BAS 16 CARIBBEAN SEA

Hazardous Ingredients

OSHA THE PRECISE COMPOSITION OF THIS PRODUCT IS PROPRIETARY INFORMATION. A MORE COMPLETE DISCLOSURE CAN BE PROVIDED IN THE EVENT OF A MEDICAL EMERGENCY. INGREDIENTS (CAS #) PERCENT BY WEIGHT* ACGIH/TLV OSHA/PEL CUPRIC CHLORIDE (7447-39-4) MINOR 1 mg / m³ 1 mg / mg³ PHOSPHORIC ACID (7664-38-2) MINOR 1 mg / mg³ 3 mg / mg³ WATER (7732-18-5) MAJOR NOT ESTAB. * MAJOR = OVER 25% , MINOR = 6 – 25% , TRACE = UNDER 6% , RESIDUE = UNKNOWN % RESIDUE POSSIBLE SECTION III FIRE AND EXPLOSION HAZARD DATA

Acute Health Hazards

EFFECTS OF OVEREXPOSURE ACUTE INGESTION: EXPOSURE MAY BE HARMFUL OR FATAL. SYMPTOMS MAY INCLUDE SEVERE STOMACH AND INTESTINAL IRRITATION ( NAUSEA, VOMITING, DIARRHEA ) , ABDOMINAL PAIN, AND VOMITING OF BLOOD. INGESTING THIS MATERIAL MAY CAUSE BURNS AND DESTROY TISSUE IN THE MOUTH, THROAT, AND DIGESTIVE TRACT. LOW BLOOD PRESSURE AND SHOCK MAY OCCUR AS A RESULT OF SEVERE TISSUE INJURY. INHALATION: EXPOSURE TO VAPOR OR MIST IS POSSIBLE. EXPOSURE MAY BE HARMFUL OR FATAL. SYMPTOMS MAY INCLUDE SEVERE IRRITATION AND BURNS TO THE NOSE, THROAT, AND RESPIRATORY TRACT. SKIN ABSORPTION: EXPOSURE CAUSES IRREVERSIBLE SKIN DAMAGE. SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BURNS, AND SEVERE SKIN DAMAGE. EYE CONTACT: EXPOSURE CAUSES IRREVERSIBLE EYE DAMAGE. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, CORNEAL DAMAGE, AND BLINDNESS.

Principle Routes of Exposure

INHALATION AND SKIN CONTACT CHRONIC NO SPECIFIC INFORMATION AVAILABLE. EMERGENCY AND FIRST AID PROCEDURES: EYE CONTACT: IF MATERIALS GET INTO THE EYES, IMMEDIATELY FLUSH EYES GENTLY WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS APART. IF SYMPTOMS DEVELOP AS A RESULT OF VAPOR EXPOSURE, IMMEDIATELY MOVE INDIVIDUAL AWAY FROM EXPOSURE AND INTO FRESH AIR BEFORE FLUSHING AS RECOMMENDED ABOVE. SEEK IMMEDIATE MEDICAL ATTENTION. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. FLUSH EXPOSED AREA WITH LARGE AMOUNTS OF WATER. IF SKIN IS DAMAGED, SEEK IMMEDIATE MEDICAL ATTENTION. IF SKIN IS NOT DAMAGED AND SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. LAUNDER CLOTHING BEFORE REUSE. INGESTION: SEEK IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING. VOMITING WILL CAUSE FURTHER DAMAGE TO THE MOUTH AND THROAT. IF INDIVIDUAL IS CONSCIOUS AND ALERT, IMMEDIATELY RINSE MOUTH WITH WATER AND GIVE MILK OR WATER TO DRINK. IF POSSIBLE, DO NOT LEAVE INDIVIDUAL UNATTENDED. INHALATION: IF SYMPTOMS DEVELOP, IMMEDIATELY MOVE INDIVIDUAL AWAY FROM EXPOSURE AND INTO FRESH AIR. SEEK IMMEDIATE MEDICAL ATTENTION; KEEP PERSON WARM AND QUIET. IF PERSON IS NOT BREATHING, BEGIN ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. SECTION V REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT ( PROPOSITION 65 ) THIS PRODUCT IS KNOWN TO CONTAIN CHEMICALS CURRENTLY LISTED AS CARCINOGENS OR REPRODUCTIVE TOXINS UNDER

Further information

ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY SECTION VI REACTIVITY DATA STABILITY: STABLE. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. CONDITIONS TO AVOID: AVOID CONTACT WITH STRONG ALKALIES , ALKALI METALS. MATERIALS TO AVOID: SEE ABOVE HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF PHOSPHORUS. SECTION VII SPILL OR LEAK PROCEDURE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SHOVEL OR SOAK UP SPILLED MATERIAL INTO A PLASTIC CONTAINER AND REUSE OR REMOVE TO APPROVED CHEMICAL WASTE DISPOSAL AREA. FLUSH AREA WITH WATER , DIRECTING RUNOFF TO APPROPRIATE TREATMENT OR DISPOSAL CONTAINER. NEVER FLUSH TO SEWER. MAJOR SPILLS SHOULD BE REPORTED ACCORDING TO REGULATIONS. WASTE DISPOSAL METHOD: DISPOSE OF WASTE IN ACCORDANCE WITH FEDERAL , STATE AND LOCAL REGULATIONS. SECTION VIII SAFE HANDLING AND USE INFORMATION RESPIRATORY PROTECTION: WHENEVER EXPOSURE TO VAPOR/MIST IS LIKELY UNLESS LEVELS ARE BELOW APPLICABLE LIMITS, WEAR A PROPERLY FITTED NIOSH/MSHA APPROVED RESPIRATOR. FOR EMERGENCIES, A SELF-CONTAINED BREATHING APPARATUS OR FULL FACE RESPIRATOR IS RECOMMENDED. VENTILATION: VENTILATION MUST BE SUFFICIENT TO CONTROL VAPORS. BREATHING OF VAPORS MUST BE AVOIDED. THIS MATERIAL SHOULD BE CONFINED AS FAR AS POSSIBLE WITHIN SEALED OR COVERED EQUIPMENT IN WHICH CASE NORMAL VENTILATION SHOULD BE ADEQUATE . SPECIAL ( LOCAL ) VENTILATION WILL BE NEEDED IN AREAS WHERE VAPORS ARE EXPECTED TO BE VENTED. PROTECTIVE GLOVES IMPERVIOUS GLOVES , NEOPRENE OR RUBBER . EYE PROTECTION SAFETY EYEWEAR INCLUDING SPLASH GUARDS OR SIDE SHIELDS , CHEMICAL GOGGLES , OR FACE SHIELDS . OTHER PROTECTIVE EQUIPMENT CLEAN , BODY COVERING CLOTHING . FURTHER SAFETY EQUIPMENT ( APRON , FOOTWEAR , ETC . ) SHOULD BE USED AS NECESSARY TO PREVENT CONTACT WITH MATERIAL. SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: PREVENT ALL SKIN AND EYE CONTACT. AVOID BREATHING VAPORS. RE-SEAL PARTIALLY USED CONTAINERS. ENSURE THAT ALL CONTAINERS ARE PROPERLY LABELLED TO PREVENT ACCIDENTAL INGESTION. WASH WITH SOAP AND WATER BEFORE EATING , DRINKING , SMOKING OR USING TOILET FACILITIES. OBSERVE CONDITIONS OF GOOD INDUSTRIAL HYGIENE AND SAFE WORKING PRACTICES. REMOVE AND THOROUGHLY LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED SHOES. STORE UNDER COOL , DRY CONDITIONS AND AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES. OTHER PRECAUTIONS: ADDITION TO WATER RELEASE HEAT WHICH CAN RESULT IN VIOLENT FOAMING AND SPATTERING. ALWAYS ADD SLOWLY AND IN SMALL AMOUNTS. NEVER ADD WATER TO ACIDS. ALWAYS ADD ACIDS TO WATER. CONTAINERS TO THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES ( VAPOR , LIQUID , AND/OR SOLID ) , ALL HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED. DISCLAIMER OF LIABILITY THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY , EXPRESS OR IMPLIED , REGARDING ITS CORRECTNESS. THE CONDITIONS OR METHODS OF HANDLING , STORAGE , USE AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS , WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS , DAMAGE , OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING , STORAGE , USE OR DISPOSAL OF THE PRODUCT. SUMMARY OF HMIS RATING I. HEALTH HAZARD RATING 0 MINIMAL HAZARD: NO SIGNIFICANT RISH TO HEALTH. 1 SLIGHT HAZARD: IRRITATION OR MINOR REVERSIBLE INJURY POSSIBLE. 2 TEMPORARY OR MINOR INJURY MAY OCCUR. 3 SERIOUS HAZARD: MAJOR INJURY LIKELY UNLESS PROMPT ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN. 4 SEVERE HAZARD: LIFE-THREATENING, MAJOR OR PERMANENT DAMAGE MAY RESULT FROM SINGLE OR REPEATED EXPOSURES. Date of revision April 5, 2012 Page 4 of 4 MSDS # 112 II. FLAMMABILITY HAZARD RATING 0 MINIMAL HAZARD: MATERIALS THAT ARE NORMALLY STABLE AND WILL NOT BURN UNLESS HEATED. 1 SLIGHT HAZARD: MATERIALS THAT MUST BE PREHEATED BEFORE IGNITION WILL OCCUR. FLAMMABLE LIQUIDS IN THIS CATEGORY WILL HAVE FLASH POINTS ( THE LOWEST TEMPERATURE AT WHICH IGNITION WILL OCCUR ) AT OR ABOVE 200°F ( NFPA CLASS IIIB ) . 2 MODERATE HAZARD: MATERIAL THAT MUST BE MODERATELY HEATED BEFORE IGNITION WILL OCCUR INCLUDING FLAMMABLE LIQUIDS WITH FLASH POINTS AT OR ABOVE 100°F AND BELOW 200°F ( NFPA CLASS II & CLASS IIIA ) . 3 SERIOUS HAZARD: MATERIALS CAPABLE OF IGNITION UNDER ALMOST ALL NORMAL TEMPERATURE CONDITIONS, INCLUDING FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73°F AND BOILING POINTS ABOVE 100°F AS WELL AS LIQUIDS WITH FLASH POINTS BETWEEN 73°F AND 100°F ( NFPA CLASS IB AND IC ) . 4 SEVERE HAZARD: VERY FLAMMABLE GASES OR VERY VOLATILE FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73°F AND BOILING POINTS BELOW 100°F ( NFPA CLASS IA ) . III. REACTIVITY HAZARD RATING 0 MINIMAL HAZARD: MATERIALS THAT ARE NORMALLY STABLE, EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH WATER. 1 SLIGHT HAZARD: MATERIALS THAT ARE NORMALLY STABLE BUT CAN BECOME UNSTABLE AT HIGH TEMPERATURES AND PRESSURES. THESE MATERIALS MAY REACT WITH WATER BUT THEY WILL NOT RELEASE ENERGY VIOLENTLY. 2 MODERATE HAZARD: MATERIALS THAT, IN THEMSELVES, ARE NORMALLY UNSTABLE AND WILL READILY UNDERGO VIOLENT CHEMICAL CHANGE BUT WILL NOT DETONATE. THESE MATERIALS MAY ALSO REACT VIOLENTLY WITH WATER. 3 SERIOUS HAZARD: MATERIALS THAT ARE CAPABLE OF DETONATION OR EXPLOSIVE REACTION BUT REQUIRE A STRONG INITIATING SOURCE OR MUST BE HEATED UNDER CONFINEMENT BEFORE INITIATION; OR MATERIALS THAT REACT EXPLOSIVELY WITH WATER. 4 SEVERE HAZARD: MATERIALS THAT ARE READILY CAPABLE OF DETONATION OR EXPLOSIVE DECOMPOSTION AT NORMAL