Benzidine (ring-D₈, 98%) 100 µg/mL in toluene

Hazard statements (CLP)

H225, H304, H315, H336, H361, H373, H401

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS US classification Classification of the substance or mixture GHS US classification Flammable liquid, Category 2 H225 Highly flammable liquid and vapor. Skin corrosion/irritation, Category 2 H315 Causes skin irritation. Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child. Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness. Specific target organ toxicity — Repeated exposure, Category 2 H373 May cause damage to organs through prolonged or repeated exposure Aspiration hazard, Category 1 H304 May be fatal if swallowed and enters airways. Hazardous to the aquatic environment — Acute Hazard, Category 2 H401 Toxic to aquatic life Full text of H statements : see section 16

2.2 Label elements

GHS US labeling

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure H401 - Toxic to aquatic life

Precautionary statements

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment. P241 - Use explosion-proof equipment. P242 - Use non-sparking tools. P243 - Take action to prevent static discharges. P260 - Do not breathe dust, fume, gas, mist, vapors, spray. P261 - Avoid breathing dust, fume, gas, mist, vapors, spray. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection, and hearing protection. P301+P310 - If swallowed: Immediately call a poison center or doctor. P302+P352 - If on skin: Wash with plenty of water. P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a poison center or doctor if you feel unwell. P314 - Get medical advice or attention if you feel unwell. P321 - Specific treatment (see supplemental first aid instruction on this label). P331 - Do NOT induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice or attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P370+P378 - In case of fire: Use appropriate media to extinguish. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents and/or container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulations. 2.3. Hazards associated with known or reasonably anticipated uses No additional information available

2.3 Other hazards

No additional information available 2.5. Unknown acute toxicity No additional information available

2.1 Classification of the substance or mixture

GHS US classification Flammable liquid, Category 2 H225 Highly flammable liquid and vapor. Skin corrosion/irritation, Category 2 H315 Causes skin irritation. Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child. Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness. Specific target organ toxicity — Repeated exposure, Category 2 H373 May cause damage to organs through prolonged or repeated exposure. Aspiration hazard, Category 1 H304 May be fatal if swallowed and enters airways. Hazardous to the aquatic environment — Acute Hazard, Category 2 H401 Toxic to aquatic life. Full text of H statements : see section 16