Note: Ingredients listed on restricted chemical lists
EC/CAS
204-661-8/123-91-1
Name of the chemical
1,4-Dioxane
Concentration
42.03
General Information
Version
3.0
Revision date
2022-11-07
Product name
40% P-DIOXANE IN BENZENE-D6
Icons in SDS
Company Information
company name
Cambridge Isotope Laboratories, Inc
e-mail address of the competent person responsible for the Safety Data Sheet
cilsales@isotope.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H304, H315, H319, H335, H340, H350, H401
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Hazard statements
see section 16 see section 16 see section 16 : H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H340 - May cause genetic defects (in contact with skin, if inhaled, if swallowed) H350 - May cause cancer (in contact with skin, if inhaled, if swallowed) : H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H340 - May cause genetic defects (Dermal, Inhalation, oral) H350 - May cause cancer (Dermal, Inhalation, oral) H401 - Toxic to aquatic life
EU Classification
Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc.Cat.1; R45 Carc.Cat.1; R49 Carc.Cat.3; R40 Muta.Cat.1; R46 F; R11 Xn; R65 Xi; R36/37/38 N; R51/53
Classification (GHS-US)
Flam. Liq. 2 H225 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Muta. 1B H340 Carc. 1A H350 STOT SE 3 H335 Asp. Tox. 1 H304 Aquatic Acute 2 H401
Adverse physicochemical, human health and environmental effects
Blood, Eyes, Female reproductive system, Bone marrow.
2.2 Label elements
Labeling
Hazard pictograms
GHS02 GHS08 GHS07 GHS02 GHS08 GHS07
Signal word
Danger : Danger
Hazardous Ingredients
BENZENE-D6 (D, 99.5%); 1,4-DIOXANE (P-DIOXANE) UNLABELED
Precautionary statements
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment P261 - Avoid breathing fume, mist, spray, vapors. P264 - Wash both hands thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear eye protection, face protection, protective clothing, protective gloves. GHS-US labeling : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P261 - Avoid breathing fume, mist, spray, vapors. P264 - Wash Both hands thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear eye protection, face protection, protective clothing, protective gloves. P301+P310 - If swallowed: Immediately call a poison center or doctor P302+P352 - If on skin: Wash with plenty of water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a poison center or doctor if you feel unwell P321 - Specific treatment (see Hazard pictograms (CLP) on this label) P331 - Do NOT induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370+P378 - In case of fire: Use Alcohol resistant foam, Carbon dioxide, Dry chemical, Water spray to extinguish. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to Comply with applicable regulations
2.3 Other hazards
No additional information available