BENZIDINE (RING-D8, 98%) 100 UG/ML IN TOLUENE

Hazard statements (CLP)

H225, H304, H315, H336, H361, H373, H401

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Hazard statements

see section 16 see section 16 see section 16 : H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure : H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure H401 - Toxic to aquatic life

EU Classification

Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Repr.Cat.3; R62 Repr.Cat.3; R63 F; R11 R48 Xi; R38 Xn; R65 R67

Classification (GHS-US)

Flam. Liq. 2 H225 Skin Irrit. 2 H315 Repr. 2 H361 STOT SE 3 H336 STOT RE 2 H373 Asp. Tox. 1 H304 Aquatic Acute 2 H401

Adverse physicochemical, human health and environmental effects

Bladder, Liver, Kidney, Brain.

2.2 Label elements

Labeling

Hazard pictograms

GHS02 GHS08 GHS07 GHS02 GHS08 GHS07

Signal word

Danger : Danger

Hazardous Ingredients

TOLUENE UNLABELED

Precautionary statements

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting equipment P260 - Do not breathe dust/fume/gas/mist/vapors/spray. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. GHS-US labeling : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting equipment P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe dust/fume/gas/mist/vapors/spray. P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - If swallowed: Immediately call a poison center or doctor P302+P352 - If on skin: Wash with plenty of water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a poison center or doctor if you feel unwell P314 - Get medical advice/attention if you feel unwell. P321 - Specific treatment (see supplemental first aid instruction on this label) P331 - Do NOT induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P370+P378 - In case of fire: Use media other than water to extinguish. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation

PBT Substances

not relevant – no registration required