HD FLOOR & WALL

Hazard statements (CLP)

H315, H317, H318, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP)] Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Harmful to aquatic life with long lasting effects

Hazard pictograms

GHS05 GHS07

Signal word

Danger

Contains

FORMALDEHYDE, POLYMER WITH N1-(2-AMINOETHYL)-N2-[2- AMINOETHYL)AMINO]ETHYL]-1,2-ETHANEDIAMINE, 2,2'-[1,4- BUTANEDIYLBIS(OXYMETHYLE), O,O'-BIS(2- AMINOPROPYL)POLYPROPYLENEGLYCOL, 3,6,9- TRIAZAUNDECAMETHYLENEDIAMINE

Hazard statements

H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water.

2.3 Other hazards

Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 1 H318 Skin sensitisation, Category 1 H317 Hazardous to the aquatic environment – Chronic Hazard, Category 3 H412 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Harmful to aquatic life with long lasting effects. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS05 GHS07 Signal word (CLP) : Danger Contains : FORMALDEHYDE, POLYMER WITH N1-(2-AMINOETHYL)-N2-[2- AMINOETHYL)AMINO]ETHYL]-1,2-ETHANEDIAMINE, 2,2'-[1,4- BUTANEDIYLBIS(OXYMETHYLE), O,O'-BIS(2- AMINOPROPYL)POLYPROPYLENEGLYCOL, 3,6,9- TRIAZAUNDECAMETHYLENEDIAMINE Hazard statements (CLP) : H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H412 - Harmful to aquatic life with long lasting effects. Precautionary statements (CLP) : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P302+P352 - IF ON SKIN: Wash with plenty of water. 2.3. Other hazards Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] FORMALDEHYDE, POLYMER WITH N1-(2- CAS-No.: 180583-06-6 10 – 30 Skin Sens. 1, H317 AMINOETHYL)-N2-[2- Aquatic Chronic 2, H411 AMINOETHYL)AMINO]ETHYL]-1,2- ETHANEDIAMINE, 2,2'-[1,4- BUTANEDIYLBIS(OXYMETHYLE) O,O'-BIS(2- CAS-No.: 9046-10-0 < 5 Skin Corr. 1A, H314 AMINOPROPYL)POLYPROPYLENEGLYCOL EC-No.: 618-561-0 Eye Dam. 1, H318 Aquatic Chronic 3, H412 3,6,9-TRIAZAUNDECAMETHYLENEDIAMINE CAS-No.: 112-57-2 < 5 Acute Tox. 4 (Oral), H302 (ATE=500 EC-No.: 203-986-2 mg/kg bodyweight) EC Index-No.: 612-060-00-0 Acute Tox. 4 (Dermal), H312 (ATE=1100 mg/kg bodyweight) Skin Corr. 1A, H314 Skin Sens. 1, H317 Aquatic Chronic 2, H411 Full text of H- and EUH-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Serious damage to eyes. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Special hazards arising from the substance or mixture Fire hazard : Not flammable. Explosion hazard : No direct explosion hazard. Reactivity in case of fire : Product is not explosive. Hazardous decomposition products in case of fire : Toxic fumes may be released. 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Hygiene measures : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool. 7.3. Specific end use(s) Coatings and paints, thinners, paint removers. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.1.1 National occupational exposure and biological limit values No additional information available 8.1.2. Recommended monitoring procedures No additional information available 8.1.3. Air contaminants formed No additional information available 8.1.4. DNEL and PNEC No additional information available 8.1.5. Control banding No additional information available 8.2. Exposure controls 8.2.1. Appropriate engineering controls Appropriate engineering controls: Ensure good ventilation of the work station. 8.2.2. Personal protection equipment Personal protective equipment symbol(s): 8.2.2.1. Eye and face protection Eye protection: Safety glasses 8.2.2.2. Skin protection Skin and body protection: Wear suitable protective clothing Hand protection: Protective gloves 8.2.2.3. Respiratory protection Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment 8.2.2.4. Thermal hazards No additional information available 8.2.3. Environmental exposure controls Environmental exposure controls: Avoid release to the environment.