Menadione ≥ 98 % for biochemistry

Hazard statements (CLP)

H302, H315, H317, H319, H335, H400, H410

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

According to Regulation (EC) No 1272/2008 [CLP Classification of the substance or mixture

Hazard categories

Cat- Hazard class and Hazard egory category statement 3.1O Acute toxicity (oral) Acute Tox. 4 H302 3.2 Skin corrosion/irritation Skin Irrit. 2 H315 3.3 Serious eye damage/eye irritation Eye Irrit. 2 H319 3.4S Skin sensitisation Skin Sens. 1 H317 3.8R Specific target organ toxicity - single exposure (respir- STOT SE 3 H335 atory tract irritation) 4.1A Hazardous to the aquatic environment - acute hazard Aquatic Acute 1 H400 4.1C Hazardous to the aquatic environment - chronic hazard Aquatic Chronic 1 H410 For full text of abbreviations: see SECTION 16

Most important adverse effects

Spillage and fire water can cause pollution of watercourses

Signal word

Warning Not required

Hazard pictograms

GHS07, GHS09 H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. P280 Wear protective gloves/eye protection. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Labelling of packages where the contents do not exceed 10 ml Not required

Hazard statements

H302 Harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H335 May cause respiratory irritation H410 Very toxic to aquatic life with long lasting effects Not required

Prevention

P280 Wear protective gloves/eye protection

Response

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell P302+P352 IF ON SKIN: Wash with plenty of water P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Labelling of packages where the contents do not exceed 125 ml

Precautionary statements

Not required

Results of PBT and vPvB assessment

According to the results of its assessment, this substance is not a PBT or a vPvB. Endocrine disrupting properties Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP) Section Hazard class Cat- Hazard class and Hazard egory category statement 3.1O Acute toxicity (oral) 4 Acute Tox. 4 H302 3.2 Skin corrosion/irritation 2 Skin Irrit. 2 H315 3.3 Serious eye damage/eye irritation 2 Eye Irrit. 2 H319 3.4S Skin sensitisation 1 Skin Sens. 1 H317 3.8R Specific target organ toxicity - single exposure (respir- 3 STOT SE 3 H335 atory tract irritation) 4.1A Hazardous to the aquatic environment - acute hazard 1 Aquatic Acute 1 H400 4.1C Hazardous to the aquatic environment - chronic hazard 1 Aquatic Chronic 1 H410 For full text of abbreviations: see SECTION 16 The most important adverse physicochemical, human health and environmental effects Spillage and fire water can cause pollution of watercourses.