Bullet Roof GRP Roofing Topcoat

Hazard statements (CLP)

H226, H304, H315, H319, H332, H335, H361, H361d, H372, H412

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

In compliance with EC regulation No. 1272/2008 and its amendments. Flammable liquid, Category 3 (Flam. Liq. 3, H226). Skin irritation, Category 2 (Skin Irrit. 2, H315). Eye irritation, Category 2 (Eye Irrit. 2, H319). Reproductive toxicity, Category 2 (Repr. 2, H361). Specific target organ toxicity (single exposure), Category 3 (STOT SE 3, H335). Specific target organ toxicity (repeated exposure), Category 1 (STOT RE 1, H372). This mixture does not present an environmental hazard. No known or foreseeable environmental damage under standard conditions of use. In compliance with EC regulation No. 1272/2008 and its amendments. Flammable liquid, Category 3 (Flam. Liq. 3, H226). Skin irritation, Category 2 (Skin Irrit. 2, H315). Eye irritation, Category 2 (Eye Irrit. 2, H319). Reproductive toxicity, Category 2 (Repr. 2, H361). Specific target organ toxicity (single exposure), Category 3 (STOT SE 3, H335). Specific target organ toxicity (repeated exposure), Category 1 (STOT RE 1,H372). This mixture does not present an environmental hazard. No known or foreseeable environmental damage under standard conditions ofuse.

2.2 Label elements

In compliance with EC regulation No. 1272/2008 and its amendments. In compliance with EC regulation No. 1272/2008 and its amendments.

Hazard pictograms

GHS07 GHS08 GHS02 GHS07 GHS08 GHS02

Signal word

DANGER DANGER

Product definition

EC 202-851-5 STYRENE Product name : Sentinel Topcoat 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Registered company name :Principal Building Products Ltd Address : Barbot Hall Industrial Estate, Mangham Road, Rotherham S61 4RJ Telephone :01709 728150 Fax : 01709 724975 sales@pbpltd.co.uk www.pbpltd.co.uk EC 202-851-5 STYRENE

Hazard statements

H226 Flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H361d Suspected of damaging the unborn child. H372 Causes damage to organs through prolonged or repeated exposure (if inhaled). H226 Flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H361d Suspected of damaging the unborn child. H372 Causes damage to organs through prolonged or repeated exposure (if inhaled).

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/.../equipment. P242 Use only non-sparking tools. SECTION 1 : IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/.../equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. Principal Building Products Ltd, Barbot Hall Industrial Estate, Mangham Road, Rotherham, S61 P260 4RJ, Tel 01709 728150 Email sales@pbpltd.co.uk Web www.sentinelgrp.co.uk Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response

P302 + P352 IF ON SKIN: Wash with plenty of water/... P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/attention. P312 Call a POISON CENTER/doctor/.../if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see ... on this label). P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use... to extinguish. P302 + P352 IF ON SKIN: Wash with plenty of water/... P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/attention. P312 Call a POISON CENTER/doctor/.../if you feel unwell. P314 Get medical advice/attention if you feelunwell. P321 Specific treatment (see ... on this label). P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medicaladvice/attention. P362 + P364 Take off contaminated clothing and wash it beforereuse. P370 + P378 In case of fire: Use... to extinguish.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Precautionary statements

Disposal P501 Dispose of contents/container to ... Disposal P501 Dispose of contents/container to ...

2.3 Other hazards

The mixture does not contain substances classified as ‘Substances of Very High Concern' (SVHC) >= 0.1% published by the European Chemicals Agency (ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table The mixture satisfies neither the PBT nor the vPvB criteria for mixtures in accordance with annexe XIII of the REACH regulations EC 1907/2006. SECTION 3 : COMPOSITION/INFORMATION ONINGREDIENTS 3.2. Mixtures Composition : Identification (EC) 1272/2008 Note % INDEX: 471_34_1 [1] 10 <= x % < 25 CAS: 471-34-1 EC: 207-439-9 CALCIUM CARBONATE INDEX: 601_026_00_0 GHS07, GHS08, GHS02 [1] 10 <= x % < 25 CAS: 100-42-5 Dgr EC: 202-851-5 Flam. Liq. 3, H226 Asp. Tox. 1, H304 STYRENE Skin Irrit. 2, H315 Eye Irrit. 2, H319 Acute Tox. 4, H332 STOT SE 3, H335 Repr. 2, H361d STOT RE 1, H372 Aquatic Chronic 3, H412 INDEX: 13463_67_7 [1] 2.5 <= x % < 10 CAS: 13463-67-7 EC: 236-675-5 TITANIUM DIOXIDE Information on ingredients: [1] Substance for which maximum workplace exposure limits are available. P243 Take precautionary measures against staticdischarge. P260 Do not breathedust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eyeprotection/face protection.

Other hazards

The mixture does not contain substances classified as ‘Substances of Very High Concern' (SVHC) >= 0.1% published by the European Chemicals Agency (ECHA) under article 57 ofREACH: http://echa.europa.eu/fr/candidate-list-table The mixture satisfies neither the PBT nor the vPvB criteria for mixtures in accordance with annexe XIII of the REACH regulations EC 1907/2006.