METHYLENE CHLORIDE-D2 (D, 99.8%)

Hazard statements (CLP)

H302, H302+H312, H312, H315, H319, H335, H336, H351, H373

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

1999/45/EC Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Liver, Pancreas, Blood, Central nervous system, Heart, Kidney. Inhalation: anesthetic effects, nausea and drunkeness. Suspected of causing cancer (in contact with skin, if swallowed, if inhaled). May cause damage to organs (liver, blood, central nervous system) through prolonged or repeated exposure (if swallowed, if inhaled). May cause drowsiness or dizziness. Harmful in contact with skin. Harmful if swallowed. May cause respiratory irritation. Causes skin irritation. Causes serious eye irritation

Hazard pictograms

GHS08 GHS07 GHS08 GHS07

Signal word

Warning Warning

Hazard statements

H302+H312 - Harmful if swallowed or in contact with skin H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer (in contact with skin, if inhaled, if swallowed) H373 - May cause damage to organs (central nervous system, blood, liver) through prolonged or repeated exposure (oral, inhalation) H302+H312 - Harmful if swallowed or in contact with skin H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer (Dermal, Inhalation, oral) H373 - May cause damage to organs (blood, central nervous system, liver, respiratory system) through prolonged or repeated exposure (Dermal, Inhalation, oral)

Precautionary statements

P260 - Do not breathe dust, fume, gas, mist, spray, vapours P264 - Wash Both hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective clothing, protective gloves P301+P312 - IF SWALLOWED: Call a doctor, a POISON CENTER if you feel unwell P302+P352 - IF ON SKIN: Wash with plenty of water P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing GHS-US labelling P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust, fume, gas, mist, spray, vapours P261 - Avoid breathing dust, fume, gas, mist, spray, vapours P264 - Wash Both hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, face protection, protective clothing, protective gloves P301+P312 - If swallowed: Call a doctor, a POISON CENTER if you feel unwell P302+P352 - If on skin: Wash with plenty of water P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention P312 - Call a doctor, a POISON CENTER if you feel unwell P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment (see Hazard pictograms (CLP) on this label) P330 - Rinse mouth P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P362+P364 - Take off contaminated clothing and wash it before reuse P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to Comply with applicable regulations

PBT Substances

not relevant – no registration required

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox. 4 (Oral) H302 Acute Tox. 4 (Dermal) H312 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Carc. 2 H351 STOT SE 3 H336 STOT SE 3 H335 STOT RE 2 H373 Full text of hazard classes and H-statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Xi; R36/37/38 Carc.Cat.3; R40 T; R48 R67 Xn; R21/22 Full text of R-phrases: see section 16 GHS-US classification Acute Tox. 4 (Oral) H302 Acute Tox. 4 (Dermal) H312 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Carc. 2 H351 STOT SE 3 H336 STOT SE 3 H335 STOT RE 2 H373 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects Liver, Pancreas, Blood, Central nervous system, Heart, Kidney. Inhalation: anesthetic effects, nausea and drunkeness. Suspected of causing cancer (in contact with skin, if swallowed, if inhaled). May cause damage to organs (liver, blood, central nervous system) through prolonged or repeated exposure (if swallowed, if inhaled). May cause drowsiness or dizziness. Harmful in contact with skin. Harmful if swallowed. May cause respiratory irritation. Causes skin irritation. Causes serious eye irritation.