1,4-DIOXANE-D8 (P-DIOXANE) (D, 99%) 2 MG/ML IN METHANOL

Hazard statements (CLP)

H225, H301, H301+H311+H331, H311, H315, H319, H331, H351, H370

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Hazard statements

see section 16 see section 16 see section 16 : H225 - Highly flammable liquid and vapour H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H319 - Causes serious eye irritation H370 - Causes damage to organs (central nervous system, eyes, heart, kidneys, liver) (in contact with skin, if inhaled, if swallowed) : H225 - Highly flammable liquid and vapour H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H319 - Causes serious eye irritation H351 - Suspected of causing cancer (Dermal, Inhalation, oral) H370 - Causes damage to organs (eyes, liver, kidneys, heart, central nervous system) (Dermal, Inhalation, oral)

EU Classification

Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F; R11 T; R23/24/25 Xi; R36/38 Xn; R48/20

Classification (GHS-US)

Flam. Liq. 2 H225 Acute Tox. 3 (Oral) H301 Acute Tox. 3 (Dermal) H311 Acute Tox. 3 (Inhalation:vapour) H331 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Carc. 2 H351 STOT SE 1 H370

Adverse physicochemical, human health and environmental effects

Eyes, Kidney, Liver, Heart, Central nervous system. Highly flammable liquid and vapour. Causes damage to organs (eyes, kidneys, liver, heart, central nervous system) (if inhaled, if swallowed, in contact with skin). Toxic in contact with skin. Toxic if inhaled. Toxic if swallowed. Causes skin irritation. Causes serious eye irritation.

2.2 Label elements

Labeling

Hazard pictograms

GHS02 GHS08 GHS06 GHS02 GHS08 GHS06

Signal word

Danger : Danger

Precautionary statements

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment P260 - Do not breathe dust, mist, vapors, fume, gas, spray. P264 - Wash Both hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. GHS-US labeling : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, open flames, sparks. - No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe dust, fume, mist, gas, spray, vapors. P261 - Avoid breathing dust, fume, gas, spray, vapors, mist. P264 - Wash Both hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective clothing, protective gloves. P301+P310 - If swallowed: Immediately call a doctor, a POISON CENTER P302+P352 - If on skin: Wash with plenty of water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P307+P311 - If exposed: Call a poison center/doctor P308+P313 - If exposed or concerned: Get medical advice/attention. P311 - Call a doctor, a POISON CENTER P312 - Call a doctor, a POISON CENTER if you feel unwell P321 - Specific treatment (see Suitable first-aid treatment should be immediately available. on this label) P322 - Specific treatment (see Hazard pictograms (CLP) on this label) P330 - Rinse mouth. P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P361+P364 - Take off immediately all contaminated clothing and wash it before reuse. P362+P364 - Take off contaminated clothing and wash it before reuse. P370+P378 - In case of fire: Use Dry chemical, Alcohol resistant foam, Carbon dioxide. to extinguish. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to Dispose in a safe manner in accordance with local/national regulations

PBT Substances

not relevant – no registration required