Inhibitor Cocktail Bacteria

Hazard statements (CLP)

H314, H318, H332, H373

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

According to Regulation (EC) No 1272/2008 [CLP Classification of the substance or mixture

Hazard categories

Cat- Hazard class and Hazard egory category statement 3.1I Acute toxicity (inhal.) Acute Tox. 4 H332 3.2 Skin corrosion/irritation 1C Skin Corr. 1C H314 3.3 Serious eye damage/eye irritation Eye Dam. 1 H318 3.9 Specific target organ toxicity - repeated exposure STOT RE 2 H373 For full text of abbreviations: see SECTION 16

Most important adverse effects

Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi- dermis and into the dermis. Delayed or immediate effects can be expected after short or long-term exposure

Signal word

Danger Danger

Hazard pictograms

GHS05, GHS07, GHS08 H314 Causes severe skin burns and eye damage. P280 Wear protective gloves/eye protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Hazard statements

H314 Causes severe skin burns and eye damage H332 Harmful if inhaled H373 May cause damage to organs (respiratory system) through prolonged or re- peated exposure (if inhaled)

Prevention

P280 Wear protective gloves/eye protection

Response

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower] P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

Hazardous Ingredients

Ethylenediamine tetraacetic acid disodium salt di- hydrate, 4-(2-Aminoethyl)benzenesulfonyl fluor- ide hydrochloride Labelling of packages where the contents do not exceed 125 ml

Contains

Ethylenediamine tetraacetic acid disodium salt dihydrate, 4-(2-Aminoethyl)benzenesulfonyl fluoride hydro- chloride

Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP) Section Hazard class Cat- Hazard class and Hazard egory category statement 3.1I Acute toxicity (inhal.) 4 Acute Tox. 4 H332 3.2 Skin corrosion/irritation 1C Skin Corr. 1C H314 3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318 3.9 Specific target organ toxicity - repeated exposure 2 STOT RE 2 H373 For full text of abbreviations: see SECTION 16 The most important adverse physicochemical, human health and environmental effects Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi- dermis and into the dermis. Delayed or immediate effects can be expected after short or long-term exposure. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 (CLP) Signal word Danger Pictograms GHS05, GHS07, GHS08 Hazard statements H314 Causes severe skin burns and eye damage H332 Harmful if inhaled H373 May cause damage to organs (respiratory system) through prolonged or re- peated exposure (if inhaled) Precautionary statements Precautionary statements - prevention P280 Wear protective gloves/eye protection Precautionary statements - response P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower] P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Hazardous ingredients for labelling: Ethylenediamine tetraacetic acid disodium salt di- hydrate, 4-(2-Aminoethyl)benzenesulfonyl fluor- ide hydrochloride Labelling of packages where the contents do not exceed 125 ml Signal word: Danger Symbol(s) H314 Causes severe skin burns and eye damage. P280 Wear protective gloves/eye protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. contains: Ethylenediamine tetraacetic acid disodium salt dihydrate, 4-(2-Aminoethyl)benzenesulfonyl fluoride hydro- chloride 2.3 Other hazards Results of PBT and vPvB assessment This mixture does not contain any substances that are assessed to be a PBT or a vPvB. SECTION 3: Composition/information on ingredients 3.1 Substances not relevant (mixture) 3.2 Mixtures Description of the mixture Name of sub- Identifier Wt% Classification acc. to Pictograms Notes stance GHS Ethylenediamine tet- CAS No > 80 Acute Tox. 4 / H332 raacetic acid disodi- 6381-92-6 STOT RE 2 / H373 um salt dihydrate EC No 205-358-3 4-(2-Aminoethyl)ben- CAS No 10 – 15 Skin Corr. 1C / H314 zenesulfonyl fluoride 30827-99-7 Eye Dam. 1 / H318 hydrochloride EC No 608-547-2 Pepstatin A CAS No 1 – < 5 26305-03-3 EC No 247-600-0 Bestatin hydrochloride CAS No < 2 65391-42-6 E-64 CAS No < 1 66701-25-5 Name of sub- Identifier Specific Conc. Limits M-Factors ATE Exposure stance route Ethylenediam- CAS No - 1,6 mg/l/4h inhalation: dust/ ine tetraacetic 6381-92-6 mist acid disodium salt dihydrate EC No 205-358-3 For full text of abbreviations: see SECTION 16 SECTION 4: First aid measures 4.1 Description of first aid measures General notes Take off immediately all contaminated clothing. Self-protection of the first aider. Following inhalation Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice. Following skin contact After contact with skin, wash immediately with plenty of water. Immediate medical treatment re- quired because corrosive injuries that are not treated are hard to cure. Following eye contact In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold- ing eyelids apart and consult an ophthalmologist. Protect uninjured eye. Following ingestion Rinse mouth immediately and drink plenty of water. Call a physician immediately. If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects). 4.2 Most important symptoms and effects, both acute and delayed Corrosion, Risk of blindness, Gastric perforation, Risk of serious damage to eyes 4.3 Indication of any immediate medical attention and special treatment needed none SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media co-ordinate firefighting measures to the fire surroundings water, foam, dry extinguishing powder, ABC-powder Unsuitable extinguishing media water jet 5.2 Special hazards arising from the substance or mixture Combustible. Hazardous combustion products In case of fire may be liberated: Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO₂), May produce toxic fumes of carbon monoxide if burning. 5.3 Advice for firefighters In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reas- onable distance. Wear self-contained breathing apparatus. Wear full chemical protective clothing. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe dust. 6.2 Environmental precautions Keep away from drains, surface and ground water. 6.3 Methods and material for containment and cleaning up Advice on how to contain a spill Covering of drains. Take up mechanically. Advice on how to clean up a spill Take up mechanically. Control of dust. Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area. 6.4 Reference to other sections Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom- patible materials: see section 10. Disposal considerations: see section 13. SECTION 7: Handling and storage 7.1 Precautions for safe handling Handle and open container with care. Avoid dust formation. Clear contaminated areas thoroughly. Measures to prevent fire as well as aerosol and dust generation Removal of dust deposits. Advice on general occupational hygiene Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.