METHANOL-D4 (D, 99.8%) +0.05% V/V TMS

Hazard statements (CLP)

H225, H301+H311+H331, H315, H319, H370

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

1999/45/EC Classification of the substance or mixture

Hazard statements

see section 16 see section 16 see section 16 : H225 - Highly flammable liquid and vapour H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H319 - Causes serious eye irritation H370 - Causes damage to organs (eyes, heart, kidneys, central nervous system) (in contact with skin, if inhaled, if swallowed) : H225 - Highly flammable liquid and vapour H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H319 - Causes serious eye irritation H370 - Causes damage to organs (central nervous system, eyes, heart, kidneys) (Dermal, Inhalation, oral)

EU Classification

Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F; R11 T; R23/24/25 Xi; R36/38 Xi; R39

Classification (GHS-US)

Flam. Liq. 2 H225 Acute Tox. 3 (Oral) H301 Acute Tox. 3 (Dermal) H311 Acute Tox. 3 (Inhalation) H331 Skin Irrit. 2 H315 Eye Irrit. 2A H319 STOT SE 1 H370

Adverse physicochemical, human health and environmental effects

Eyes, Kidney, Liver, Heart, Central nervous system

Hazard pictograms

GHS02 GHS08 GHS06 GHS02 GHS08 GHS06

Signal word

Danger : Danger

Precautionary statements

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment P260 - Do not breathe dust, fume, gas, mist, spray, vapors. P264 - Wash Both hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. GHS-US labeling : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe dust, fume, gas, mist, spray, vapors. P261 - Avoid breathing dust, fume, gas, mist, spray, vapors. P264 - Wash Both hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective clothing, protective gloves. P301+P310 - If swallowed: Immediately call a poison center or doctor P302+P352 - If on skin: Wash with plenty of water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P311 - Call a poison center or doctor P312 - Call a poison center or doctor if you feel unwell P321 - Specific treatment (see Hazard pictograms (CLP) on this label) P330 - Rinse mouth. P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P361 - Take off immediately all contaminated clothing. P362 - Take off contaminated clothing and wash before reuse. P363 - Wash contaminated clothing before reuse. P370+P378 - In case of fire: Use Alcohol resistant foam, Carbon dioxide, Water spray to extinguish. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to Comply with applicable regulations

2.3 Other hazards

No additional information available

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2 H225 Acute Tox. 3 (Oral) H301 Acute Tox. 3 (Dermal) H311 Acute Tox. 3 (Inhalation:dust,mist) H331 Skin Irrit. 2 H315 Eye Irrit. 2 H319 STOT SE 1 H370 Full text of hazard classes and H-statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F; R11 T; R23/24/25 Xi; R36/38 Xi; R39 Full text of R-phrases: see section 16 GHS-US classification Flam. Liq. 2 H225 Acute Tox. 3 (Oral) H301 Acute Tox. 3 (Dermal) H311 Acute Tox. 3 (Inhalation) H331 Skin Irrit. 2 H315 Eye Irrit. 2A H319 STOT SE 1 H370 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects Eyes, Kidney, Liver, Heart, Central nervous system.