4-BROMOPHENOL UNLABELED 100 UG/ML IN TOLUENE

Hazard statements (CLP)

H225, H304, H315, H336, H361, H373, H401

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Hazard statements

see section 16 see section 16 see section 16 : H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility. Suspected of damaging the unborn child. (if inhaled, if swallowed, in contact with skin) H373 - May cause damage to organs (liver, kidneys, brain, urinary bladder) through prolonged or repeated exposure (in contact with skin, if inhaled, if swallowed) : H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility, Suspected of damaging the unborn child. (Dermal, Inhalation, oral) H373 - May cause damage to organs (kidneys, liver, urinary bladder, brain) through prolonged or repeated exposure (Dermal, Inhalation, oral) H401 - Toxic to aquatic life

EU Classification

Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F; R11 Xi; R38 Xn; R65 Repr.Cat.3; R62 Repr.Cat.3; R63 R67 N; R51/53 Xn; R48/20

Classification (GHS-US)

Flam. Liq. 2 H225 Skin Irrit. 2 H315 Repr. 2 H361 STOT SE 3 H336 STOT RE 2 H373 Asp. Tox. 1 H304 Aquatic Acute 2 H401

Adverse physicochemical, human health and environmental effects

Brain. Kidneys. Liver. Urinary bladder. Suspected of damaging fertility. Suspected of damaging the unborn child. May cause damage to organs (brain, kidneys, liver, urinary bladder) (if inhaled, if swallowed, in contact with skin). May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Causes skin irritation.

2.2 Label elements

Labeling

Hazard pictograms

GHS02 GHS08 GHS07 GHS02 GHS08 GHS07

Signal word

Danger : Danger

Hazardous Ingredients

TOLUENE UNLABELED

Precautionary statements

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment P260 - Do not breathe dust, fume, gas, mist, spray, vapors. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective clothing, protective gloves. GHS-US labeling : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe fume, mist, spray, vapors. P261 - Avoid breathing dust, fume, gas, mist, spray, vapors. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear eye protection, face protection, protective clothing, protective gloves. P301+P310 - If swallowed: Immediately call a doctor, a POISON CENTER P302+P352 - If on skin: Wash with plenty of water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a doctor, a POISON CENTER if you feel unwell P314 - Get medical advice/attention if you feel unwell. P321 - Specific treatment (see Hazardous component(s) for labeling on this label) P331 - Do NOT induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P370+P378 - In case of fire: Use alcohol resistant foam, carbon dioxide (CO2), dry extinguishing powder to extinguish. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation

PBT Substances

not relevant – no registration required