1,3-DICHLOROPROPENE (D4, 98%) CIS/TRANS MIX

SECTION 2: Hazards identification

GHS US classification Classification of the substance or mixture GHS US classification Flammable liquids Category 3 Flammable liquid and vapor Acute toxicity (oral) Category 3 Toxic if swallowed Acute toxicity (dermal) Category 3 Toxic in contact with skin Acute toxicity (inhalation) Category 3 Toxic if inhaled Skin corrosion/irritation Category 2 Causes skin irritation Serious eye damage/eye irritation Category 2A Causes serious eye irritation Skin sensitization, Category 1 May cause an allergic skin reaction Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation May cause respiratory irritation Aspiration hazard Category 1 May be fatal if swallowed and enters airways Hazardous to the aquatic environment – Acute Hazard Category 1 Very toxic to aquatic life Hazardous to the aquatic environment – Chronic Hazard Category 1 Very toxic to aquatic life with long lasting effects

2.2 Label elements

GHS US labeling

Signal word

Danger

Hazard statements

Flammable liquid and vapor Toxic if swallowed, in contact with skin or if inhaled May be fatal if swallowed and enters airways Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation May cause respiratory irritation Very toxic to aquatic life with long lasting effects

Precautionary statements

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. heat, hot surfaces, open flames, sparks Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust, fume, gas, mist, spray, vapors. Wash Both hands thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective clothing, protective gloves. If swallowed: Immediately call a poison center or doctor. If on skin: Wash with plenty of water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center or doctor. Call a poison center or doctor if you feel unwell. Specific treatment (see Hazard pictograms (CLP) on this label). Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off immediately all contaminated clothing. Take off contaminated clothing and wash before reuse. Take off contaminated clothing and wash it before reuse. Wash contaminated clothing before reuse. In case of fire: Use Use personal protective equipment as required. to extinguish. Collect spillage. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container to Comply with applicable regulations.

Other hazards which do not result in classification

No additional information available

Ingredient(s) with unknown acute toxicity

Not applicable

2.1 Classification of the substance or mixture

GHS US classification Flammable liquids Category 3 Flammable liquid and vapor Acute toxicity (oral) Category 3 Toxic if swallowed Acute toxicity (dermal) Category 3 Toxic in contact with skin Acute toxicity (inhalation) Category 3 Toxic if inhaled Skin corrosion/irritation Category 2 Causes skin irritation Serious eye damage/eye irritation Category 2A Causes serious eye irritation Skin sensitization, Category 1 May cause an allergic skin reaction Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation May cause respiratory irritation Aspiration hazard Category 1 May be fatal if swallowed and enters airways Hazardous to the aquatic environment – Acute Hazard Category 1 Very toxic to aquatic life Hazardous to the aquatic environment – Chronic Hazard Category 1 Very toxic to aquatic life with long lasting effects