METHOD 521 NITROSAMINE NATIVE MIXTURE UNLABELED 100 UG/ML IN METHYLENE CHLORIDE

Hazard statements (CLP)

H302, H302+H312, H312, H315, H319, H335, H336, H351, H373

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Hazard statements

see section 16 see section 16 see section 16 : H302+H312 - Harmful if swallowed or in contact with skin H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer (in contact with skin, if inhaled, if swallowed) H373 - May cause damage to organs (central nervous system, blood, liver) through prolonged or repeated exposure (oral, inhalation) : H302+H312 - Harmful if swallowed or in contact with skin H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer (Dermal, Inhalation, oral) H373 - May cause damage to organs (blood, central nervous system, liver, respiratory system) through prolonged or repeated exposure (Dermal, Inhalation, oral)

EU Classification

Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Xi; R36/37/38 Carc.Cat.3; R40 T; R48/25 R67 Xn; R21/22

Classification (GHS-US)

Acute Tox. 4 (Oral) H302 Acute Tox. 4 (Dermal) H312 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Carc. 2 H351 STOT SE 3 H336 STOT SE 3 H335 STOT RE 2 H373

Adverse physicochemical, human health and environmental effects

Liver, Pancreas, Blood, Central nervous system, Heart, Kidney. Inhalation: anesthetic effects, nausea and drunkeness. Suspected of causing cancer (in contact with skin, if swallowed, if inhaled). May cause damage to organs (liver, blood, central nervous system) through prolonged or repeated exposure (if swallowed, if inhaled). May cause drowsiness or dizziness. Harmful in contact with skin. Harmful if swallowed. May cause respiratory irritation. Causes skin irritation. Causes serious eye irritation.

2.2 Label elements

Labeling

Hazard pictograms

GHS08 GHS07 GHS08 GHS07

Signal word

Warning : Warning

Precautionary statements

P260 - Do not breathe dust, fume, gas, mist, spray, vapors. P264 - Wash Both hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective clothing, protective gloves. P301+P312 - IF SWALLOWED: Call a doctor, a POISON CENTER if you feel unwell. P302+P352 - IF ON SKIN: Wash with plenty of water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. GHS-US labeling : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe dust, fume, gas, mist, spray, vapors. P261 - Avoid breathing dust, fume, gas, mist, spray, vapors. P264 - Wash Both hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear eye protection, face protection, protective clothing, protective gloves. P301+P312 - If swallowed: Call a doctor, a POISON CENTER if you feel unwell P302+P352 - If on skin: Wash with plenty of water P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a doctor, a POISON CENTER if you feel unwell P314 - Get medical advice/attention if you feel unwell. P321 - Specific treatment (see Hazard pictograms (CLP) on this label) P330 - Rinse mouth. P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P362+P364 - Take off contaminated clothing and wash it before reuse. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to Comply with applicable regulations

PBT Substances

not relevant – no registration required