Piperylene

Hazard statements (CLP)

H225, H302+H332, H304, H315, H319, H335, H336, H340, H350, H361, H373, H410

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Emergency overview Highly flammable liquid and vapour. Harmful if swallowed or if inhaled. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.May cause drowsiness or dizziness.May cause genetic defects. May cause cancer.Suspected of damaging fertility or the unborn child.May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects.

Physical hazards

Flammable liquids, Category 2

Health hazards

Acute toxicity (oral), Category 4 : Acute toxicity (inhal.), Category 4 : Skin corrosion/irritation, Category 2 : Serious eye damage/eye irritation, Category 2 : Germ cell mutagenicity, Category 1B : Carcinogenicity, Category 1B : Reproductive toxicity, Category 2 : Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation : Specific target organ toxicity — Single exposure, Category 3, Narcosis : Specific target organ toxicity — Repeated exposure, Category 2 : Aspiration hazard, Category 1 Harmful if swallowed or if inhaled,May be fatal if swallowed and enters airways,Causes skin irritation,Causes serious eye irritation,May cause respiratory irritation,May cause drowsiness or dizziness,May cause genetic defects,May cause cancer,Suspected of damaging fertility or the unborn child,May cause damage to organs through prolonged or repeated exposure. Symptoms/effects : May cause genetic defects,May cause cancer,Suspected of damaging fertility or the unborn child. Symptoms/effects after : Causes serious eye irritation. eye contact Symptoms/effects after : Harmful if swallowed,Ingestion may cause nausea, ingestion vomiting and diarrhea,May result in aspiration into the lungs, causing chemical pneumonia,May be fatal if swallowed and enters airways. Symptoms/effects after : Harmful if inhaled,May cause drowsiness or inhalation dizziness,May cause respiratory irritation,Overexposure to vapours may result in cough Symptoms/effects after : Causes skin irritation. skin contact

Environmental hazards

Hazardous to the aquatic environment — Acute Hazard, Category 1 : Hazardous to the aquatic environment — Chronic Hazard, Category 1 Other hazards not mentioned above are Not applicable or No data is available. Very toxic to aquatic life with long lasting effects.

Hazard pictograms

CN)

Signal word

GHS CN) Danger

Hazard statements

H225 - Highly flammable liquid and vapour. CN) H302+H332 - Harmful if swallowed or if inhaled H315 - Causes skin irritation. H319 - Causes serious eye irritation. H340 - May cause genetic defects. H350 - May cause cancer. H361 - Suspected of damaging fertility or the unborn child. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness. H373 - May cause damage to organs through prolonged or repeated exposure. H304 - May be fatal if swallowed and enters airways. H410 - Very toxic to aquatic life with long lasting effects. CENTER or doctor. P302+P352 - IF ON SKIN: Wash with plenty of water. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - IF exposed or concerned: Get medical advice/attention. P312 - Call a POISON CENTER or doctor if you feel unwell. P314 - Get medical advice/attention if you feel unwell. P321 - Specific treatment (see supplemental first aid instruction on this label) P330 - Rinse mouth. P331 - Do NOT induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P370+P378 - In case of fire: Use media other than water to extinguish. P391 - Collect spillage. Storage precautionary : P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up. 10/18/2019 Disposal precautionary : P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Prevention

P201 - Obtain special instructions before use.

Precautionary statements

P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting equipment. P242 - Use only non-sparking tools. 10/18/2019 P243 - Take precautionary measures against static discharge. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection.

Response

Precautionary : P301+P310 - IF SWALLOWED: Immediately call a POISON

Other physicochemical hazards

Highly flammable liquid and vapour.

2.3 Other hazards

Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below ground level Burning liquid may float on water May spread fire