Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
50 - < 75
General Information
Revision date
2021-12-02
Product name
HF Modellkunststoff Komponente B
Product Synonyms
or synonyms
REACH No
not
supplier name
Country
Icons in SDS
Company Information
company name
C.HAFNER GmbH + Co. KG
e-mail address of the competent person responsible for the Safety Data Sheet
michael.huber@c-hafner.de, Michael.huber@c-hafner.de
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H304, H315, H317, H319, H332, H334, H335, H351, H373, H400, H410
Hazard statements
Code
Statements
H304
May be fatal if swallowed and enters airways
Section 2
CLP CLASSIFICATION
Section
Hazard categories
Cat- Hazard class and Hazard state- egory category ment 3.1I acute toxicity (inhal.) 4 Acute Tox. 4 H332 3.2 skin corrosion/irritation 2 Skin Irrit. 2 H315 3.3 serious eye damage/eye irritation 2 Eye Irrit. 2 H319 3.4R respiratory sensitisation 1 Resp. Sens. 1 H334 3.4S skin sensitisation 1 Skin Sens. 1 H317 3.6 carcinogenicity 2 Carc. 2 H351 3.8R specific target organ toxicity - single exposure (respiratory 3 STOT SE 3 H335 tract irritation) 3.9 specific target organ toxicity - repeated exposure 2 STOT RE 2 H373 3.10
Aspiration hazard
1 Asp. Tox. 1 H304 4.1A hazardous to the aquatic environment - acute hazard 1 Aquatic Acute 1 H400 4.1C hazardous to the aquatic environment - chronic hazard 1 Aquatic Chronic 1 H410 For full text of abbreviations: see SECTION 16.
Most important adverse effects
Delayed or immediate effects can be expected after short or long-term exposure. Spillage and fire water can cause pollution of watercourses.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 (CLP)
Signal word
danger
Hazard pictograms
GHS07, GHS08, GHS09
Hazard statements
H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protec- tion/…. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Supplemental label elements
EUH204 Contains isocyanates. May produce an allergic reaction.
Hazardous Ingredients
4,4'-methylenediphenyl diisocyanate, Bis(isopro- pyl)naphthalene
2.3 Other hazards
There is no additional information.