Salt, Sodium Chloride

2.1 Classification of the substance or mixture

serious eye damage/eye Irritation !category 2B

2.2 Label elements

Including preci;tYtlonary statements arnlng

Hazard statements

Causes eye irritation

Appearance/Odor

Physical state While c stalllne. Solid. Odorless. While, crystalline. Odorless. Color No data available Odor Threshold No data available Property Y..!l.l!.tiL Note • Method pH@20 C 9 No data available Melting/freezing point 800 °C I 1472 °F. SALT, SODIUM CHLORIDE Salt, Sodium Chloride Date: 10-Apr-2017 Bolling polnUbolllng range 1413 °C I 2575 "F. Flash Point Not Determined Evaporation rate N/A Flammablllty (solid, gas) No data available Flammablllty Limits In Air Upper Flammability Limit No data available. Lower Flammabllity Limit No data available. Vapor pressure 1 MM@855 deg Vapor density NIA Specific Gravity 2.165 Water solubility Appreciable (26.43 % by weight at 20C) Solubility In other solvents No data available Partition coefficient: n-octanol/waterNo data available Autoignition temperature No data available Decomposition temperature No data available Viscosity, kinematic No data aval!able Viscosity, dynamic No data available Explosive properties No data avallable. Oxidizing Properties No data available

Prevention

Wash face, hands and any exposed skin thoroughly after handling Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Gel medical advice/attention General Hazards Although not required to be classified under GHS, this product has been self-classified, SALT, SODIUM CHLORIDE Salt, Sodium Chloride Date: 10-Apr-2017 Synonyms Industrial Grade Sodium Chloride. E-~-~- ~~~~~~h7o~~~ ~---~-~~·~~~··1-·--- _·~7=~=~=~~-~1~=~=5===---1------=W .. ..6= 0 6""~1'-'-h;~;'""l'o __ ·==i--~ 'Yellow prusslate of soda in trace amounts Is used as an anti-caking agent In the sized sail. Elrfil_ald measures for different exposure routes Eye contact Burning feeling and temporary redness. May cause irritation and redness. Rinse thoroughly with plenty of water for at least 15 minutes, titting lower and upper eyelids. Consult a physician. If symptoms persist, call a physician. Skin contact May cause dryness lo skin. Wash off immediately with plenty of water for at least 15 minutes. If skin Irritation persists, call a physician. Inhalation Move to fresh air. Irritating to mucous membranes. May cause throat irritation. If symptoms persist, call a physician. Ingestion Drink plenty of water. Rinse mouth with water. If symptoms persist, call a physician. Nol intended for human or animal consumption. Protection of First-aiders Use personal protective equipment. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Keep patient under observation. Treat symptomatically. Suitable Extinguishing Media Material Is non-flammable. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION Use of water spray when fighting fire may be inefficient. CAUTION Use of water spray when fighting fire may be inefficient. Specific hazards arising from the No data avallabie. chemical Hazardous Combustion Products Carbon monoxide. Carbon dioxide (C02). Exptoslon data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective Equipment ang Precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHNNIOSH (approved or equivalent) and full protective gear. Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Use personal protective equipment. Avoid dust formation. Avoid contact with the skin and the eyes.

Further information

See Section 12 for additional Information. Environmental Precautions See Section 12 for additional Ecological Information. SALT, SODIUM CHLORIDE Salt, Sodium Chloride Date: 10·Apr-2017 Methods and Materials for Containment and Cleaning Up Methods for Containment Prevent further leakage or spillage if safe to do so. Avoid generation and spreading of dust. Methods for Cleaning Up Use personal protective equipment. Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. Take up mechanically and collect in suitable container for disposal. Avoid dust formation. Clean contaminated surface thoroughly. Precautions for safe handling Advice on safe handling Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid dust formation. Do not Ingest. Conditions for safe storage, Including !llJY incompatibilities Technical measures/Storage Keep containers tightly closed In a dry, cool and well-ventilated place. conditions Incompatible products Bromine Trifluoride, Lithium. Control parameters Exposure Guldelines Treat as a nuisance dust. Exposure controls Engineering Measures Showers Eyewash stations Ventilation systems. Ensure adequate ventlla!ion to remove vapors, fumes, dust, etc. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extniction. Ensure that eyewash stations and safety showers are close to the worl~station locallon. Individual protection measures, such as personal protective egulpment Eye/Face Protection Safety glasses with side-shields or Tightly filling safety goggles for dusty conditions Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Wear latex or Nltrile gloves. Respiratory protection Effective dust mask. If exposure limits are exceeded or Irritation is experienced, NtOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided In accordance with current local regufations. Hygiene measures Handle in accordance with good Industrial hygiene and safety practice. Wash hands and face before breaks and Immediately after handling the product. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the Inside, before re-use. Physical and chemical properties Physical state Solid. Softening point No data available Molecular Weight No data available VOC Content No data available. Density No data avallable Bulk Density No data available. Reactivity No data available Chemical stablllty Stable under normal conditions. Possibility of hazardous reactions None under normal processing, Hazardous Polymerfz;iJtlon Hazardous polymerization does not occur. Conditions to Avoid No data available. Incompatible Materials Bromine Trifluoride, Lithium. Hazardous Decomposition Products When heated to decomposition (above 1413 C} may emit toxic fumes of Na20 and Cl2. Information on likely routes of exposure Eye contact May cause irritation. Skin contact Irritating to skin. Prolonged contact may cause redness and Irritation. Inhalation May cause Irritation of respiratory tract. Inhalation of dust in high concentration may cause frrltaUon of respiratory system. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium Chloride = 3 g/kg (Rat) = 10 g/l<g {Rabbit) > 42 g/m3 ( Rat ) 1 h 7647·14·5 Information on toxicological effects Symptoms No data available. SALT, SODIUM CHLORIDE Salt, Sodium Chloride Revision Date ·1 O-Apr-2017 Delayed and Immediate effects as well as chronic effects from short and lonq-term exposure Sensitization No data available. Mutagenic Effects No data available. Carcinogenicity There are no known carcinogenic chemicals in this product. Reproductive Toxlclty No data available. Speclflc target organ systemic No information available. toxicity (single exposure) Specific target organ systemic No information available. toxicity (repeated exposure) Target Organ Effects Skin, Eyes, Gastrointestinal tract (GI). Aspiration hazard No information available. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmlx (oral) 3000 mg/kg LD50 Ora1 (mg/kg) 3000 mg/l<g (rat) Esllmated LD50 Dermal 10000 mg/kg (rat) Estimated LC50 Inhalation (DUST) 17572 mg/I (mist) (dust) mg/m3 4 hour Estimated Ecotoxfclty 0% of the mixture consists of components(s) of unknown hazards to the aQualic environment Chemical Name ToxiGity to algae Toxicity to fish roxlclty to daphnla and other aauatlc invertebrates Sodium Chloride 5560 - 6080 mg/L: 96 h Lepomls 1000 mg/l: 48 h Daphnla magna 7647-14-5 macrochirus LC50 now-through EC50 340.7 · 469.2 mgll: 48 h 12946 mg/l: 96 h Lepomls Daphnla magna EC50 Static macrochirus LC50 static 6020 - 7070 mgll: 96 h Plmephates promelas LC50 static 7050 mg/L: 96 h Pimephales promelas LC50 seml-statlc 6420 - 6700 mg/L: 96 h Plmephales promelas LC50 static 4747 - 7824 mg/L: 96 h Onwrhynchus myklss LC50 llow-throuoh Persistence and degradptilli.h'- No data available. Bloaccumulatlon No data available. Other adverse effects No data available Waste treatment Waste Disposal Methods This material, as supplied, Is not a llazardous waste according lo Federal regulations (40 CFR 261). This material could become a llazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, If cllernlcal additions are made to this material, or If the material is processed or otllerwise altered. Consult 40 CFR 261 to determine wllelher the altered material is a hazardous waste. Consult the appropriate state, regional, or local SALT, SODIUM CHLORIDE Salt, Sodium Chloride Revision Dato 10-Apr-2017 regulations for additional requirements. Dispose of In accordance with federal, slate, and local regulations. Contaminated packaging Emply containers should be taken lo an approved waste handling site for recycling or disposal. Do not re-use empty containers. Harmonized Tariff Schedule I Schedule B HTS/Schedule B Code 2501.00.0000 DOT Not regulated. TDG Not regulated. MEX Not regulated. lQAQ_ Not regulated. ICAO/IATA Not regulated. lMDG/IMO Not regulated. Rl1L Not regulated. ADR/RID Not regulated. AON Not regulated. International Inventories TSCA Complies DSL/NDSL Complies EtNECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA ·United States Toxic Substances Control Act SecUon B(b) Inventory DSL/NDSL ·Canadian Domestic Substances LlsVNon-Domestlc Substances List EINECS/ELINCS · European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS • Japan Existing and New Chemical Substances IECSC • China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemlcal Substances PICCS • Philippines Inventory of Chemicals and Chemical Substances AICS ·Australian Inventory of Chemical Substances U.S. Federal Regulations SARA 313 Section 313 ofTltle Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. ~­! SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No I Fire Hazard No SALT, SODIUM CHLORIDE Salt, Sodiurn Chloride Revision Date 1 O·Apr-2017 Sudden Release of Pressure Hazard No Reactive Hazard No ct ea n WatfilAru This product does not contain any substances regulated as pollutants pursuant to the Clean Waler Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liablllty Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act {SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations U.S. EPA Label Information EPA Pesticide registration number Not applicable. Technical Contact Tom Ellis Technical Manager 7901 FM 1405 Baytown, Texas 77523 Office: 281-303-1101 ext 1104 Prepared By HSE Department 4800 San Felipe St. Houston, TX 77056 Revision Date 10-Apr-2017 Reason for Revision: SOS sections updated 1 Disclaimer The Information provided In this Safety Data Sheet Is correct to the best of our knowledge, Information and belief at the date of its publication. The Information given is designed onfy as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The Information relates only to the specific material designated and may not be valid for such material used In combination with any other materials or In any process, unless specified In the text. end 04/04/20 '18 14 40 34 From:- UNITED SALT BAYTOWN LLC Purchase Order : 36299 7901 Farm to Market 1405 Delivery: 80257254 BAYTOWN TX 77523 Delivery date : 03/19/2018 USA Sales order : 1211850 Order date : 03/ 12/2018 Ship To:- Customer : 2040810 CITY OF AUSTIN TEXAS WATER TREATMENT PLANT#4 6800 N. FM 620 AUSTIN TX 78732 USA Material Number : 8303 Material Description: SALT,EVAP FOOD GRADE BULK TRU-FLO BT Batch Number : C8TU 180246 Date of Manufacture: 03/18/2018 Quantity (TON) : 23.990 Characteristic Value Sodium Chloride , % : 99.0 - 100.0 Calcium/Magnesium, ppm : 0.0 - 3,500.0 YPS, Anti-Caking Agent, ppm : 0.0 - 13.0 pH: 6.0- 10.0 Loss on Drying, % : 0.00 - 0.50 Bulk Density, lbs/cu.ft. : 68 - 82 Water Insolubles, ppm : 0.0 - 300.0 Iodine, Potassium Iodide, ppm : 0.0 Heavy Metals As Lead, ppm : 0.0 - 2.0 Arsenic , ppm : 0.0 - 1.0 USS 20 Mesh, % Retained : 0.0 - 4.0 USS 30 Mesh, % Retained : 4.0 - 32.0 USS 40 Mesh, % Retained : 4.0 - 51.0 USS 45 Mesh , % Retained : 4.0 - 24.0 USS 50 Mesh, % Retained : 1.0 - 15.0 USS 70 Mesh, % Retained: 4.0 - 15.0 USS 100 Mesh , % Retained : 1 .0 - 7 .0 USS -100 Mesh, % Retained : 0.0 - 12.0 4/4/LUHl Listing Category Search Page I NSF International The Public Health and Safety Organization NSF Product and Service Listings These NSF Official Listings are current as of Wednesday, April 04, 2018at12:15 a.m. Eastern Time. Please contact NSF International to confirm the status of any Listing, report errors, or make suggestions. Alert: NSF is concerned about fraudulent downloading and manipulation of website text. Always confirm this information clicking on the below link for the most accurate information httP-://info.nsf.org/Certi fied/PwsChemicals/Listings.asP-? ComP-any:N ame=united +salt&PlantState=Texas+ TX& NSF/ANSI6o Drinking Water Treatment Chemicals - Health ................ .....,_, United Salt Corporation 4800 San Felipe Houston, TX 77056 United States 800-554-8658 713-877-2600 Visit this comP-any 's website Cb! !;JJ.://www.unitedsalt.com) Facility : Baytown, TX http://info.nsf.org/Certified/PwsChemicals/Listings.asp?CompanyName=united+salt&TradeName=&ChemicalName=&ProductFunction=&PlantState=Texas+TX&PlantCountry=&PlantRegion= 1/2 4/4/2018 listing Category Search Page I NSF International Sodium Chloride[1] [2] Trade Designation Product Function Max Use Tru-Flo® Evaporated Food Grade Salt Other NA Tru-Soft® Water Softener Salt Pellets Other NA Tru-Soft® Water Softener Salt Pellets with Rust Inhibitor Other NA [1] Certified for use in the electrochlorination process for on-site disinfectant generators as well as softener resin regeneration. [2] For electrolytic sodium hypochlorite generator use of this product, the maximum disinfectant feed concentration shall not exceed 7 mg Cl2/L. This requirement limits bromate production in the effluent sodium hypochlorite and is based on the bromide concentration in the salt. NOTE: Only products bearing the NSF Mark are Certified. Number of matching Manufacturers is 1 Number of matching Products is 3 Processing time was o seconds http://info.nsf.org/Certified/PwsChemicals/Listings.asp?CompanyName=united+salt& TradeName=&ChemicalName=&ProductFunction=&PlantState=Texas+ TX&PlantCountry=&PlantRegion= 212 ADDENDUM PURCHASING OFFICE CITY OF AUSTIN, TEXAS Solicitation: IFB GLB0074 Addendum No: 1 Date of Addendum: 3/20/18 This addendum is to incorporate the following changes to the above referenced solicitation: I. Clarifications: 1.1 Replace the Section 0400 to reflect the change to the Section 0400 SE from Delivery shall be made within fourteen (14) business days to fourteen (14) calendar days after the order is placed. Also in Section 0400 7Fiii from The City's Laboratory will analyze the remaining sample. The percentage of active and available fluorosilicic acid contained in this sample will be used, if needed, as a basis for payment to The City's Laboratory will analyze the remaining sample. +Re- percentage of active and available fluorosilicic acid contained in this sample will be used, if needed, as a basis for payment ALL OTHER TERMS AND CONDITIONS REMAIN THE SAME. APPROVED BY: ~ hi.ti.1.f J GeOfQialela, Procurement Specialist Ill Purchasing Office, 512-97 4-2939 ACKNOWLEDGED BY: Brenntag Southwest 4/4/18 Name Date RETURN ONE COPY OF THIS ADDENDUM TO THE PURCHASING OFFICE, CITY OF AUSTIN, WITH YOUR RESPONSE OR PRIOR TO THE SOLICITATION CLOSING DATE. FAILURE TO DO SO MAY CONSTITUTE GROUNDS FOR REJECTION. GOAL DETERMINATION REQUEST FORM Buyer Name/Phone Georgia Billela/4-2939 PM Name/Phone Olivia Beck/2-1839 Sponsor/User Dept. Austin Water/2200 Sponsor Name/Phone Lydia Torres/2-0329 Solicitation No IFB 2200 GLB0074 Project Name Sodium Chloride- Bulk Contract Amount 700,000 (140,000 per Ad Date (if applicable) 3/19 - Tentative year) Procurement Type DAD-CSP DAD-CM@R DAD - Design Build D AD - Design Build Op Maint DAD-JOC D IFB - Construction D IFB-IDIQ DPS Project Specific D PS - Rotation List D Nonprofessional Services !Z'.I Commodities/Goods D Cooperative Agreement D Critical Business Need D lnterlocal Agreement D Ratification D Sole Source* Provide Project Description** The City of Austin (City) seeks bids in response to this solicitation to establish a contract with a qualified Vendor (Contractor) who can provide Sodium Chloride (bulk). The Sodium Chloride (Bulk) will be used in the manufacture of sodium hypochlorite to add to the municipal water supply at Water Treatment Plant 4 Project History: Was a solicitation previously issued; if so were goals established? Were subcontractors/subconsultants utilized? Include prior Solicitation No. IFB STA1105- No Goals List the scopes of work (commodity codes) for this project. (Attach commodity breakdown by percentage; eCAPRIS printout acceptable) 77563 - Salt, Evaporated Georgia Billela 3/9/18 Buyer Confirmation Date: * Sole Source must include Certificate of Exemption **Project Description not required for Sole Source FOR SMBR USE ONLY Date: Received 3/9/2018 I Date Assigned to 13/9/2018 BOC In accordance with Chapter2-9(A-D)-19 of the Austin City Code, SMBR makes the following determination: D Goals %MBE %WBE D Subgoals % African American % Hispanic % Asian/Native American %WBE Goal Determination Request Rev 04.04.2016 GOAL DETERMINATION REQUEST FORM D Exempt from MBE/WBE Procurement Program ~ No Goals Goal Determination Request Rev 04.04.2016 GOAL DETERMINATION REQUEST FORM This determination is based upon the following: D Insufficient availability of M/WBEs D No availability of M/WBEs D Insufficient subcontracting opportunities [gl No subcontracting opportunities D Sufficient availability of M/WBEs D Sufficient subcontracting opportunities D Sole Source D Other If Other was selected, provide reasoning: MBE/WBE/DBE Availability There are 0 W /MBE certified vendors for this scope of work. Subcontracting Opportunities Identified There are no subcontracting opportunities identified. Signature/ Date Returned to/ Date: Goal Determination Request