3.1D Acute toxicity (dermal) 3 Acute Tox. 3 H311 3.1I Acute toxicity (inhal.) 3 Acute Tox. 3 H331 3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314 3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318 For full text of abbreviations: see SECTION 16 The most important adverse physicochemical, human health and environmental effects Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi- dermis and into the dermis. The product is combustible and can be ignited by potential ignition sources.