Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
10-<20 >=0.1%
EC/CAS
227-534-9/5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
615-005- 0.1-<0.3 01-2119480143- >=0.1%
General Information
Revision date
2023-01-27
Product name
HERBERTS 1K-LF 194
1.2.1 Relevant identified uses
Adhesive
1.2.2. Uses advised against
Consumer use
Emergency telephone
+44 (1785) 272650
Icons in SDS
Company Information
company name
Bostik Limited
e-mail address of the competent person responsible for the Safety Data Sheet
SDS.box-EU@bostik.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Contains
4,4'-Methylenediphenyl diisocyanate, o-(p-isocyanatobenzyl)phenyl isocyanate
Signal word
Danger
Hazard statements
H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P260 - Do not breathe dust/fume/gas/mist/vapours/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor P501 - Dispose of contents/ container to an approved waste disposal plant
Special rules for supplemental label elements for certain mixtures
As from 24 August 2023 adequate training is required before industrial or professional use.
Additional information
This product requires tactile warnings if supplied to the general public.
2.3 Other hazards
No information available.
PBT Substances
& vPvB This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
2.1 Classification of the substance or mixture
Regulation (EC) No 1272/2008 Skin corrosion/irritation Category 2 - (H315) Serious eye damage/eye irritation Category 2 - (H319) Respiratory sensitisation Category 1 - (H334) Skin sensitisation Category 1 - (H317) Carcinogenicity Category 2 - (H351) Specific target organ toxicity — single exposure Category 3 - (H335) Category 3 Respiratory irritation Specific target organ toxicity — repeated exposure Category 2 - (H373)
