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SECTION 2: Hazards identification

Classification of the substance or mixture Not classified

Signal word

No signal word.

Hazard statements

No known significant effects or critical hazards.

Prevention

Not applicable.

Response

Not applicable.

Storage

Not applicable.

Disposal

Not applicable.

Supplemental label elements

Not applicable.

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Not classified. substance or mixture GHS label elements Signal word No signal word. Hazard statements No known significant effects or critical hazards. Precautionary statements Prevention Not applicable. Response Not applicable. Storage Not applicable. Disposal Not applicable. Supplemental label Not applicable. elements Other hazards which do not None known. result in classification Section 3. Composition and ingredient information Substance/mixture Mixture Water and Urea (32.5%) There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention if symptoms occur. Inhalation If inhaled, remove to fresh air. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Get medical attention if symptoms occur. Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if symptoms occur. Ingestion Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Most important symptoms/effects, acute and delayed See Section 11 for more detailed information on health effects and symptoms. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treatment should in general be symptomatic and directed to relieving any effects. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments No specific treatment. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. Section 5. Firefighting measures Extinguishing media Suitable extinguishing In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray. media Unsuitable extinguishing Do not use water jet. media Specific hazards arising In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Hazardous thermal Combustion products may include the following: decomposition products carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide) nitrogen oxides (NO, NO₂ etc.) Special protective actions No action shall be taken involving any personal risk or without suitable training. for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. Special protective Fire-fighters should wear positive pressure self-contained breathing apparatus equipment for fire-fighters (SCBA) and full turnout gear. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. For emergency responders If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Section 6. Accidental release measures Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and material for containment and cleaning up Small spill Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, Store in accordance with local regulations. Store in original container protected including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. Not suitable Prolonged exposure to elevated temperature. Section 8. Exposure controls and personal protection Control parameters Occupational exposure limits None. Appropriate engineering All activities involving chemicals should be assessed for their risks to health, to controls ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained. Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards. Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits. The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible. Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Section 8. Exposure controls and personal protection Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Safety glasses with side shields. Skin protection Hand protection Wear suitable gloves. The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/ manufacturer and with a full assessment of the working conditions. Recommended: Wear protective gloves if prolonged or repeated contact is likely. Skin protection Use of protective clothing is good industrial practice. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716 Gloves:AS/NZS 2161.1 Eye protection:AS/NZS 1336 and AS/NZS 1337 Section 9. Physical and chemical properties Appearance Physical state Clear to slightly hazy liquid. Colour Colourless. to Green. Odour Ammoniacal. [Slight] Odour threshold Not available. pH 9.8 to 10 [Conc. (% w/w): 10%] Melting point -11.5°C (11.3°F) Boiling point 100°C (212°F) Flash point Not available. Evaporation rate Not available. Flammability (solid, gas) Not applicable. Based on - Physical state Lower and upper explosive Not available. (flammable) limits Vapour pressure 6.4 kPa (48 mm Hg) [40°C (104°F)] Vapour density Section 9. Physical and chemical properties Not available. Relative density Not available. Density 1090 kg/m³ (1.09 g/cm³) at 20°C Solubility Soluble in water. Partition coefficient: n- Not available. octanol/water Auto-ignition temperature Not available. Decomposition temperature 100°C (212°F) Viscosity Not available. Section 10. Stability and reactivity Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information. Chemical stability The product is stable. Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur. reactions Under normal conditions of storage and use, hazardous polymerisation will not occur. Conditions to avoid Avoid contamination by any source including metals, dust and organic materials. Incompatible materials No specific data. Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products products should not be produced. Section 11. Toxicological information Information on toxicological effects Information on likely routes Routes of entry anticipated: Dermal, Inhalation. of exposure Potential acute health effects Eye contact No known significant effects or critical hazards. Inhalation Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. At normal ambient temperatures this product will be unlikely to present an inhalation hazard because of its low volatility. Skin contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Eye contact No specific data. Inhalation No specific data. Skin contact No specific data. Ingestion No specific data. Delayed and immediate effects as well as chronic effects from short and long-term exposure Eye contact Potential risk of transient stinging or redness if accidental eye contact occurs. Inhalation Overexposure to the inhalation of airborne droplets or aerosols may cause irritation of the respiratory tract. Skin contact Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ or dermatitis. Ingestion Ingestion of large quantities may cause nausea and diarrhoea. General No known significant effects or critical hazards. Section 11. Toxicological information Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Section 12. Ecological information Persistence and degradability Expected to be biodegradable. Bioaccumulative potential This product is not expected to bioaccumulate through food chains in the environment. Mobility in soil Soil/water partition Not available. coefficient (KOC) Mobility Soluble in water. Other adverse effects No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimised wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Special Precautions for No additional special precautions identified. Landfill or Incineration Section 14. Transport information ADG IMDG IATA UN number Not regulated. UN proper - shipping name Transport hazard - class(es) Packing group - Section 14. Transport information Environmental No. hazards Additional - information Special precautions for user Not available. Section 15. Regulatory information Standard for the Uniform Scheduling of Medicines and Poisons Not regulated. Model Work Health and Safety Regulations - Scheduled Substances No listed substance Montreal Protocol Ingredient name List name Status Not listed. Stockholm Convention on Persistent Organic Pollutants Ingredient name List name Status Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Ingredient name List name Status Not listed. International lists National inventory REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1. Australia inventory (AICS) All components are listed or exempted. Canada inventory All components are listed or exempted. China inventory (IECSC) All components are listed or exempted. Japan inventory (ENCS) All components are listed or exempted. Korea inventory (KECI) All components are listed or exempted. Philippines inventory All components are listed or exempted. (PICCS) Taiwan Chemical All components are listed or exempted. Substances Inventory (TCSI) United States inventory All components are active or exempted. (TSCA 8b) Section 16. Any other relevant information History Date of printing 4/9/2021 Date of issue/Date of 4/9/2021 revision Date of previous issue 1/20/2016 Version 2 Section 16. Any other relevant information Prepared by Product Stewardship Key to abbreviations ADG = Australian Dangerous Goods ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NOHSC = National Occupational Health and Safety Commission REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation [Regulation (EC) No. 1907/2006] STEL = Short term exposure limit SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations TWA = Time weighted average VOC = Volatile Organic Compound SADT = Self-Accelerating Decomposition Temperature Varies = may contain one or more of the following 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7, 64742-63-8, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0, 72623-87-1 Procedure used to derive the classification Classification Justification Not classified. Indicates information that has changed from previously issued version. Notice to reader All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet. The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group. It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited. Page : 1 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name/designation : Fuels, diesel Chemical name : Fuels, diesel EC Index : 649-224-00-6 EC-No. : 269-822-7 CAS-No. : 68334-30-5 REACH registration No : 01-2119484664-27-0195 Product group : Trade product 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Use of the substance/mixture : Fuels see attached exposure scenario. Title Use descriptors Use as an intermediateX PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15, ERC6a, ESVOC (ES Ref.: 02) SPERC 6.1a.v1 Distribution of substanceX PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9, PROC15, ERC4, (ES Ref.: 03) ERC5, ERC6a, ERC6b, ERC6c, ERC6d, ERC7, ESVOC SPERC 1.1b.v1 LubricantsX PROC1, PROC2, PROC3, PROC4, PROC7, PROC8a, PROC8b, PROC9, PROC10, (ES Ref.: 05) PROC13, PROC17, PROC18, ERC4, ERC7, ESVOC SPERC 4.6a.v1 Use as a fuelX PROC1, PROC2, PROC3, PROC8a, PROC8b, PROC16, ERC7, ESVOC SPERC (ES Ref.: 06) 7.12a.v1 Functional fluidsX PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9, ERC7, ESVOC (ES Ref.: 09) SPERC 7.13a.v1 Use as a fuelX PROC1, PROC2, PROC3, PROC8a, PROC8b, PROC16, ERC9a, ERC9b, ESVOC (ES Ref.: 07) SPERC 9.12b.v1 Use as a fuelX PC13, ERC9a, ERC9b, ESVOC SPERC 9.12c.v1 (ES Ref.: 08) Manufacture of substanceX PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15, ERC1, ESVOC (ES Ref.: 01) SPERC 1.1.v1 Formulation & (re)packing of substances PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC14, and mixturesX PROC15, ERC2, ESVOC SPERC 2.2.v1 (ES Ref.: 04) Full text of use descriptors: see section 16 1.2.2. Uses advised against No data available 1.3. Details of the supplier of the safety data sheet Trafigura Ventures V.B.V. Evert van de Beekstraat 1-82 The Base, Tower B - 5th Floor 1118 CL Schiphol - The Netherlands T +31 20 504 1800 TrafiguraReach@trafigura.com 1.4. Emergency telephone number Emergency number : +32 3 575 03 30 Page : 2 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 This telephone number is available 24 hours per day, 7 days per week. Country Official advisory body Address Emergency number Ireland National Poisons Information Centre 9 Dublin Beaumont Hospital Beaumont Road +353 1 809 21 66 (public, Beaumont Hospital 8am - 10pm, 7/7) +353 01 809 2566 (Professionals, 24/7) United Kingdom National Poisons Information Service Claremont Place 0844 892 0111 (UK only, Newcastle-upon-Tyne (Newcastle Centre) NE1 4LP Newcastle 24/7, healthcare Regional Drugs and Therapeutics Centre, Wolfson Unit professionals only) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Flam. Liq. 3 H226 Acute Tox. 4 (Inhalation) H332 Skin Irrit. 2 H315 Carc. 2 H351 STOT RE 2 H373 Asp. Tox. 1 H304 Aquatic Chronic 2 H411 Full text of H statements : see section 16 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) : GHS02 GHS07 GHS08 GHS09 Signal word : Danger Hazard statements (CLP) : H226 - Flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H332 - Harmful if inhaled. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 - Do not breathe mist, vapours, spray, gas, fume. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P310+P331 - IF SWALLOWED: Immediately call a POISON CENTER, a doctor. Do NOT induce vomiting. P391 - Collect spillage. Listed in Annex VI : EC Index-No. : 649-224-00-6 Page : 3 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 2.3. Other hazards Other hazards : PBT/vPvB data. This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. SECTION 3: Composition/information on ingredients 3.1. Substances Comments : UVCB Substance name : Fuel diesel CAS-No. : 68334-30-5 EC-No. : 269-822-7 EC Index : 649-224-00-6 Substance name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Fuels, diesel; Gasoil - unspecified (CAS-No.) 68334-30-5 100 Flam. Liq. 3, H226 (EC-No.) 269-822-7 Asp. Tox. 1, H304 (EC Index) 649-224-00-6 Skin Irrit. 2, H315 (REACH-no) 01-2119484664-27-0195 Acute Tox. 4 (Inhalation), H332 Carc. 2, H351 STOT RE 2, H373 Aquatic Chronic 2, H411 Full text of H-statements: see section 16 3.2. Mixtures Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures Additional advice : First aider: Pay attention to self-protection. See also section 8 . Treat symptomatically. Never give anything by mouth to an unconscious person. Show this safety data sheet to the doctor in attendance. In case of doubt or persistent symptoms, consult always a physician. Inhalation : Keep at rest. Provide fresh air. In case of doubt or persistent symptoms, consult always a physician. If unconscious place in recovery position and seek medical advice. Give oxygen or artificial respiration if necessary. Skin contact : Remove contaminated clothing and shoes. After contact with skin, wash immediately with plenty of water and soap. In case of doubt or persistent symptoms, consult always a physician. In the event of a high pressure injection injury, worker should obtain immediate medical assistance. Eyes contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical advice/attention. Ingestion : Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Inhalation : Harmful if inhaled. May cause respiratory irritation. Skin contact : Causes skin irritation. Eyes contact : Contact with eyes may cause irritation. Ingestion : May be fatal if swallowed and enters airways. May cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Page : 4 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 Chronic symptoms : Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. 4.3. Indication of any immediate medical attention and special treatment needed No data available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray, Alcohol resistant foam, Carbon dioxide, Dry extinguishing powder. Unsuitable extinguishing media : Strong water jet. 5.2. Special hazards arising from the substance or mixture Specific hazards : Vapours are heavier than air and may spread along floors. On heating there is a risk of a build-up of pressure in hermetically sealed containers or tanks. Do not allow run- off from fire-fighting to enter drains or water courses. Explosion hazard : Vapours may form explosive mixture with air. Hazardous decomposition products in : Carbon oxides (CO, CO2). Hydrogen sulfide. Sulphur oxides. case of fire 5.3. Advice for firefighters Firefighting instructions : Special protective equipment for firefighters. . In case of fire: Wear self-contained breathing apparatus. Use water spray or fog for cooling exposed containers. Evacuate personnel to a safe area. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel For non-emergency personnel : Provide adequate ventilation. Evacuate personnel to a safe area. Use personal protective equipment as required. Reference to other sections: 8. Avoid contact with skin, eyes and clothing. Do not breathe vapour/aerosol. Vapours may form explosive mixture with air. Vapours are heavier than air and may spread along floors. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ensure equipment is adequately earthed. Material can create slippery conditions. Product may release Hydrogen Sulphide: A specific assessment of inhalation risks from the presence of hydrogen sulphide in tank headspaces, confined spaces, product residue, tank waste and waste water, and unintentional releases should be made to help determine controls appropriate to local circumstances. 6.1.2. For emergency responders For emergency responders : Ensure procedures and training for emergency decontamination and disposal are in place. Concerning personal protective equipment to use, see section 8. 6.2. Environmental precautions Do not allow to enter into surface water or drains. Do not allow to enter into surface water or drains. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Stop leak if safe to do so. Dam up. Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite or powdered limestone. Keep in suitable, closed containers for disposal. If liquid has been spilt in large quantities clean up promptly by scoop or vacuum. After cleaning, flush traces away with water. Dispose of contaminated materials in accordance with current regulations. 6.4. Reference to other sections Concerning personal protective equipment to use, see section 8. Concerning disposal elimination after cleaning, see section 13. Page : 5 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Provide adequate information, instruction and training for operators. Provide adequate ventilation. Use personal protective equipment as required. Concerning personal protective equipment to use, see section 8. Avoid contact with skin, eyes and clothing. Do not breathe vapour/aerosol. Take precautionary measures against static discharges. Ensure equipment is adequately earthed. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take any precaution to avoid mixing with combustibles... See also section 10. Ensure proper process control to avoid excess waste discharge (temperature, concentration, pH, time). Do not use compressed air for filling, discharging or handling. Do not allow to enter into surface water or drains. Product may release Hydrogen Sulphide: A specific assessment of inhalation risks from the presence of hydrogen sulphide in tank headspaces, confined spaces, product residue, tank waste and waste water, and unintentional releases should be made to help determine controls appropriate to local circumstances. Hygiene measures : Keep good industrial hygiene. When using do not eat, drink or smoke. Wash hands and face before breaks and immediately after handling of the product. Take off contaminated clothing. Separate working clothes from town clothes. Keep away from food, drink and animal feedingstuffs. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Do not store near or with any of the incompatible materials listed in section 10. Protect from sunlight. Keep container tightly closed in a cool, well-ventilated place. Keep in a bunded area. Product may release Hydrogen Sulphide: A specific assessment of inhalation risks from the presence of hydrogen sulphide in tank headspaces, confined spaces, product residue, tank waste and waste water, and unintentional releases should be made to help determine controls appropriate to local circumstances. Storage of flammable liquids. Packaging materials : Keep only in the original container. Steel. Stainless steel. 7.3. Specific end use(s) see attached exposure scenario. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Fuels, diesel; Gasoil - unspecified (68334-30-5) Belgium Limit value (mg/m³) 100 mg/m³ (aerosol and vapor) Ireland OEL (8 hours ref) (mg/m³) 100 mg/m³ Ireland OEL (15 min ref) (mg/m3) 300 mg/m³ (calculated) Poland NDS (mg/m³) 0,5 mg/m³ (respirable fraction stable particulates) Portugal OEL TWA (mg/m³) 100 mg/m³ (aerosol and vapor) USA - ACGIH ACGIH TWA (mg/m³) 100 mg/m³ (inhalable fraction and vapor) Fuels, diesel (68334-30-5) DNEL/DMEL (workers) Acute - systemic effects, inhalation (15min) 4300 mg/m³ Long-term - systemic effects, dermal (8h) 2,9 mg/kg bodyweight/day Long-term - systemic effects, inhalation (8h) 68 mg/m³ DNEL/DMEL (general population) Acute - systemic effects, inhalation (15min) 2600 mg/kg bodyweight/day Long-term - systemic effects, inhalation 20 mg/m³ Page : 6 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 Fuels, diesel (68334-30-5) Long-term - systemic effects, dermal 1,3 mg/kg bodyweight/day PNEC (additional information) Additional information Substance of unknown or variable composition, complex reaction products or biological material (UVCB). No data available Additional information : Exposure limits. Personal monitoring. Room air monitoring 8.2. Exposure controls Engineering measure(s) : Provide adequate ventilation. Use only in area provided with appropriate exhaust ventilation. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Take precautionary measures against static discharge. Provide adequate precautions, such as electrical grounding and bonding, or inert atmospheres. Organisational measures to prevent /limit releases, dispersion and exposure. See also section 7. Personal protective equipment : The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hand protection : The selection of specific gloves for a specific application and time of use in a working area, should also take into account other factors on the working space, such as (but not limited to): other chemicals that are possibly used, physical requirements (protection against cutting/drilling, skill, thermal protection), and the instructions/specification of the supplier of gloves. rubber gloves. (EN 374). NBR (Nitrile rubber). Material thickness: 0,54mm. Breakthrough time : >240min. The data about break through time/strength of material are standard values! The exact break through time/strength of material has to be obtained from the producer of the protective glove. Eye protection : Goggles. face shield (EN 166). Body protection : Wear suitable coveralls to prevent exposure to the skin. Protective helmets. antistatic boots Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Half-face mask (DIN EN 140). full face mask (DIN EN 136). Filter type: A (EN 141) / ABEK (H2S) (EN141). Self-contained open-circuit compressed air breathing apparatus (EN 137) Thermal hazard protection : Not required for normal conditions of use. Use dedicated equipment. Environmental exposure controls : Avoid release to the environment. Comply with applicable Community environmental protection legislation. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : liquid. Colour : Yellow. Odour : petroleum hydrocarbon odour. Odour threshold : No data available pH : NA: UVCB Relative evaporation rate (butylacetate=1) : No data available Melting / freezing point : -40 - 6 °C Freezing point : No data available Initial boiling point and boiling range : 141 - 500 °C Flash point : 55 - 75 °C 3 - Flammable liquids Page : 7 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 Auto-ignition temperature : > 225 °C Decomposition temperature : No data available Flammability (solid, gas) : Not applicable,liquid Vapour pressure : 0,4 kPa Vapour density : > 1 Vapour density Relative density : No data available Density : 800 - 910 kg/m³ Solubility : Water: NA: UVCB Partition coefficient n-octanol/water : NA: UVCB Kinematic viscosity : 4,574 mm²/s @ 20°C Dynamic viscosity : No data available Explosive properties : NA: The study does not need to be conducted because there are no chemical groups associated with explosive properties present in the molecule. Oxidising properties : NA: The classification procedure needs not to be applied because there are no chemical groups present in the molecule which are associated with oxidising properties. Explosive limits : No data available 9.2. Other information No data available SECTION 10: Stability and reactivity 10.1. Reactivity Flammable liquid. Reference to other sections: 10.5. 10.2. Chemical stability The product is stable under storage at normal ambient temperatures. 10.3. Possibility of hazardous reactions Vapours may form explosive mixture with air. 10.4. Conditions to avoid Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. See also section 7. Handling and storage. 10.5. Incompatible materials Incompatible with strong acids and oxidizing agents. Bases. See also section 7. Handling and storage. 10.6. Hazardous decomposition products Carbon oxides, H2S, SOx. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Inhalation: Harmful if inhaled. Fuels, diesel (68334-30-5) LD50/oral/rat 7600 mg/kg LD50/dermal/rabbit > 4300 mg/kg LC50/inhalation/4h/rat 4,1 mg/l/4h Fuels, diesel; Gasoil - unspecified (68334-30-5) LD50/oral/rat 7500 mg/kg LD50/dermal/rabbit > 2000 mg/kg LC50/inhalation/4h/rat 4,6 mg/l/4h Page : 8 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 Skin corrosion/irritation : Causes skin irritation. pH: NA: UVCB Serious eye damage/irritation : Not classified (Based on available data, the classification criteria are not met.) pH: NA: UVCB Respiratory or skin sensitisation : Not classified (Based on available data, the classification criteria are not met.) Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met.) Carcinogenicity : Suspected of causing cancer. Test Method : Dermal, mouse, males, life long, 3x wk, 24µL. Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met.) STOT-single exposure : Not classified (Based on available data, the classification criteria are not met.) STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure. Target Organs : blood liver thymus Fuels, diesel (68334-30-5) NOAEL (dermal, rat/rabbit, 90 days) 30 mg/kg bodyweight/day NOAEC, mammalian, long term, 1710 mg/m³ (90 days) Inhalation, Rat, systemic Aspiration hazard : May be fatal if swallowed and enters airways. Fuels, diesel (68334-30-5) Kinematic viscosity 4,574 mm²/s @ 20°C Other information : Symptoms related to the physical, chemical and toxicological characteristics. Reference to other sections: 4.2. SECTION 12: Ecological information 12.1. Toxicity Environmental properties : Toxic to aquatic life with long lasting effects. Fuels, diesel (68334-30-5) EL50, aquatic invertebrates, acute, 68 mg/l (48 hours) Freshwater, Daphnia magna (Big water flea) IL50, aquatic algae, Pseudokirchneriella 22 mg/l (72 hours) subcapitata LL50, fish, acute, Freshwater, 21 mg/l (96 hours) Oncorhynchus mykiss (Rainbow trout) NOEL, aquatic invertebrates, long term, 0.21 mg/l (14 days) Freshwater, Daphnia magna (Big water flea) NOEL, fish, long term, Freshwater, 0.083 mg/l (QSAR) Oncorhynchus mykiss (Rainbow trout) Fuels, diesel; Gasoil - unspecified (68334-30-5) LC50 fish 1 35 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 1- 100 mg/l 12.2. Persistence and degradability Fuels, diesel (68334-30-5) Persistence and degradability Not applicable. Page : 9 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 12.3. Bioaccumulative potential Fuels, diesel (68334-30-5) Partition coefficient n-octanol/water NA: UVCB Fuels, diesel; Gasoil - unspecified (68334-30-5) Partition coefficient n-octanol/water 3.6- 6 12.4. Mobility in soil Fuels, diesel (68334-30-5) Ecology - soil Not applicable. UVCB. 12.5. Results of PBT and vPvB assessment Fuels, diesel (68334-30-5) Results of PBT assessment This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 12.6. Other adverse effects Additional information : Do not allow to enter into surface water or drains SECTION 13: Disposal considerations 13.1. Waste treatment methods Product/Packaging disposal : Handle with care. Safe handling: see section 7. Handling and storage. Refer to recommendations manufacturer/supplier for information on recovery/recycling. Collect and dispose of waste product at an authorised disposal facility. Dispose of contaminated materials in accordance with current regulations. Additional information : Never use pressure to empty container. Do not burn, or use a cutting torch on the empty drum. Do not puncture or incinerate. Delivery to an approved waste disposal company. Dispose of contaminated materials in accordance with current regulations. Further ecological information : Do not allow to enter into surface water or drains. European waste catalogue (2001/573/EC, : Classified as hazardous waste according to European Union regulations. 75/442/EEC, 91/689/EEC) Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities. The following Waste Codes are only suggestions: 130701 - fuel oil and diesel 150110 - packaging containing residues of or contaminated by dangerous substances SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID 14.1. UN number 1202 14.2. UN proper shipping name GAS OIL (Fuels, diesel; GAS OIL (Fuels, diesel; Gas oil (Fuels, diesel; GAS OIL (Fuels, diesel; GAS OIL (Fuels, diesel; Gasoil - unspecified) Transport document description UN 1202 GAS OIL UN 1202 Gas oil UN 1202 GAS OIL (Fuels, diesel; Gasoil - unspecified), 3, III, unspecified), 3, III (D/E) 14.3. Transport hazard class(es) 3 Page : 10 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 ADR IMDG IATA ADN RID 14.4. Packing group III 14.5. Environmental hazards Dangerous for the environment : No environment : No environment : No environment : No environment : No Marine pollutant : No ADN :N2 14.6. Special precautions for user - Overland transport Classification code (ADR) : F1 Special provisions : 640L, 363, 664 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container : T2 instructions (ADR) Portable tank and bulk container special : TP1 provisions (ADR) Tank code (ADR) : LGBF Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages : V12 (ADR) Special provisions for carriage - Operation : S2 (ADR) Hazard identification number (Kemler No.) : 30 Orange plates : Tunnel restriction code : D/E EAC code : 3Y - Transport by sea Special provisions (IMDG) : 363 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T2 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E Page : 11 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 EmS-No. (Spillage) : S-E Stowage category (IMDG) : A Properties and observations (IMDG) : Immiscible with water. - Air transport PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y344 PCA limited quantity max net quantity : 10L (IATA) PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) : 220L Special provisions (IATA) : A3 ERG code (IATA) : 3L - Inland waterway transport Classification code (ADN) : F1 Special provisions (ADN) : 363, 640L Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 0 - Rail transport Classification code (RID) : F1 Special provisions (RID) : 363, 640L Limited quantities (RID) : 5L Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container : T2 instructions (RID) Portable tank and bulk container special : TP1 provisions (RID) Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 3 Special provisions for carriage – Packages : W12 (RID) Colis express (express parcels) (RID) : CE4 Hazard identification number (RID) : 30 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Code: IBC : This product is being carried under the scope of MARPOL Annex l Diesel fuel. Page : 12 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3. Liquid substances or mixtures which are regarded as dangerous in accordance with Fuels, diesel - Fuels, diesel; Gasoil - unspecified Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008 3(a) Substances or mixtures fulfilling the criteria for any of the following hazard classes or Fuels, diesel - Fuels, diesel; Gasoil - unspecified categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F 3(b) Substances or mixtures fulfilling the criteria for any of the following hazard classes or Fuels, diesel - Fuels, diesel; Gasoil - unspecified categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 3(c) Substances or mixtures fulfilling the criteria for any of the following hazard classes or Fuels, diesel - Fuels, diesel; Gasoil - unspecified categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 Fuels, diesel is not on the REACH Candidate List Fuels, diesel is not on the REACH Annex XIV List 15.1.2. National regulations Germany Reference to AwSV : Water hazard class (WGK) 2, significant hazard to waters (Classification according to VwVwS, Annex 1 or 2; ID No. 76) Risk classification according to VbF : A III - Liquids with a flashpoint above 55°C up to 100°C 12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Immission Control Act - 12.BImSchV TA Luft : Organic Substances Netherlands Waterbezwaarlijkheid : 6 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. (A) SZW-lijst van kankerverwekkende stoffen : Fuel diesel is listed SZW-lijst van mutagene stoffen : Fuel diesel is listed NIET-limitatieve lijst van voor de : The substance is not listed voortplanting giftige stoffen – Borstvoeding NIET-limitatieve lijst van voor de : The substance is not listed voortplanting giftige stoffen – Vruchtbaarheid NIET-limitatieve lijst van voor de : The substance is not listed voortplanting giftige stoffen – Ontwikkeling Denmark Recommendations Danish Regulation : Page : 13 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 15.2. Chemical safety assessment For this substance a chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: 1 Modified 2 Modified 15 Modified 16 Modified Abbreviations and acronyms: ADN = Accord Européen relatif au Transport International des Marchandises Dangereuses par voie de Navigation du Rhin ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route CLP = Classification, Labelling and Packaging Regulation according to 1272/2008/EC IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods Code LEL = Lower Explosive Limit/Lower Explosion Limit UEL = Upper Explosion Limit/Upper Explosive Limit REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals CSR = Chemical Safety Report DNEL = Derived No Effect Level EC50 = Median Effective Concentration N = Dangerous for the environment LC50 = Median lethal concentration LD50 = Median lethal dose NOEL = no-observed-effect level PBT = persistent, bioaccumulating and toxic (PBT). PNEC = Predicted No Effect Concentration STEL = Short term exposure limit TLV = Threshold limits TWA = time weighted average vPvB = very persistent and very bioaccumulating WGK = Wassergefährdungsklasse (Water Hazard Class under German Federal Water Management Act) NA = Not applicable UVCB = Substance of unknown or variable composition, complex reaction products or biological material (UVCB) Sources of key data used to compile the : European Chemicals Agency SDS of supplier. datasheet Training advice : Training staff on good practice. Manipulations are to be done only by qualified and authorised persons. Full text of H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment - chronic hazard category 2 Asp. Tox. 1 Aspiration hazard, Category 1 Carc. 2 Carcinogenicity, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H332 Harmful if inhaled. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. Page : 14 / 14 Revision nr : 3.0 Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 H411 Toxic to aquatic life with long lasting effects. According to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Classification according to Regulation (EC) No. 1272/2008 [CLP] Labelling according to Regulation (EC) No. 1272/2008 [CLP] DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 1 of 10 ______________________________________________________________________________________________________________________ SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Product Description: Glycol Product Code: 351010602030 Intended Use: Antifreeze/coolant COMPANY IDENTIFICATION Supplier: AMPOL AUSTRALIA PETROLEUM PTY LTD ABN 17 000 032 128 29-33 Bourke Rd Alexandria New South Wales 2015 Australia 24 Hour Emergency Telephone 1800 033 111 Product Technical Information 1300364169 Supplier General Contact +612 9250-5000 FAX +612 9250-5742 SECTION 2 HAZARDS IDENTIFICATION This material is hazardous according to regulatory guidelines (see (M)SDS Section 15). GHS CLASSIFICATION: Acute oral toxicant: Category 4. Specific target organ toxicant (repeated exposure): Category 2. GHS Label Elements: Pictogram: Signal Word: Warning Hazard Statements: Health: H302: Harmful if swallowed. H373: May cause damage to organs through prolonged or repeated Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 2 of 10 ______________________________________________________________________________________________________________________ exposure. Kidney Precautionary Statements: General: P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P103: Read label before use. Prevention: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe mist / vapours. P264: Wash skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear protective gloves and clothing. Response: P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P308 + P313: IF exposed or concerned: Get medical advice/attention. P314: Get medical advice/attention if you feel unwell. P330: Rinse mouth. Storage: P405: Store locked up. Disposal: P501: Dispose of contents and container in accordance with local regulations. Contains: ETHYLENE GLYCOL; TETRASODIUM EDTA Other hazard information: Physical / Chemical Hazards: No significant hazards. Health Hazards: High-pressure injection under skin may cause serious damage. Ingestion may cause serious adverse effects and may be fatal. May cause kidney failure and central nervous system effects. Prolonged exposure to elevated concentrations of mist or liquid may cause irritation of the skin, eyes, and respiratory tract. Environmental Hazards: No significant hazards. NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes 2-ETHYLHEXANOIC ACID, SODIUM SALT 19766-89-3 0.1 - < 1% H361(D) DISODIUM TETRABORATE PENTAHYDRATE 12179-04-3 0.1 - < 0.3% H319(2A), H360(1B)(D), H360(1B)(F) ETHYLENE GLYCOL 107-21-1 30 - < 40% H302, H373 TETRASODIUM EDTA 64-02-8 0.1 - < 1% H302, H332, H318, H373 * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Other ingredients determined not to be hazardous up to 100%. Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 3 of 10 ______________________________________________________________________________________________________________________ SECTION 4 FIRST AID MEASURES INHALATION Immediately remove from further exposure. Get immediate medical assistance. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. Give supplemental oxygen, if available. If breathing has stopped, assist ventilation with a mechanical device. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION Seek immediate medical attention. NOTE TO PHYSICIAN This product contains ethylene glycol and/or diethylene glycol which, if ingested, are metabolized to toxic metabolites by the enzyme alcohol dehydrogenase, for which ethanol and 4-methylpyrazole \{U.S. drug name Fomepizole, trade name Antizol\} are antagonists. Administration of oral or intravenous ethanol or intravenous 4-methylpyrazole may arrest further metabolism of this material and thereby ameliorate the toxicity. Use of ethanol or 4-methylpyrazole does not affect toxic metabolites that are already present and is not a substitute for hemodialysis. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water or standard foam FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke, Fume FLAMMABILITY PROPERTIES Flash Point [Method]: >100°C (212°F) [Closed Cup] Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 4 of 10 ______________________________________________________________________________________________________________________ Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. PROTECTIVE MEASURES Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Do not touch or walk through spilled material. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Consult an expert. Material will sink. This product emulsifies, disperses or is miscible in water. Remove material, as much as possible, using mechanical equipment. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Remove debris in path of spill and remove contaminated debris from shoreline and water surface. Dispose of according to local regulations. Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid breathing mists or vapour. Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator. STORAGE Do not store in open or unlabelled containers. Material is defined under the National Standard [NOHSC:1015] Storage and Handling of Workplace Dangerous Goods. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMIT VALUES Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 5 of 10 ______________________________________________________________________________________________________________________ Exposure limits/standards (Note: Exposure limits are not additive) Substance Name Form Limit/Standard Note Source DISODIUM TETRABORATE TWA 1 mg/m3 Australia WES PENTAHYDRATE DISODIUM TETRABORATE Inhalable STEL 6 mg/m3 ACGIH PENTAHYDRATE fraction. DISODIUM TETRABORATE Inhalable TWA 2 mg/m3 ACGIH PENTAHYDRATE fraction. ETHYLENE GLYCOL Vapour. STEL 104 mg/m3 40 ppm Skin Australia WES ETHYLENE GLYCOL Particulat TWA 10 mg/m3 Skin Australia WES e. ETHYLENE GLYCOL Vapour. TWA 52 mg/m3 20 ppm Skin Australia WES ETHYLENE GLYCOL Aerosol, STEL 10 mg/m3 ACGIH inhalable ETHYLENE GLYCOL Vapor STEL 50 ppm ACGIH fraction ETHYLENE GLYCOL Vapor TWA 25 ppm ACGIH fraction NOTE: Limits/standards shown for guidance only. Follow applicable regulations. Biological limits No biological limits allocated. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: Organic vapour No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 6 of 10 ______________________________________________________________________________________________________________________ Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Nitrile,Viton Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Form: Clear Colour: Blue-Green Odour: Characteristic Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 °C): 1.05 Flammability (Solid, Gas): N/A Flash Point [Method]: >100°C (212°F) [Closed Cup] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: N/D Decomposition Temperature: N/D Vapour Density (Air = 1): N/D Vapour Pressure: [N/D at 20ºC] Evaporation Rate (n-butyl acetate = 1): N/D pH: 7 Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Complete Viscosity: [N/D at 40ºC] Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 7 of 10 ______________________________________________________________________________________________________________________ Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/D SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. INCOMPATIBLE MATERIALS: Strong Acids, Strong oxidisers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for Minimally Toxic. Based on assessment of the components. material. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Ingestion Acute Toxicity (Human): LDLo 100 ml Moderately toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for Minimally Toxic. Based on assessment of the components. material. Skin Corrosion/Irritation: No end point data Negligible irritation to skin at ambient temperatures. Based on for material. assessment of the components. Eye Serious Eye Damage/Irritation: No end point May cause mild, short-lasting discomfort to eyes. Based on data for material. assessment of the components. Sensitisation Respiratory Sensitization: No end point data Not expected to be a respiratory sensitizer. for material. Skin Sensitization: No end point data for Not expected to be a skin sensitizer. Based on assessment of the material. components. Aspiration: No end point data for material. Not expected to be an aspiration hazard. Based on physico- chemical properties of the material. Germ Cell Mutagenicity: No end point data Not expected to be a germ cell mutagen. Based on assessment of for material. the components. Carcinogenicity: No end point data for Not expected to cause cancer. Based on assessment of the material. components. Reproductive Toxicity: No end point data Contains a substance that may be a reproductive toxicant. Based for material. on assessment of the components. Lactation: No end point data for material. Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 8 of 10 ______________________________________________________________________________________________________________________ Single Exposure: No end point data for Not expected to cause organ damage from a single exposure. material. Repeated Exposure: No end point data for Contains a substance that may cause damage to organs from material. prolonged or repeated exposure. Based on assessment of the components. TOXICITY FOR SUBSTANCES NAME ACUTE TOXICITY TETRASODIUM EDTA Oral Lethality: LD 50 1847 mg/kg (Rat) OTHER INFORMATION For the product itself: Target Organs Repeated Exposure: Kidney Contains: ETHYLENE GLYCOL (EG): Repeated high oral exposure has caused kidney damage, neurological effects, degeneration of the liver and changes in blood chemistry and circulating blood cells in laboratory animals. Repeated overexposure has the potential to cause similar toxic effects in humans. EG causes developmental and reproductive effects at high dose levels in laboratory animals. The relevance of these findings to humans is uncertain. However, as a precaution, avoid exposure during pregnancy. Sodium tetraborate: Adverse effects on fertility and fetal development have been observed in laboratory animals. IARC Classification: The following ingredients are cited on the lists below: None. --REGULATORY LISTS SEARCHED-- 1 = IARC 1 2 = IARC 2A 3 = IARC 2B SECTION 12 ECOLOGICAL INFORMATION The information given is based on data for the material, components of the material, or for similar materials, through the application of bridging principals. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Material -- Expected to remain in water or migrate through soil. PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be readily biodegradable. Atmospheric Oxidation: Material -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Material -- Potential to bioaccumulate is low. Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 9 of 10 ______________________________________________________________________________________________________________________ SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Even though this product is readily biodegradable, it must not be indiscriminately discarded into the environment. Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (ADG) : Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION This material is considered hazardous according to Australia Model Work Health and Safety Regulations. Product is not regulated according to Australian Dangerous Goods Code. Poison Schedule number allocated by the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) established under the Therapeutic Goods Act. POISON SCHEDULE NUMBER: S5 AS1940 COMBUSTIBLE CLASS: C2 REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS Listed or exempt from listing/notification on the following chemical inventories : AIIC, ENCS, IECSC, PICCS, TCSI, TSCA SECTION 16 OTHER INFORMATION Product Name: MOBIL COOLANT EXTRA READY MIXED -24 C Revision Date: 05 Oct 2021 Page 10 of 10 ______________________________________________________________________________________________________________________ KEY TO ABBREVIATIONS AND ACRONYMS: N/D = Not determined, N/A = Not applicable, STEL = Short-Term Exposure Limit, TWA = Time-Weighted Average KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H302: Harmful if swallowed; Acute Tox Oral, Cat 4 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H319(2A): Causes serious eye irritation; Serious Eye Damage/Irr, Cat 2A H332: Harmful if inhaled; Acute Tox Inh, Cat 4 H360(1B)(D): May damage the unborn child; Repro Tox, Cat 1B (Develop) H360(1B)(F): May damage fertility; Repro Tox, Cat 1B (Fertility) H361(D): Suspected of damaging the unborn child; Repro Tox, Cat 2 (Develop) H373: May cause damage to organs through prolonged or repeated exposure; Target Organ, Repeated, Cat 2 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Section 01: Company Mailing Address information was modified. Section 08: Exposure Limits Table information was modified. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re- publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly of indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 7090980DAU (1013981) ----------------------------------------------------------------------------------------------------------------------------------------------------- Prepared by: Exxon Mobil Corporation EMBSI, Clinton NJ USA Contact Point: See Section 1 for Local Contact number End of (M)SDS Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - Ireland JCB HP Engine Oil 10W-30 SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Product name : JCB HP Engine Oil 10W-30 Viscosity or Type : SAE 10W-30 Material uses : Lubricating oil for automotive engines 1.2 Relevant identified uses of the substance or mixture and uses advised against Not applicable. 1.3 Details of the supplier of the safety data sheet Manufacturer / Distributor : JCB Service World Parts Centre Waterloo Park Beamhurst Staffordshire England ST14 5PA e-mail address of person : aftermarketproduct.hotline@jcb.com (Mon to Fri 9.00am to 4.00pm UK time) responsible for this SDS Communication in English only 1.4 Emergency telephone number Telephone number : +44 1865 407333 - English language only +1 202 464 2554 - English language only specific to US and Canada SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : Mixture Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Not classified. The product is not classified as hazardous according to Regulation (EC) 1272/2008 as amended. Ingredients of unknown : None. toxicity Ingredients of unknown : None. ecotoxicity See Section 11 for more detailed information on health effects and symptoms. 2.2 Label elements Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. Date of issue/Date of revision : 15-06-2018 Date of previous issue : 19-05-2017 Version : 2.02 1/12 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - Ireland JCB HP Engine Oil 10W-30 SECTION 2: Hazards identification Supplemental label : Contains Benzenesulfonic acid, mono-C16-24-alkyl derivs., calcium salts. May elements produce an allergic reaction. Safety data sheet available on request. Annex XVII - Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Special packaging requirements Containers to be fitted : Not applicable. with child-resistant fastenings Tactile warning of danger : Not applicable. 2.3 Other hazards Other hazards which do : Prolonged or repeated contact may dry skin and cause irritation. not result in classification SECTION 3: Composition/information on ingredients 3.2 Mixtures : Mixture Product/ingredient name Identifiers % Regulation (EC) No. Type Notes 1272/2008 [CLP] Distillates (petroleum), REACH #: ≥75 - ≤90 Not classified. [2] L hydrotreated heavy paraffinic 01-2119484627-25 CAS: 64742-54-7 Index: 649-467-00-8 Lubricating oils (petroleum), REACH #: ≥10 - ≤25 Asp. Tox. 1, H304 [1] H-L C20-50, hydrotreated neutral oil- 01-2119474889-13 based EC: 276-738-4 CAS: 72623-87-1 Index: 649-483-00-5 Mineral oil CAS: * ≤5 Asp. Tox. 1, H304 [1] [2] - See Section 16 for the full text of the H statements declared above. The mineral oils in the product contain < 3% DMSO extract (IP 346). There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section. Type [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern [6] Additional disclosure due to company policy Occupational exposure limits, if available, are listed in Section 8. Date of issue/Date of revision : 15-06-2018 Date of previous issue : 19-05-2017 Version : 2.02 2/12 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - Ireland JCB HP Engine Oil 10W-30 SECTION 4: First aid measures 4.1 Description of first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Skin contact : Wash skin thoroughly with soap and water or use recognised skin cleanser. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. 4.2 Most important symptoms and effects, both acute and delayed Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : Adverse symptoms may include the following: irritation dryness cracking Ingestion : No specific data. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing : Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog). media Unsuitable extinguishing : Do not use water jet. media 5.2 Special hazards arising from the substance or mixture Hazards from the : In a fire or if heated, a pressure increase will occur and the container may burst. substance or mixture Hazardous combustion : Decomposition products may include the following materials: products carbon dioxide carbon monoxide sulfur oxides 5.3 Advice for firefighters Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Date of issue/Date of revision : 15-06-2018 Date of previous issue : 19-05-2017 Version : 2.02 3/12 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - Ireland JCB HP Engine Oil 10W-30 SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". 6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains precautions and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 6.3 Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. 6.4 Reference to other : See Section 1 for emergency contact information. sections See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. SECTION 7: Handling and storage The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 7.1 Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. 7.3 Specific end use(s) Recommendations : Not available. Industrial sector specific : Not available. solutions Date of issue/Date of revision : 15-06-2018 Date of previous issue : 19-05-2017 Version : 2.02 4/12 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - Ireland JCB HP Engine Oil 10W-30 SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases. 8.1 Control parameters Occupational exposure limits Product/ingredient name Exposure limit values Distillates (petroleum), hydrotreated heavy NAOSH (Ireland, 3/2016). paraffinic OELV-8hr: 5 ppm 8 hours. Form: inhalable dust Mineral oil NAOSH (Ireland, 5/2010). OELV-8hr: 5 ppm 8 hours. Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace procedures atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required. DNELs/DMELs No DNELs/DMELs available. PNECs No PNECs available 8.2 Exposure controls Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Wear suitable gloves tested to EN374. Recommended: < 1 hour (breakthrough time): nitrile rubber 0.17 mm. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision : 15-06-2018 Date of previous issue : 19-05-2017 Version : 2.02 5/12 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - Ireland JCB HP Engine Oil 10W-30 SECTION 8: Exposure controls/personal protection Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Recommended: Boiling point > 65 °C: A1; Boiling point < 65 °C: AX1; Hot material: A1P2. Environmental exposure : Emissions from ventilation or work process equipment should be checked to controls ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state : Liquid. [Oily liquid.] Appearance : Clear. Colour : Yellow [Light] Odour : Slight Odour threshold