CRL FREEZ-IT SPRAY PROPELLENT

Hazard statements (CLP)

H222, H229

Code

Statements

H222

Extremely flammable aerosol

SECTION 2: Hazards identification

Physical hazards

Flammable aerosols

Health hazards

Not classified

Environmental hazards

Not classified

Signal word

Danger

Hazard statements

Extremely flammable aerosol.

Prevention

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use.

Response

Wash hands after handling.

Storage

Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal

Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC)

Additional information

None.

2.1 Classification of the substance or mixture

Not classified. Environmental hazards Not classified. OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Response Wash hands after handling. Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Butane 106-97-8 60 - 80 Propane 74-98-6 20 - 40 Ethyl Alcohol 64-17-5 2.5-10 Other components below reportable levels 0.01 - 0.1 #: This substance has workplace exposure limit(s). *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Get medical attention if symptoms persist. Product #: 1000011274 Version#:01 Issue date: 09-17-2015 Page 1 of 9 $DS81142_Cat. No.FNB8_1/16 <n. Skin contact Rinse skin with water/shower. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Ingestion In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Most important Dizziness. Direct contact with eyes may cause temporary irritation. symptoms/effects, acute and delayed Indication of immediate Provide general supportive measures and treat symptomatically. medical attention and special treatment needed General information Take off all contaminated clothing immediately. 5. Fire-fighting measures Suitable extinguishing media Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Contents under pressure. Pressurized container may explode when exposed to heat or flame. the chemical Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting Move containers from fire area if you can do so without risk. Containers should be cooled with equipment/instructions water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). emergency procedures Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no containment and cleaning up smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Scoop up used absorbent into drums or other appropriate container. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not re-use empty containers. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, Level 3 Aerosol. including any incompatibilities Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in original tightly closed container. Refrigeration recommended. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS). Level 3 Aerosol. Page 2 of 9 <n 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Ethyl Alcohol (CAS 64-17-5) PEL 1900 mg/m3 1000 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3 1000 ppm US. ACGIH Threshold Limit Values Components Type Value Butane (CAS 106-97-8) STEL 1000 ppm Ethyl Alcohol (CAS 64-17-5) STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Butane (CAS 106-97-8) TWA 1900 mg/m3 800 ppm Ethyl Alcohol (CAS 64-17-5) TWA 1900 mg/m3 1000 ppm Propane (CAS 74-98-6) TWA 1800 mg/m3 1000 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Explosion-proof general and local exhaust ventilation. controls Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Wear appropriate chemical resistant clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene When using do not smoke. Always observe good personal hygiene measures, such as washing considerations after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Clear colorless Odor Fruity Odor threshold Not available. pH Not applicable estimated Melting point/freezing point Not available. Initial boiling point and boiling 8.82°F (-12.88°C) estimated range Flash point -156.0°F (-104.4°C) Propellant estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower 4.3% estimated (%) Page 3 of 9 <n Flammability limit - upper Not available. (%) Explosive limit