P11846 | Eruca Sativa Extract 4:1

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture Classification according to

Hazard pictograms

Not Applicable

Signal word

NOT APPLICABLE

Hazard statements

Not Applicable

Supplemental label elements

Not Applicable

Prevention

Not Applicable

Response

Not Applicable

Storage

Not Applicable

Disposal

Not Applicable

2.3 Other hazards

Cumulative effects may result following exposure*. REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

2.1 Classification of the substance or mixture

Classification according to regulation (EC) No 1272/2008 Not Applicable [CLP] [1] 2.2. Label elements Hazard pictogram(s) Not Applicable SIGNAL WORD NOT APPLICABLE Hazard statement(s) Not Applicable Supplementary statement(s) Not Applicable Precautionary statement(s) Prevention Not Applicable Precautionary statement(s) Response Not Applicable Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal Not Applicable 2.3. Other hazards Cumulative effects may result following exposure*. REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS 3.1.Substances 1.CAS No 2.EC No %[weight] Name Classification according to regulation (EC) No 1272/2008 [CLP] 3.Index No 4.REACH No 1.Not Available 2.Not Available 92 Eruca Sativa Extract Not Applicable 3.Not Available 4.Not Available 1.9050-36-6 2.232-940-4 8 maltodextrin Not Applicable 3.Not Available 4.Not Available Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from C&L; * EU IOELVs available 3.2.Mixtures See 'Information on ingredients' in section 3.1 SECTION 4 FIRST AID MEASURES 4.1. Description of first aid measures Eye Contact Generally not applicable. Skin Contact Generally not applicable. Inhalation Generally not applicable. Ingestion Generally not applicable. 4.2 Most important symptoms and effects, both acute and delayed See Section 11 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 FIREFIGHTING MEASURES 5.1. Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. 5.2. Special hazards arising from the substrate or mixture Fire Incompatibility None known. 5.3. Advice for firefighters Fire Fighting Slight hazard when exposed to heat, flame and oxidisers. For starch/ air mixtures Starch is a class St1 dust at normal moisture level: Minimum Ignition Temperature (MIE): >30 mJ at normal moisture level Pmax 9.5 Bar Fire/Explosion Hazard Kst 170 bar.m/s Layer Ignition Temperature: >450 deg C Autoignition Temperature: 170 deg C (above this temperature starch will self-heat) Dust Explosion Hazard Class 1 Dusts fall into one of three Kst* classes. Class 1 dusts; Kst 1-200 m3/sec; Class 2 dusts; 201-299 m3/sec. Class 3 dusts; Kst 300 or more. Most agricultural dusts (grains, flour etc.) are Class 1; pharmaceuticals and other speciality chemicals are typically Class 1 or 2; most unoxidised metallic dusts are Class 3. The higher the Kst, the more energetically the dust will burn and the greater is the explosion risk and the greater is the speed of the explosion.. Standard test conditions, used to derive the Kst, are representative of industrial conditions, but do not represent and absolute worst case. Increased levels of turbulence increase the speed of the explosion dramatically. * Kst - a normalised expression of the burning dust pressure rise rate over time. Dusts with Minimum Ignition Energies (MIEs) ranging between 20 and 100 mJ may be sensitive to ignition. They require that: · plant is grounded · personnel might also need to be grounded · the use of high resistivity materials (such as plastics) should be restricted or avoided during handling or in packaging The majority of ignition accidents occur within or below this range. The MIE of a dust/air mix depends on the particle size the water content and the temperature of the dust. The finer and the dryer the dust the lower the MIE. Higher temperatures cause lower MIE and an increased risk of dust explosion. Quoted values for MIE generally are only representative. Characteristics may change depending upon the process and conditions of use or any changes made to the dust during use, including further grinding or mixing with other products. In order to obtain more specific data for dust, as used, it is recommended that further characterisation testing.is performed. Articles and manufactured articles may constitute a fire hazard where polymers form their outer layers or where combustible packaging remains in place. Certain substances, found throughout their construction, may degrade or become volatile when heated to high temperatures. This may create a secondary hazard. SECTION 6 ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures See section 8 6.2. Environmental precautions See section 12 6.3. Methods and material for containment and cleaning up Clean up all spills immediately. Minor Spills Secure load if safe to do so. Bundle/collect recoverable product. Collect remaining material in containers with covers for disposal. Minor hazard. Clear area of personnel. Alert Fire Brigade and tell them location and nature of hazard. Wear physical protective gloves e.g. Leather. Major Spills Contain spill/secure load if safe to do so. Bundle/collect recoverable product and label for recycling. Collect remaining product and place in appropriate containers for disposal. Clean up/sweep up area. Water may be required. 6.4. Reference to other sections Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 HANDLING AND STORAGE 7.1. Precautions for safe handling Limit all unnecessary personal contact. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Safe handling Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained. Fire and explosion protection See section 5 Other information Store away from incompatible materials. 7.2. Conditions for safe storage, including any incompatibilities Generally packaging as originally supplied with the article or manufactured item is sufficient to protect against physical hazards. Suitable container If repackaging is required ensure the article is intact and does not show signs of wear. As far as is practicably possible, reuse the original packaging or something providing a similar level of protection to both the article and the handler. Avoid contamination of water, foodstuffs, feed or seed. Reducing sugar-based material. Storage incompatibility Autooxidation of reducing sugars may produce up to 3000 ppm carbon monoxide under moderately alkaline conditions. High pH aqueous solutions of saccharides (aldoses, ketoses) or polysaccharides based on these sugars may generate hazardous atmospheres in confined spaces. Reducing sugars contain an aldehyde or free hemiacetal in the open-chain form. Sugars with ketone groups in their open chain form are capable of isomerising via a series of tautomeric shifts to produce an aldehyde group in solution. Therefore, ketone-bearing sugars like fructose are considered reducing sugars but it is the isomer containing an aldehyde group which is reducing since ketones cannot be oxidized without decomposition of the sugar. Many disaccharides, like lactose and maltose, also have a reducing form, as one of the two units may have an open-chain form with an aldehyde group. However, sucrose and trehalose, in which the anomeric carbons of the two units are linked together, are non-reducing disaccharides since neither of the rings is capable of opening. In glucose polymers such as starch and starch-derivatives like glucose syrup, maltodextrin and dextrin the macromolecule begins with a reducing sugar, a free aldehyde. More hydrolysed starch contains more reducing sugars. The percentage of reducing sugars present in these starch derivatives is called dextrose equivalent (DE). Dilute solutions of all sugars are subject to fermentation, either by yeast or by other microorganisms or enzymes derived from these, producing gases which can pressurise and burst sealed containers. Some microorganisms will produce hydrogen or methane, adding a fire and explosion hazard. None known 7.3. Specific end use(s) See section 1.2 SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1. Control parameters DERIVED NO EFFECT LEVEL (DNEL) Not Available PREDICTED NO EFFECT LEVEL (PNEC) Not Available OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes Not Available EMERGENCY LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 P11846 | Eruca Sativa Extract 4:1 Not Available Ingredient Original IDLH Revised IDLH Eruca Sativa Extract Not Available maltodextrin Not Available Not Available 8.2. Exposure controls Articles or manufactured items, in their original condition, generally don't require engineering controls during handling or in normal use. Exceptions may arise following extensive use and subsequent wear, during recycling or disposal operations where substances, found in the article, may be released to the environment. Assess operations based upon available dust explosion information to determine the suitability of preventative or protective systems as precautionary measures against possible dust explosions. If prevention is not possible, consider protection by use of containment, venting or suppression of dust handling 8.2.1. Appropriate engineering equipment. Where explosion venting is considered to be the most appropriate method of protection, vent areas should preferably be calculated based on Kst rather than an St value. If nitrogen purging is considered as the protective system, it must operate with an oxygen level below the limiting oxygen controls concentration. The system should include an oxygen monitoring and shut-down facility in the event of excessive oxygen being detected. The maximum surface temperature of enclosures potentially exposed to this material should be based on values obtained by taking 2/3 of the minimum ignition temperature (MIE) of the dust cloud. The effect of dust layers should be reviewed. An isolated (insulated) human body can readily produce electrostatic discharges in excess of 50 mJ, but have been recorded up to 100 mJ. 8.2.2. Personal protection Safety glasses. Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent] No special equipment for minor exposure i.e. when handling small quantities. Eye and face protection OTHERWISE: Safety glasses with side shields. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent] Safety glasses with side shields Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent] Skin protection See Hand protection below Hands/feet protection Wear general protective gloves, eg. light weight rubber gloves. Body protection See Other protection below No special equipment needed when handling small quantities. OTHERWISE: Other protection Overalls. Barrier cream. Eyewash unit. Respiratory protection Not Applicable Respiratory protection not normally required due to the physical form of the product. 8.2.3. Environmental exposure controls See section 12 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Not Available Physical state article Relative density (Water = 1) Not Available Odour Not Available Partition coefficient n-octanol / Not Available water Odour threshold Not Available Auto-ignition temperature (°C) Not Available pH (as supplied) Not Available Decomposition temperature Not Available Melting point / freezing point Not Available Viscosity (cSt) Not Available (°C) Initial boiling point and boiling Not Available Molecular weight (g/mol) Not Available range (°C) Flash point (°C) Not Available Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability Not Available Oxidising properties Not Available Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm or Not Available mN/m) Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available Vapour pressure (kPa) Not Available Gas group Not Available Solubility in water (g/L) Immiscible pH as a solution (1%) Not Available Vapour density (Air = 1) Not Available VOC g/L Not Available 9.2. Other information Not Available SECTION 10 STABILITY AND REACTIVITY 10.1.Reactivity See section 7.2 10.2. Chemical stability Product is considered stable and hazardous polymerisation will not occur. 10.3. Possibility of hazardous See section 7.2 reactions 10.4. Conditions to avoid See section 7.2 10.5. Incompatible materials See section 7.2 10.6. Hazardous decomposition See section 5.3 products SECTION 11 TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Inhaled The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. Starch is generally of low toxicity. An abnormal craving for starch (amylophagia) during pregnancy has been recognized in certain areas. Ingestion The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence. Skin Contact The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Eye Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with windburn). Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by EC Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of course. Chronic Some workers may develop chronic occupational dermatitis (generally mild) through the handling of starch products. When starch is used as a lubricant in surgical gloves, small amounts, released into the patient during the course of surgery, have resulted in granulomas and peritonitis. TOXICITY IRRITATION 4:1 Not Available TOXICITY