4-Methyl-3-nitroaniline ≥ 99%, for synthesis

Hazard statements (CLP)

H301, H301+H311+H331, H311, H331, H373, H411

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

Hazard categories

Cat- Hazard class and egory

Hazard statements

3.1O Acute toxicity (oral) 3 Acute Tox. 3 H301 3.1D Acute toxicity (dermal) 3 Acute Tox. 3 H311 3.1I Acute toxicity (inhal.) 3 Acute Tox. 3 H331 3.9 Specific target organ toxicity - repeated exposure 2 STOT RE 2 H373 4.1C Hazardous to the aquatic environment - chronic hazard 2 Aquatic Chronic 2 H411 For full text of abbreviations: see SECTION 16 H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled H373 May cause damage to organs through prolonged or repeated exposure H411 Toxic to aquatic life with long lasting effects Not required

Most important adverse effects

Delayed or immediate effects can be expected after short or long-term exposure. Spillage and fire wa- ter can cause pollution of watercourses.

2.2 Label elements

Labelling

Signal word

Danger Danger Not required

Hazard pictograms

GHS06, GHS08, GHS09 H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled. P261 Avoid breathing dust. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTRE/doctor if you feel unwell. Labelling of packages where the contents do not exceed 10 ml

Prevention

P261 Avoid breathing dust P273 Avoid release to the environment P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P302+P352 IF ON SKIN: Wash with plenty of soap and water P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P312 Call a POISON CENTRE/doctor if you feel unwell Labelling of packages where the contents do not exceed 125 ml

Precautionary statements

Not required

Results of PBT and vPvB assessment

According to the results of its assessment, this substance is not a PBT or a vPvB. Endocrine disrupting properties Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%. SECTION 3: Composition/information on ingredients 3.1 Substances Name of substance 4-Methyl-3-nitroaniline Molecular formula C₇H₈N₂O₂ Molar mass 152,2 g/mol CAS No 119-32-4 EC No 204-314-0 Index No 612-025-00-X Substance, Specific Conc. Limits, M-factors, ATE Specific Conc. Limits M-Factors ATE

Principle Routes of Exposure

- 100 mg/kg oral 300 mg/kg dermal >0,5 mg/l/4h inhalation: dust/mist