10% TMS IN METHANOL

Hazard statements (CLP)

H225, H301, H301+H311+H331, H311, H315, H319, H331, H373

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Hazard statements

see section 16 see section 16 see section 16 : H225 - Highly flammable liquid and vapor H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H319 - Causes serious eye irritation H373 - May cause damage to organs (central nervous system, eyes, heart, kidneys, liver) through prolonged or repeated exposure (in contact with skin, if inhaled, if swallowed) : H225 - Highly flammable liquid and vapor H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H319 - Causes serious eye irritation H373 - May cause damage to organs (central nervous system, eyes, heart, kidneys, liver) through prolonged or repeated exposure (Dermal, Inhalation, oral)

EU Classification

Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F; R11 T+; R27 T; R48/23/24/25 Xi; R36/38

Classification (GHS-US)

Flam. Liq. 2 H225 Acute Tox. 3 (Oral) H301 Acute Tox. 3 (Dermal) H311 Acute Tox. 3 (Inhalation:vapour) H331 Skin Irrit. 2 H315 Eye Irrit. 2A H319 STOT RE 2 H373

Adverse physicochemical, human health and environmental effects

Highly flammable liquid and vapor. May cause damage to organs (eyes, kidneys, liver, heart, central nervous system) through prolonged or repeated exposure (if inhaled, if swallowed, inhalation, in contact with skin). Toxic in contact with skin. Toxic if inhaled. Toxic if swallowed. Causes skin irritation. Causes serious eye irritation.

2.2 Label elements

Labeling

Hazard pictograms

GHS02 GHS08 GHS06 GHS02 GHS08 GHS06

Signal word

Danger : Danger

Precautionary statements

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P260 - Do not breathe dust, mist, vapors, fume, gas, spray P264 - Wash Both hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area GHS-US labeling : P210 - Keep away from heat, open flames, sparks. - No smoking P233 - Keep container tightly closed P240 - Ground/Bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P260 - Do not breathe dust, fume, mist, gas, spray, vapors P261 - Avoid breathing dust, fume, gas, spray, vapors, mist P264 - Wash Both hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective clothing, protective gloves P301+P310 - If swallowed: Immediately call a doctor, a POISON CENTER P302+P352 - If on skin: Wash with plenty of water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P311 - Call a doctor, a POISON CENTER P312 - Call a doctor, a POISON CENTER if you feel unwell P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment (see Suitable first-aid treatment should be immediately available. on this label) P322 - Specific treatment (see Hazard pictograms (CLP) on this label) P330 - Rinse mouth P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P361+P364 - Take off immediately all contaminated clothing and wash it before reuse P362+P364 - Take off contaminated clothing and wash it before reuse P370+P378 - In case of fire: Use Dry chemical, Alcohol resistant foam, Carbon dioxide. to extinguish P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to Dispose in a safe manner in accordance with local/national regulations

PBT Substances

not relevant – no registration required