Oil Well Cement, conforming to standard ISO 10426-1/API Spec 10 A

BUZZI UNICEM S.p.A

Revision date : 2018-08-09

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GHS05 GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

General Information

Revision date

2018-08-09

Product name

Oil Well Cement, conforming to standard ISO 10426-1/API Spec 10 A

CAS No.

65997-15-1

1.2.1 Relevant identified uses

The cement is used as a hydraulic binder for the manufacture of concrete, hydraulic mortar, plaster, etc

Manufacturer Name

Professional

Icons in SDS

GHS05 GHS07

Company Information

company name

BUZZI UNICEM S.p.A

e-mail address of the competent person responsible for the Safety Data Sheet

reach@buzziunicem.it

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H318, H335

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 [CLP]]

2.1 Classification of the substance or mixture

In accordance with Regulation (EC) No. 1272/2008 (CLP)

Hazard categories

Risk phases Category Skin irritation 2 H315: causes skin irritation Serious eye damage / irritation 1 H318: causes serious eye damage H317: may cause an allergic skin Skin sensitisation 1B reaction Specific toxicity for target organs (single exposure) - H335: may cause respiratory 3 STOT SE, respiratory irritation irritation

2.2 Label elements

In accordance with Regulation (EC) No. 1272/2008 (CLP) Warnings Risk phases H318: causes serious eye damage H315: causes skin irritation H317: may cause an allergic skin reaction H335: may cause respiratory irritation Safety phases P102: keep out of reach of children P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+ IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses P338+P312: if present and easy to do – continue rinsing. If you feel unwell, call a Poison Centre or doctor. . 2 P302+P352+ IF ON SKIN: wash with plenty of soap and water; if skin irritation or rash occurs: P333+P313: Get medical advice/attention. P261+P304+ Avoid breathing the dust. IF INHALED: Remove person to fresh air and keep P340+P312: comfortable for breathing If you feel unwell, call a Poison Centre or doctor. P501: dispose of product/containers in accordance with current regulations.

2.3 Other hazards

In the presence of water, for example when manufacturing concrete or mortar, or when it gets wet, the cement produces a strong alkaline solution (high pH due to the formation of hydroxides of calcium, sodium and potassium). Frequent inhalation of cement dust over a long period of time increases the risk of developing lung diseases (above all, for repeated and prolonged exposure to dust by some types of cement-based mixtures containing siliceous components – for more details, see Subsection 15.1). Repeated and prolonged contact of cement and/or its pastes on moist skin (due to sweat or humidity) may cause irritation and contact dermatitis [Reference (4)]. Both cement and cement pastes, in case of prolonged contact with the skin, may cause sensitisation due to the presence of trace amounts of chromium (VI) salts; if necessary, this effect can be diminished by adding a specific reducing agent to keep the level of sensitising soluble chromium (VI) below the limit of 0.0002% (2 ppm) of the total dry weight of the ready-to-use cement, according to the legislation specified under Section 15.1 [Reference (3)]. If large amounts are ingested, cement may cause ulcerations of the digestive system. Under normal conditions of use, cements and cement pastes do not pose particular risks to the environment, as long as the recommendations provided in Sections 6, 8, 12 and 13 are followed. The cement does not meet the criteria for PBT or vPvB, in accordance with Annex XIII of Regulation (EC) No. 1907/2006 “REACH”.

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