ACRYLONITRILE (D3, 98%) (+0.1% 4-METHOXYPHENOL)

Hazard statements (CLP)

H225, H301, H301+H311+H331, H311, H315, H317, H318, H331, H335, H350, H361, H401, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS US classification Classification of the substance or mixture GHS US classification Flammable liquids Category 2 Acute toxicity (oral) Category 3 Acute toxicity (dermal) Category 3 Acute toxicity (inhalation) Category 3 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitization, Category 1 Carcinogenicity Category 1B Reproductive toxicity Category 2 H225 Highly flammable liquid and vapor H301 Toxic if swallowed H311 Toxic in contact with skin H331 Toxic if inhaled H315 Causes skin irritation H318 Causes serious eye damage H317 May cause an allergic skin reaction H350 May cause cancer (Dermal, Inhalation, oral) H361 Suspected of damaging fertility or the unborn child (Dermal, oral, Inhalation) Specific target organ toxicity – Single exposure, Category 3, H335 May cause respiratory irritation Respiratory tract irritation Hazardous to the aquatic environment – Acute Hazard Category 2 H401 Toxic to aquatic life Hazardous to the aquatic environment – Chronic Hazard Category 2 H411 Toxic to aquatic life with long lasting effects Full text of H statements : see section 16

2.2 Label elements

GHS US labeling

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H335 - May cause respiratory irritation H350 - May cause cancer (Dermal, Inhalation, oral) H361 - Suspected of damaging fertility or the unborn child (Dermal, oral, Inhalation) H401 - Toxic to aquatic life H411 - Toxic to aquatic life with long lasting effects

Precautionary statements

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. heat, hot surfaces, open flames, sparks P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P261 - Avoid breathing dust, fume, gas, mist, spray, vapors. P264 - Wash Both hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing must not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear eye protection, face protection, protective clothing, protective gloves. P301+P310 - If swallowed: Immediately call a poison center or doctor. P302+P352 - If on skin: Wash with plenty of water. P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - If exposed or concerned: Get medical advice/attention. P310 - Immediately call a poison center or doctor. P311 - Call a poison center or doctor. P312 - Call a poison center or doctor if you feel unwell. P321 - Specific treatment (see Hazard pictograms (CLP) on this label). P330 - Rinse mouth. P332+P313 - If skin irritation occurs: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P361 - Take off immediately all contaminated clothing. P362 - Take off contaminated clothing and wash before reuse. P362+P364 - Take off contaminated clothing and wash it before reuse. P363 - Wash contaminated clothing before reuse. P370+P378 - In case of fire: Use Alcohol resistant foam, Carbon dioxide, Dry chemical, Water spray to extinguish. P391 - Collect spillage. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to Comply with applicable regulations.

Other hazards which do not result in classification

No additional information available

Ingredient(s) with unknown acute toxicity

Not applicable

2.1 Classification of the substance or mixture

GHS US classification Flammable liquids Category 2 H225 Highly flammable liquid and vapor Acute toxicity (oral) Category 3 H301 Toxic if swallowed Acute toxicity (dermal) Category 3 H311 Toxic in contact with skin Acute toxicity (inhalation) Category 3 H331 Toxic if inhaled Skin corrosion/irritation Category 2 H315 Causes skin irritation Serious eye damage/eye irritation Category 1 H318 Causes serious eye damage Skin sensitization, Category 1 H317 May cause an allergic skin reaction Carcinogenicity Category 1B H350 May cause cancer (Dermal, Inhalation, oral) Reproductive toxicity Category 2 H361 Suspected of damaging fertility or the unborn child (Dermal, oral, Inhalation) Specific target organ toxicity – Single exposure, Category 3, H335 May cause respiratory irritation Respiratory tract irritation Hazardous to the aquatic environment – Acute Hazard Category 2 H401 Toxic to aquatic life Hazardous to the aquatic environment – Chronic Hazard Category 2 H411 Toxic to aquatic life with long lasting effects Full text of H statements : see section 16