4-Hydroxyphenanthrene (unlabeled) 50 µg/mL in toluene

Hazard statements (CLP)

H225, H304, H315, H319, H332, H336, H351, H361, H371, H373, H400

Code

Statements

H225

Highly flammable liquid and vapour

H304

May be fatal if swallowed and enters airways

H315

Causes skin irritation

H319

Causes serious eye irritation

H332

Harmful if inhaled

H336

May cause drowsiness or dizziness

H351

Suspected of causing cancer

H361

Suspected of damaging fertility or the unborn child

H371

May cause damage to organs

H373

May cause damage to organs through prolonged or repeated exposure

H400

Very toxic to aquatic life

SECTION 2: Hazards identification

GHS US classification Classification of the substance or mixture GHS US classification Flammable liquids, Category 2 Acute toxicity (inhalation:dust,mist), Category 3 Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2A Carcinogenicity, Category 2 Reproductive toxicity, Category 2 H225 Highly flammable liquid and vapor H332 Harmful if inhaled H315 Causes skin irritation H319 Causes serious eye irritation H351 Suspected of causing cancer (Dermal, Inhalation, oral) H361 Suspected of damaging fertility or the unborn child (Dermal, Inhalation, oral) Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness. Specific target organ toxicity — Single exposure, Category 2 H371 brain, liver, kidneys, urinary bladder (Dermal, Inhalation, oral). Specific target organ toxicity — Repeated exposure, Category 2 H373 May cause damage to organs (brain, liver, kidneys, urinary bladder) through prolonged or repeated exposure (Dermal, Inhalation, oral) Aspiration hazard, Category 1 H304 May be fatal if swallowed and enters airways. Hazardous to the aquatic environment — Acute Hazard, Category 1 H400 Very toxic to aquatic life Full text of H statements : see section 16

2.2 Label elements

GHS US labeling

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H332 - Harmful if inhaled H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer (Dermal, Inhalation, oral). H361 - Suspected of damaging fertility or the unborn child (Dermal, Inhalation, oral) H371 - brain, liver, kidneys, urinary bladder (Dermal, Inhalation, oral). H373 - May cause damage to organs (brain, liver, kidneys, urinary bladder) through prolonged or repeated exposure (Dermal, Inhalation, oral) H400 - Very toxic to aquatic life

Precautionary statements

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. heat, hot surfaces, open flames, sparks P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment. P242 - Use non-sparking tools. P243 - Take action to prevent static discharges. P260 - Do not breathe dust, fume, mist, spray, vapors, gas. P261 - Avoid breathing dust, fume, gas, mist, spray, vapors. P264 - Wash Both hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear eye protection, face protection, protective clothing, protective gloves. P301+P310 - If swallowed: Immediately call a poison center or doctor. P302+P352 - If on skin: Wash with plenty of water. P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a poison center or doctor if you feel unwell. P314 - Get medical advice or attention if you feel unwell. P321 - Specific treatment (see Hazard pictograms (CLP) on this label). P331 - Do NOT induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice or attention. P337+P313 - If eye irritation persists: Get medical advice or attention. P362 - Take off contaminated clothing. P370+P378 - In case of fire: Use Alcohol resistant foam, Carbon dioxide, Dry chemical, Water spray to extinguish. P391 - Collect spillage. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of Comply with applicable regulations to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulations. 2.3. Hazards associated with known or reasonably anticipated uses No additional information available

2.3 Other hazards

No additional information available 2.5. Unknown acute toxicity No additional information available

2.1 Classification of the substance or mixture

GHS US classification Flammable liquids, Category 2 H225 Highly flammable liquid and vapor. Acute toxicity (inhalation:dust,mist), Category 3 H332 Harmful if inhaled. Skin corrosion/irritation, Category 2 H315 Causes skin irritation. Serious eye damage/eye irritation, Category 2A H319 Causes serious eye irritation. Carcinogenicity, Category 2 H351 Suspected of causing cancer (Dermal, Inhalation, oral). Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child (Dermal, Inhalation, oral). Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness. Specific target organ toxicity — Single exposure, Category 2 H371 brain, liver, kidneys, urinary bladder (Dermal, Inhalation, oral). Specific target organ toxicity — Repeated exposure, Category 2 H373 May cause damage to organs (brain, liver, kidneys, urinary bladder) through prolonged or repeated exposure (Dermal, Inhalation, oral). Aspiration hazard, Category 1 H304 May be fatal if swallowed and enters airways. Hazardous to the aquatic environment — Acute Hazard, Category 1 H400 Very toxic to aquatic life. Full text of H statements : see section 16