BELLACIDE 301

Hazard statements (CLP)

H302, H373

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

GHS Classification Acute toxicity (Oral) Category 4 Specific target organ toxicity Category 2 (Kidney) repeated exposure

Signal word

Warning

Hazard statements

H302 Harmful if swallowed. H373 May cause damage to organs through prolonged or re- peated exposure.

Prevention

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P314 Get medical advice/ attention if you feel unwell.

Disposal

P501 Dispose of contents/ container to an approved waste dis- SDS Number: 100000003103 1 / 11 ETHYLENE GLYCOL ETHYLENE GLYCOL Version 1.12 Msds revision date 07/14/2022 posal plant.

Other hazards

None known

2.1 Classification of the substance or mixture

Specific target organ toxicity : Category 2 (Kidney) - repeated exposure GHS label elements Hazard pictograms : Signal word : Warning Hazard statements : H302 Harmful if swallowed. H373 May cause damage to organs through prolonged or re- peated exposure. Precautionary statements : Prevention: P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P314 Get medical advice/ attention if you feel unwell. Disposal: P501 Dispose of contents/ container to an approved waste dis- SDS Number: 100000003103 1 / 11 ETHYLENE GLYCOL ETHYLENE GLYCOL Version 1.12 Revision Date: 07/14/2022 posal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Substance Hazardous components CAS-No. Chemical name Weight percent 107-21-1 Ethylene glycol 90 - 100 111-46-6 Diethylene glycol 0 - 5 Any Concentration shown as a range is due to batch variation. Synonyms : Ethylene glycol Industrial/Ethylene glycol Meglob- al/Glycol/Solv Ethylene glycol, SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Wash off with soap and water. Wash clothing before reuse. If skin irritation persists, call a physician. In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Do not induce vomiting without medical advice. Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Foam Dry chemical SDS Number: 100000003103 2 / 11 ETHYLENE GLYCOL ETHYLENE GLYCOL Version 1.12 Revision Date: 07/14/2022 Carbon dioxide (CO2) Unsuitable extinguishing : High volume water jet media Specific hazards during fire- : Do not allow run-off from fire fighting to enter drains or water fighting courses. Hazardous combustion prod- : Carbon oxides ucts toxic fumes Further information : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local cir- cumstances and the surrounding environment. Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec- for firefighters essary. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel, containment and cleaning up acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against : Normal measures for preventive fire protection. fire and explosion Advice on safe handling : Do not breathe vapours/dust. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the ap- plication area. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters SDS Number: 100000003103 3 / 11 ETHYLENE GLYCOL ETHYLENE GLYCOL Version 1.12 Revision Date: 07/14/2022 CAS-No. Components Value type Control parame- Basis (Form of ters / Permissible exposure) concentration 107-21-1 Ethylene glycol C 50 ppm OSHA P0 125 mg/m3 C 100 mg/m3 ACGIH TWA (Vapour) 25 ppm ACGIH STEL (Va- 50 ppm ACGIH pour) STEL (Inhala- 10 mg/m3 ACGIH ble fraction, Aerosol only) C (Vapour) 40 ppm CAL PEL 100 mg/m3 111-46-6 Diethylene glycol TWA 10 mg/m3 US WEEL Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are un- known, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respi- rator if there is any potential for uncontrolled release, expo- sure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Skin and body protection : Impervious clothing Choose body protection according to the amount and concen- tration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : Clear, Colorless Odour : sweet, slight SDS Number: 100000003103 4 / 11 ETHYLENE GLYCOL ETHYLENE GLYCOL Version 1.12 Revision Date: 07/14/2022 Odour Threshold : No data available pH : 9 Freezing Point (Melting : -13 - -11.2 °C (9 - 11.8 °F) point/freezing point) Boiling Point (Boiling : 197.4 °C (387.3 °F) point/boiling range) Flash point : 111 - 116 °C (232 - 241 °F) Method: closed cup Evaporation rate : 0.01 (Butyl Acetate = 1) Flammability (solid, gas) : No data available Upper explosion limit : 22 %(V) Lower explosion limit : 1.8 %(V) Vapour pressure : < 1 hPa @ 20 - 25 °C (68 - 77 °F) Relative vapour density : < 2.14 @ 20 - 25 °C (68 - 77 °F) (Air = 1.0) Relative density : 1.115 @ 20 °C (68 °F) Reference substance: (water = 1) Density : 1.11 g/cm3 @ 20 °C (68 °F) Solubility(ies) Water solubility : soluble Solubility in other solvents : No data available Partition coefficient: n- : log Pow: -1.36 octanol/water Auto-ignition temperature : 398 °C Thermal decomposition : No data available Viscosity Viscosity, dynamic : 19.83 - 21 mPa.s @ 20 - 25 °C (68 - 77 °F) Viscosity, kinematic : 145 mm2/s @ 25 °C (77 °F) SECTION 10. STABILITY AND REACTIVITY SDS Number: 100000003103 5 / 11 ETHYLENE GLYCOL ETHYLENE GLYCOL Version 1.12 Revision Date: 07/14/2022 Reactivity : Stable under recommended storage conditions. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- : No hazards to be specially mentioned. tions Conditions to avoid : Keep away from heat, flame, sparks and other ignition sources. Incompatible materials : Strong bases Strong oxidizing agents Strong acids Aldehydes Aluminium Plastics Reducing agents Peroxides Hazardous decomposition : Aldehydes products Ketones Organic acids Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute oral toxicity : Acute toxicity estimate: 489.08 mg/kg Components: 107-21-1: Acute oral toxicity : Assessment: The component/mixture is moderately toxic after single ingestion. 111-46-6: Acute oral toxicity : LD50 (Human): Calculated 1,120 mg/kg Assessment: The component/mixture is moderately toxic after single ingestion. Carcinogenicity IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens. SDS Number: 100000003103 6 / 11 ETHYLENE GLYCOL ETHYLENE GLYCOL Version 1.12 Revision Date: 07/14/2022 NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. STOT - repeated exposure Components: 107-21-1: Target Organs: Kidney Assessment: The substance or mixture is classified as specific target organ toxicant, repeated exposure, category 2. Further information Product: Remarks: No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity No data available Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro- tection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufac- tured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological infor- : No data available mation SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods SDS Number: 100000003103 7 / 11 ETHYLENE GLYCOL ETHYLENE GLYCOL Version 1.12 Revision Date: 07/14/2022 Waste from residues : Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Uni- var Solutions ChemCare: 1-800-637-7922 Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION DOT (Department of Transportation): UN3082, Environmentally hazardous substances, liquid, n.o.s., (ETHYLENE GLYCOL), 9, III IATA (International Air Transport Association): Not regulated as a dangerous good IMDG-Code: Not regulated as a dangerous good Special Notes: : This material is shipped as a Class 9, Packing Group III when each package meets or exceeds the reportable quantity, oth- erwise it may be shipped as not regulated. SECTION 15. REGULATORY INFORMATION WHMIS Classification : Not controlled. EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ Calculated product RQ (lbs) Ethylene glycol 107-21-1 5000 1,4-Dioxane 123-91-1 100 111234 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute toxicity (any route of exposure) Specific target organ toxicity (single or repeated exposure) SARA 302 : No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 : The following components are subject to reporting levels es- tablished by SARA Title III, Section 313: 107-21-1 Ethylene glycol SDS Number: 100000003103 8 / 11 ETHYLENE GLYCOL ETHYLENE GLYCOL Version 1.12 Revision Date: 07/14/2022 Clean Air Act The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR 61): 107-21-1 Ethylene glycol This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): 107-21-1 Ethylene glycol 111-46-6 Diethylene glycol Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A: 75-07-0 Acetaldehyde The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: 75-07-0 Acetaldehyde This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know 107-21-1 Ethylene glycol 123-91-1 1,4-Dioxane