BUEHLER EPOTHIN 2 HARDENER

Hazard statements (CLP)

H302+H332, H314, H335, H373, H412

Code

Statements

H302+H332

Harmful if swallowed or if inhaled

H314

Causes severe skin burns and eye damage.

H335

May cause respiratory irritation

H373

May cause damage to organs through prolonged or repeated exposure

H412

Harmful to aquatic life with long lasting effects

SECTION 2: Hazards identification

EMERGENCY OVERVIEW: DANGER! Can burn skin and eyes. Vapors are irritating to the eyes and respiratory tract. May cause allergic skin reaction. May be harmful if inhaled. Harmful or fatal if swallowed. May cause harm to the aquatic environment. Repeated or prolonged contact may cause organ damage – see Chronic Effects information. GHS LABEL INFORMATION

Hazard pictograms

50-Hrmfl+Corrsv+Env

Signal word

DANGER! HAZARD LABEL STATEMENTS: H302+H332 Harmful if swallowed or inhaled H314 Causes severe skin burns and eye damage H335 May cause respiratory irritation H373 May cause damage to organs through prolonged or repeated exposure H412 Harmful to aquatic life with long lasting effects

Precautionary statements

P260 Do not breathe mist/vapors/spray. P264 Wash all contact areas after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/eye protection/face protection (see SDS for type). P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P315 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical attention. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. P308 + P310 IF Exposed or Concerned: Immediately call a POISON CENTER or doctor. Continued ACUTE EFFECTS – INGESTION: May cause nausea and vomiting. Small amounts (a tablespoonful) swallowed during normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause injury. ACUTE EFFECTS – EYE: CORROSIVE. Can cause eye burns and permanent tissue damage. Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. ACUTE EFFECTS – ISKIN: CORROSIVE. Contact may cause burns. ACUTE EFFECTS – INHALATION: Causes respiratory tract irritation. Prolonged or excessive overexposure may cause drying and irritation of the mucous membranes with coughing shortness of breath. May be harmful if inhaled. ACUTE EFFECTS – INGESTION: May cause irritation or burns of mouth, throat, and stomach, with nausea, abdominal pain, and possible collapse. Harmful if swallowed. CHRONIC OVEREXPOSURE EFFECTS: *Preexisting pulmonary and dermatological conditions may be aggravated by exposure to hazardous components. *Triethylenetetramine (TETA) caused embryofetal toxicity and fetal malformations when fed to pregnant rats. Similar effects were not seen in studies in which this material was applied to the skin of rabbits, a more relevant route of industrial exposure. These effects are believed to be secondary to copper deficiency, resulting from the chelating activity of the amine. Carcinogenicity - Hamster-Oral: Tumorigenic/Neoplastic by RTECS criteria. Gastrointestinal tumors. **Studies suggest that repeated and prolonged overexposure effects may be targeted at the kidneys.

Principle Routes of Exposure

SKIN CONTACT, EYE CONTACT