see item 16.5

BUZZI UNICEM S.p.A

Revision date : 2015-01-06

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GHS05 GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

General Information

Revision date

2015-01-06

Product name

see item 16.5

1.2.1 Relevant identified uses

The Premiscelato is mixed with water and used as both finishing and smoothing plaster in building applications and as mortar for walls and paving blocks

Manufacturer Name

Professional

Icons in SDS

Company Information

company name

BUZZI UNICEM S.p.A

e-mail address of the competent person responsible for the Safety Data Sheet

reach@buzziunicem.it

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H318, H335

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

2.1 Classification of the substance or mixture

According to (EC) Regulation no. 1272/2008 (CLP)

Hazard statements

category Skin irritation 2 H315: Causes skin irritation Serious eye damage/eye irritation 1 H318: Causes serious eye damage H317: May cause an allergic skin Skin sensitisation 1B reaction Specific target organ toxicity (single exposure) - H335: May cause respiratory 3 STOT SE, respiratory tract irritation irritation H318: causes serious damage to eyes H315: causes skin irritation H317: may cause an allergic skin reaction H335: can cause respiratory irritation

2.2 Label elements

According to Regulation (EC) No. 1272/2008 (CLP) Warnings Danger

Precautionary statements

P102: Keep out of reach of children. P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+ IN CASE OF CONTACT WITH EYES: rinse with water for several minutes. P338+P312: Remove contact lenses, if it can be done easily; continue flushing; If you feel unwell, contact a POISON CENTER or a doctor. P302+P352+ IN CASE OF CONTACT WITH SKIN: wash with plenty of soap and water; P333+P313: in case of skin irritation or rash, consult a doctor. P261+P304+ Avoid breathing in the dust. IN CASE OF INHALATION: Remove victim to fresh P340+P312: air and keep still in a position comfortable for breathing. If you feel unwell, contact a POISON CENTER or a doctor. P501: Dispose of the product/container in compliance with regulations in force. 2

2.3 Other hazards

When the mixture is mixed with water, for example during production of plasters or mortars, or when it gets wet, it produces a strong alkaline solution (high pH due to the formation of calcium, sodium and potassium hydroxides). Repeated inhalation of the powder mixture, for a long period of time, increases the risk of the onset of lung diseases. Some special formulations may contain a percentage of free crystalline silica, which requires the implementation of suitable technical-organisational measures and the systematic monitoring of occupational exposure (for additional information, see item 15.1). Repeated and prolonged contact between the mixture and/or its paste on wet skin (due to perspiration or humidity) may cause irritation and/or dermatitis [Reference (4)]. In case of prolonged contact with the skin, both the mixture and its paste can cause sensitisation and/or allergic reaction in some individuals, due to the presence of traces of Chromium VI salts; if necessary, this effect can be mitigated by adding a specific reducing agent to keep the content of soluble chromium VI in concentrations of less than 0.0002% (2 ppm) of the total dry weight, in compliance with the regulatory provisions referred to in item 15.1 [Reference (3)]. If swallowed in significant quantity, the mixture may cause ulcerations of the digestive system. Under normal conditions of use, the mixture and its paste do not present any particular risks for the environment, save for compliance with the recommendations provided in items 6, 8, 12 and 13 below. The mixture does not meet the criteria for PBT or vPvB, pursuant to Annex XIII of Regulation 1907/2006/EC, known as “REACH”.

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